Improved daily precipitation nitrate and ammonium concentration models for the Chesapeake Bay Watershed

Daily precipitation nitrate and ammonium concentration models were developed for the Chesapeake Bay Watershed (USA) using a linear least-squares regression approach and precipitation chemistry data from 29 National Atmospheric Deposition Program/National Trends Network (NADP/NTN) sites. Only weekly samples that comprised a single precipitation event were used in model development. The most significant variables in both ammonium and nitrate models included: precipitation volume, the number of days since the last event, a measure of seasonality, latitude, and the proportion of land within 8km covered by forest or devoted to industry and transportation. Additional variables included in the nitrate model were the proportion of land within 0.8km covered by water and/or forest. Local and regional ammonia and nitrogen oxide emissions were not as well correlated as land cover. Modeled concentrations compared very well with event chemistry data collected at six NADP/AirMoN sites within the Chesapeake Bay Watershed. Wet deposition estimates were also consistent with observed deposition at selected sites. Accurately describing the spatial distribution of precipitation volume throughout the watershed is important in providing critical estimates of wet-fall deposition of ammonium and nitrate.     

Enhanced Wet Deposition Estimates using Modeled Precipitation Inputs

Effective assessments of linkages between atmospheric deposition and sensitive aquatic and terrestrial ecosystems require a knowledge of spatial patterns in deposition of greater resolution than currently available using point estimates and two-dimensional surface algorithms. A high resolution wet deposition model was developed for the Eastern U.S.A. by incorporating daily precipitation measurements from National Oceanic and Atmospheric Administration (NOAA) monitoring sites located within the Eastern U.S.A.; topographic variables, including elevation, slope, and aspect that affect the amount and distribution of precipitation across the region; and precipitation chemistry data from National Atmospheric Deposition Program (NADP) sites within and adjacent to the region. Model performance, which was tested against independent measurements from three physiographic regions of the eastern U.S.A., revealed a statistically significant reduction in interpolation error compared to traditional two-dimensional surface algorithms.     

Policy diffusion in arid Basin water management: a Q method approach in the Murray–Darling Basin,Australia

The Murray–Darling Basin is Australia’s national food bowl, home to almost half of the national income from food production, as well as internationally significant wetlands, iconic red gum forests, endangered flora and fauna, and approximately 40 autonomous indigenous nations. Persistent severe drought and extreme flooding episodes have presented new challenges in the region. Chief among these challenges is the establishment of a legitimate framework to sustainably manage water resources that finds common ground between environmental, indigenous and commercial interests. A powerful approach to examine these processes is through the theory of diffusion and adaptation of policy innovations. Here, we describe an approach to place this theory on empirical ground using Q methodology. We elucidate patterns of subjectivity, to explore the perceptions of expert advice, subsidiarity and local knowledge to better understand the interests in play. We find that respect is held for local practitioners (water managers and farmers) and indigenous knowledge, but while policy innovations are being generated, the diffusion of policy is contested. We identify the potential, though limited, for common ground through substantive and respectful consultation.     

Brake Lining Decomposition Products

A number of investigators have found asbestos bodies in the lungs of urban residents who were not occupationally exposed to asbestos. A relationship between the carinogenic properties of asbestos and the urban excess of lung cancer has been suggested. The decomposition products of brake linings have been described as a possible source of these fibers. Brake testing laboratory methods were used to test fiber emission from a variety of friction products. Only a very small fraction of the asbestos escaped as free fiber while the remainder was transformed into some other, nonfibrous, mineral. A significant release of free fiber occurred only under conditions extreme enough to produce brake failure.     

How Climate and Vegetation Influence the fire Regime of the Alaskan Boreal Biome: The Holocene Perspective

We synthesize recent results from lake-sediment studies of Holocene fire-climate-vegetation interactions in Alaskan boreal ecosystems. At the millennial time scale, the most robust feature of these records is an increase in fire occurrence with the establishment of boreal forests dominated by Picea mariana: estimated mean fire-return intervals decreased from ≥300 yrs to as low as ∼80 yrs. This fire-vegetation relationship occurred at all sites in interior Alaska with charcoal-based fire reconstructions, regardless of the specific time of P. mariana arrival during the Holocene. The establishment of P. mariana forests was associated with a regional climatic trend toward cooler/wetter conditions. Because such climatic change should not directly enhance fire occurrence, the increase in fire frequency most likely reflects the influence of highly flammable P. mariana forests, which are more conducive to fire ignition and spread than the preceding vegetation types (tundra, and woodlands/forests dominated by Populus or Picea glauca). Increased lightning associated with altered atmospheric circulation may have also played a role in certain areas where fire frequency increased around 4000 calibrated years before present (BP) without an apparent increase in the abundance of P. mariana. When viewed together, the paleo-fire records reveal that fire histories differed among sites in the same modern fire regime and that the fire regime and plant community similar to those of today became established at different times. Thus the spatial array of regional fire regimes was non-static through the Holocene. However, the patterns and causes of the spatial variation remain largely unknown. Advancing our understanding of climate-fire-vegetation interactions in the Alaskan boreal biome will require a network of charcoal records across various ecoregions, quantitative paleoclimate reconstructions, and improved knowledge of how sedimentary charcoal records fire events. In this paper, charcoal refers to macroscopic (≥180 μm) as opposed to microscopic (< 180 μm) particles unless indicated otherwise. Radiocarbon ages were converted to calibrated years before AD 1950 using the atmospheric calibration data set (Stuiver et al. 1998).     

Dissolution rates of three high explosive compounds: TNT,RDX, and HMX

Incidental exposure to high explosive compounds can cause subtle health effects to which a population could be more susceptible than injury by detonation. Proper source characterization is a key requirement in the conduct of risk assessments. For nonvolatile solid explosives, dissolution is one of the primary mechanisms that controls fate and transport, resulting in exposure to these compounds remote from their source. To date, information describing dissolution rates of high explosives has been sparse. The objective of this study was to determine the dissolution rates of three high explosive compounds, 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), in dilute aqueous solutions as a function of temperature, surface area, and energy input. To determine each variable's impact on dissolution rate, experiments were performed where one variable was changed while the other two were held constant. TNT demonstrated the fastest dissolution rate followed by HMX and then RDX. Dissolution rate correlation equations were developed for each explosive compound incorporating the three aforementioned variables, independently, and collectively in one correlation equation.     

Source areas contributing to the episodic acidification of a forested headwater stream

A study was initiated on the Leading Ridge Experimental Watersheds in central Pennsylvania to investigate the extent to which episodic depressions of streamwater pH result from direct channel interception of acidified rainwaters and from rapid subsurface stormflow. During a 4.78-cm rainfall event on June 6, 1986, stream pH declined from 5.93 to 5.46. Analysis of the storm hydrograph indicated that direct channel interception accounted for only 2.8% of the total stormflow volume but contributed 40% of the total increase in the concentration of H⁺. At peak flow, channel interception accounted for 5.7% of the stormflow volume and 72% of H⁺. Large increases in the height of the saturated soil zone and coinciding increases in H⁺ concentrations in soilwater were measured at a number of soilwater observation wells. These fluctuations occurred almost simultaneously with measured fluctuations in both streamflow and streamwater H⁺ concentrations, indicating direct interactions between saturated soilwater and the storm discharge. These results indicate that cathcments in which soil macropores permit rapid subsurface flow could be especially susceptible to stream acidification.