Biogenic Sulfur Gas Emissions from Soils in Eastern and Southeastern United States

Data are presented for the first systematic measurements of biogenic sulfur gas flux from the major soil orders within the eastern and southeastern United States. Sulfur flux samples were collected and analyzed on-site during the fall of 1977, spring and summer of 1978 and summer of 1979. A total of 27 sampling locales in 17 states were examined. Eight additional sites were visited in 1980.

At some locales, two to four soils were examined, providing an even broader sampling of the soil orders. Three of the locales were revisited two or three times during the course of the study to establish the influence of seasonal climatology upon the measured emission rates and chemical composition of the sulfur flux mixtures.

The sulfur gas enhancement of sulfur-free sweep air passing through dynamic emission flux chambers placed over selected sampling areas was determined by combined cryogenic enrichment sampling and wall-coated, open tubular, capillary column, cryogenic gas chromatography (WCOT/GC) using a sulfur selective, flame photometric detector (FPD).

Sulfur gas mixtures varied with soil order, ambient temperature, insolation, soil moisture, cultivation, and vegetative cover. Statistical analyses indicated strong temperature and soil order relationships for sulfur emissions from soils.

Fluxes ranged from 0.001 g to 1940 g of total sulfur as S/m²/yr. The calculated mean annual sulfur flux, weighted by soil order, was 0.03 g S/m²/yr for the study land area, or 110,872 metric tons (mT). The estimated annual average sulfur flux increased from 65 mT per 6400 km² for the land grids in the northernmost east-west grid tier to an average 1800 mT for the land grids in the southern Florida grid tiers.

This systematic sampling of major soils provides a much broader data base for estimating biogenic sulfur flux than previously reported for isolated intertidal sites, and presents the first sulfur flux estimates for inland soils which make up approximately 93% of the land of the eastern United States.     

Atmospheric Factors Influencing Daily Sulfate Concentrations in Chicago Air

Abstract

Confidence interval construction for central tendency is a problem of practical consequence for those who must analyze air contaminant data. Determination of compliance with relevant ambient air quality criteria and assessment of associated health risks depend upon quantifying the uncertainty of estimated mean pollutant concentrations. The bootstrap is a resampling technique that has been steadily gaining popularity and acceptance during the past several years. A potentially powerful application of the bootstrap is the construction of confidence intervals for any parameter of any underlying distribution. Properties of bootstrap confidence intervals were determined for samples generated from lognormal, gamma, and Weibull distributions. Bootstrap t intervals, while having smaller coverage errors than Student's t or other bootstrap methods, under-cover for small samples from skewed distributions. Therefore, we caution against using the bootstrap to construct confidence intervals for the mean without first considering the effects of sample size and skew. When sample sizes are small, one might consider using the median as an estimate of central tendency. Confidence intervals for the median are easy to construct and do not under-cover. Data collected by the Northeast States for Coordinated Air Use Management (NESCAUM) are used to illustrate application of the methods discussed.     

Change in Pulmonary Function in Children Associated with Air Pollution Episodes

Pulmonary function of approximately 200 school children in Steubenville, OH was measured before and immediately following air pollution alerts in the fall of 1978 and 1979. TSP concentrations exceeded the National Primary Ambient Air Quality 24 h standards in 1978. SO₂ exceeded the standard in 1979. The children were then reexamined in three weekly visits following each alert. Estimated mean Forced Vital Capacity (FVC) was approximately 2% lower following each alert, although the lowest means were observed one to two weeks after the episodes. Forced Expired Volume in 0.75 sec (FEV_0.75) did not change during the 1978 study, but was 4% lower immediately following the 1979 alert. The children were measured again in five weekly examinations in the spring and fall of 1980. Air pollution levels did not exceed the standards on either occasion. In the spring of 1980, estimated mean FVC and FEV_0.75 showed a decline similar to that observed following the alerts in 1978 and 1979. In the fall of 1980, there were no significant differences in the estimated mean FVC or FEV_0.75 between the examinations. A total of 335 children were tested in the four studies, including 194 who participated in more than one study. The evidence for each child from all the studies was combined in a regression analysis of pulmonary function on TSP and SO₂ average concentrations in the previous 24 h. The distribution of the individual regression coefficients was centered significantly below zero, implying a decrease in pulmonary function with increasing TSP and SO₂ concentrations. The magnitude of the median change was less than 1% of the mean FVC and FEV_0.75 over the range of TSP and SO₂ concentrations observed.     

Formaldehyde Release from Simulated Wall Panels Insulated with Urea-Formaldehyde Foam Insulation

An important potential source of formaldehyde in the home is ureaformaldehyde foam insulation (UFFI). This study measures the long-term release of formaldehyde through the interior wall of test panels foamed with commercial urea-formaldehyde insulation. The measurements, made approximately 16 mo after initial foaming, were conducted under both static and dynamic air conditions with air flow selected to simulate a typical air exchange found in houses. Estimated room concentrations based on a simple model of uniform mixing within a room and measured emission rates are presented. Measurements of formaldehyde in the air from within the UFFI cavities are also reported.     

An Assessment of the Economic Effects of Ozone on U.S. Agriculture

Past attempts to measure the economic consequences of ozone on agriculture have been based on limited plant science information. This paper reports on an economic assessment of ozone on U.S. agriculture using recent crop response data from the National Crop Loss Assessment Network (NCLAN). The results are derived from a U.S. agricultural sector model that includes major crop and livestock production as well as domestic consumption, livestock feeding and export uses. The economic effects of four hypothetical ambient ozone levels are investigated. The analysis Indicates that the benefits to society of moderate (25%) ozone reductions are approximately $1.7 billion. A 25% Increase in ozone pollution results in costs (negative benefits) of $2.1 billion. These estimates do not reflect compliance costs of achieving the ozone changes and hence are not net benefits.     

Evaluation of Selected Gaseous Halocarbons for Use in source Test Performance Audits

A repository of 38 gaseous organic compounds in compressed gas cylinders has been established by EPA. This repository was established to provide standards for source test performance audits, that is, quantitative quality assurance tests. Among these compounds are ten halogenated organic species, which are the focus of this paper.

Stability studies of all ten compounds have been performed to determine the feasibility of using them as performance audit standards. Results indicate that all of the halocarbons tested are adequately stable to be used as reliable audit standards.

Subsequent to completion of stability studies, four of the ten halocarbons were used in source test performance audits. Results are available at this time for two of the four compounds; the results show agreement within 10% of the concentrations previously established by Research Triangle Institute.     

Comparison of Statistical Designs and Experimental Protocols Used to Evaluate Rain Acidity Effects on Field-Grown Soybeans

Published results of four field experiments testing effects of acidic precipitation in field-grown soybeans have led to contradictory conclusions. This paper examines the experimental procedures and protocols of the four experiments which could have contributed to differences in both the reported crop yields and the interpretations or conclusions drawn from the experiments.

The most important difference among the experiments is in their statistical designs. Two of the field layouts used only one plot per treatment, providing replication only for plants, rows or sectors within plots, but not among plots. By using real data from a highly replicated experiment it is shown that with such deficient statistical designs treatment effects cannot be separated from other microenvironmental variables peculiar to a specific plot location.

The other two experiments were highly replicated. They were designed to detect differences of approximately 10% among treatment means. Type 1 error, a, was predetermined, and replication was sufficient to keep type 2 error low. This design was made possible because a preliminary experiment was available to estimate the expected components of variance. Despite differences in the procedures and protocols among the four experiments, it is primarily the quality of the experimental design which has determined their validity and relative utility for crop loss assessment.