Field based speciation of arsenic in UK and Argentinean water samples

A field method is reported for the speciation of arsenic in water samples that is simple, rapid, safe to use beyond laboratory environments, and cost effective. The method utilises solid-phase extraction cartridges (SPE) in series for selective retention of arsenic species, followed by elution and measurement of eluted fractions by inductively coupled plasma mass spectrometry (ICP-MS) for “total” arsenic. The method is suitable for on-site separation and preservation of arsenic species from water. Mean percentage accuracies (n = 25) for synthetic solutions of arsenite (As^III), arsenate (As^V), monomethylarsonic acid (MA), and dimethylarsinic acid (DMA) containing 10 μg l⁻¹ As, were 98, 101, 94, and 105%, respectively. Data are presented to demonstrate the effect of pH and competing anions on the retention of the arsenic species. The cartridges were tested in the UK and Argentina at sites where arsenic was known to be present in surface and groundwaters, respectively, at elevated concentrations and under challenging matrix conditions. In Argentinean groundwater, 4–20% of speciated arsenic was present as MA and 20–73% as As^III. In UK surface waters, speciated arsenic was measured as 7–49% MA and 12–42% DMA. Comparative data from the field method using SPE cartridges and the laboratory method using liquid chromatography coupled to ICP-MS for all water samples provided a correlation of greater than 0.999 for As^III and DMA, 0.991 for MA, and 0.982 for As^V (P < 0.01).     

Landbased Pollution Sources and Marine Environmental Quality in the Caribbean

Abstract

The near shore coastal and marine environment of several Caribbean islands is their most biologically productive and economically important zone. However, almost all landbased activities possess the real potential of degrading the quality of near shore waters and ultimately diminishing the utility of the marine resource. This condition is largely attributed to the individual smallness of the islands and their geographic proximity to each other.

Available sanitary water quality data from across the region indicated that while recreational areas are in general safe for water contact activities, bacterial densities in excess of several international criteria are consistently recorded in harbours. Organochlorine pesticide residues were generally in the 5 ng l^?1 range in unfiltered sea water but were significantly higher (1–100) ng g^?1 in limited samples of sediment and biota. Additional data requirements to gain further insight into the current state of the Caribbean environment are also identified.

A summary of the major land based sources of marine pollution (including sewage, industrial effluents and agricultural run-off) in the insular Caribbean is presented.     

Female preferences for spectral call properties in the western genetic lineage of Cope's gray treefrog (Hyla chrysoscelis)

Female frogs discriminate among potential mates based on individual variation in male advertisement calls. While considerable data have accumulated allowing comparisons of female preference functions among species, we still lack fundamental knowledge about how and why the shapes of preference functions for particular call properties vary among populations within all but a few species. Here, we report results from a study aimed at describing female preference functions for spectral call properties in Cope's gray treefrog (Hyla chrysoscelis). Widespread throughout the eastern half of North America, Cope's gray treefrog is the diploid member of the cryptic diploid–tetraploid Hyla versicolor species complex, and its populations are divided into two distinct genetic lineages (eastern and western). In this study of a western lineage population, we recorded and analyzed the spectral properties of 1,000 advertisement calls from 50 males and conducted two-stimulus phonotaxis experiments to estimate a population-level preference function. Females preferred calls with average frequencies over calls with frequencies that were 2 or 3 semitones (1.4 or 2.1 standard deviations, respectively) lower than the population mean. We observed no behavioral discrimination between calls with average and higher-than-average frequencies. Preferences discriminating against low-frequency calls were weak and were abolished by attenuating the preferred average call by 3?dB. We discuss these results in light of previous studies of eastern lineage populations, geographic variation in female preference functions, and the potential adaptive value of discriminating against calls with low frequencies.     

Development and use of water quality criteria and standards in the United States

Water quality criteria, as a means of distinguishing "good" water from "bad" water, have been employed for over 150 years. During the 1940s and 1950s, the formulation of water quality criteria and their role in water quality management were hotly debated in the United States as each state formulated its own approach to water pollution control. In 1965, when the federal government assumed control of water quality management in the US, a single, national approach to the formulation and use of criteria had to be selected and implemented nationwide. The purpose of this paper is to briefly review the history of criteria as a basis for water quality management in the US; note the different water quality management philosophies used by states prior to 1965; and summarize the relationship of criteria to monitoring over the past 30 years. Standards, as legal instruments, are developed for a specific water body by designating a use of the water (society value) and the criteria necessary to protect the use (a scientific finding). Standard violation, as a concept, tends to remain as a single-sample exercise (i.e., the sample measurement is either above or below the standard). Increasingly, however, there is a demand to classify large bodies of water (e.g., lake, river segment, or aquifer), over a set time period, such as a day, year, or decade, as either in compliance or in violation of water quality standards. No peer-reviewed, standardized method for computing standard "violations" has been widely accepted for this purpose. The paper ends with a call to develop such methods, if water quality managers must produce standard violation information (infer sample results) over time and space. Electronic Publication     

The Europeanisation of local environmental politics: Bathing water pollution in south-west England

The influence of European environmental policy is transforming more than just the way that environmental protection is organised and implemented in the UK. The nature of environmental politics is also changing dramatically. The paper examines the implementation of the Bathing Waters Directive in the South West of England to illustrate how Europeanisation opens up new scope and spaces for political action. The legal standards laid down in directives such as the Bathing Waters Directive provide an authoritative yardstick which environmental pressure groups can use to exert pressure at the local as well as the national level. In turn, Europe becomes increasingly viewed in the UK as the moral arbiter of what counts as 'pollution'.     

HYDROGEOLOGIC EVALUATION OF WETLAND BASINS FOR LAND USE PLANNING1

ABSTRACT: Wetlands occur in a variety of geologic, hydrologic, and topographic settings and exhibit diverse hydrogeologic characteristics. A wetland is more than an organic mat - it is an element in a larger hydrogeologic system. Three distinct but related effects of wetlands are: modifying the character of runoff from a basin, influencing the discharge/recharge relationship with the underlying aquifer, and effecting the potential for ground water development in a wetland dominated basin. An important goal of wetland research is to define the diverse roles that wetlands play in the regional hydrology and to define the geologic, hydrologic, and topographic factors that will allow meaningful distinctions among wetlands. Geologic and hydrologic factors include character and thickness of surficial materials; bedrock type; hydrologic position; permeability of organic layer; transmissivity, quality, and hydrologic connection of wetland related aquifers; ground water outflow; and depth of standing water. Topographic factors are position in the drainage basin, relative size, and absolute size of wetlands. A wetland classification to aid hydrologists and land use planners is proposed using selected factors involving hydrologic position, topographic position, and geologic type.     

SAMPLING FREQUENCY SELECTION FOR REGULATORY WATER QUALITY MONITORING1

ABSTRACT: The selection of sampling frequencies in order to achieve reasonably small and uniform confidence interval widths about annual sample means or sample geometric means of water quality constituents is suggested as a rational approach to regulatory monitoring network design. Methods are presented for predicting confidence interval widths at specified sampling frequencies while considering both seasonal variation and serial correlation of the quality time series. Deterministic annual cycles are isolated and serial dependence structures of the autoregressive, moving average type are identified through time series analysis of historic water quality records. The methods are applied to records for five quality constituents from a nine-station network in Illinois. Confidence interval widths about annual geometric means are computed over a range of sampling frequencies appropriate in regulatory monitoring. Results are compared with those obtained when a less rigorous approach, ignoring seasonal variation and serial correlation, is used. For a monthly sampling frequency the error created by ignoring both seasonal variation and serial correlation is approximately 8 percent. Finally, a simpler technique for evaluating serial correlation effects based on the assumption of AR(1) type dependence is examined. It is suggested that values of the parameter p₁, in the AR(1) model should range from 0.75 to 0.90 for the constituents and region studied.     

DATA REQUIREMENTS OF A WATER QUALITY MANAGEMENT PROGRAM1

ABSTRACT: Routine data collection currently consumes a large amount of the total resources devoted to water quality management. All too often data collection becomes an end in itself, with little thought given to the purpose of the data collection. The problem generally stems from a lack of proper routine surveillance system design and a failure on the part of the designers to initially identify the data needs of the management program. This study attempts, in a general way, to delineate the data needs of a water quality management program. This first required an identification of the activities involved in water quality management. The activities were then discussed in terms of the types of information needed to successfully complete their assigned tasks. Several detailed examples are given. The results of the discussion are summarized and several strategies are proposed to relate the results to surveillance system design.     

AN APPLICATION OF NETWORK THEORY TO WATER MANAGEMENT IN POULTRY PROCESSING1

ABSTRACT This paper summarizes a study employing a systems approach for analyzing one class of modifications within a poultry processing plant. The modifications considered were changes in water-flow arrangements and process characteristics to reduce water intake of the plant and waste-treatment costs. The object of the study was to develop a technique or techniques by which a combination of proposed modifications could be chosen to minimize water flow through the plant. Existing and proposed flows were represented as a network, and linear programming was used to solve the minimum-flow problem for the network. Application of the technique was made to an existing, typical plant in Durham, N.C. Results of the application showed fresh water intake could be reduced by 45% to 51%, and furthermore that annual returns of 62% to 494% could be obtained on investment in the optimum modification sets, as fresh water costs varying from 10 cents to $1.00 per 1000 gal. Types of modifications of a poultry processing plant are classified by types, and the relative importance and effectiveness of each type are discussed.