Linear least squares method for time series analysis with an application to a methane time series

A simple method of time series analysis, based upon linear least squares curve fitting, is developed. The method's advantages and disadvantages are discussed, and an example is presented using the Vostok Core methane record.     

Fractionation of Cu, Pb and Zn in certified reference soils SRM 2710 and SRM 2711 using the optimized BCR sequential extraction procedure

Sequential extraction of metals from solid media is a common analytical tool used in environmental and exploration geochemistry. A number of procedures exist, but without harmonization and standardization, meaningful comparisons are tenuous without baseline data. A newly developed, standardized sequential extraction procedure (optimized BCR) was applied to two contaminated certified reference soils from Montana, US (SRM 2710 and SRM 2711) for Cu, Pb and Zn. Four operationally defined fractions were isolated, acid extractable, reducible, oxidizable, and residual (by aqua regia). Fraction-specific concentrations, percentages and recoveries for Cu, Pb and Zn were used to explore differences between the optimized BCR procedure and three other sequential extraction schemes with published data for SRM 2710 and 2711 (i.e. Tessier scheme, Geological Survey of Canada scheme and the original BCR scheme). Results indicate significant differences between the four schemes, even for schemes that are closely associated (i.e. the original and optimized BCR schemes). Order-of-magnitude fraction-specific concentration differences were observed, especially for Pb in the reducible fraction. Differences between schemes are worrisome because trends varied between metals, between fractions and between reference soils. These data reinforce the need for increased adoption of standardized sequential extraction procedures and further examination of different solid media.     

The effect of catch crops on sulphate leaching and availability of S in the succeeding crop on sandy loam soil in Denmark

Sulphate leaching losses may reduce the long-term possibility of maintaining the S supply of crops in low input farming systems. The ability of catch crops (Italian ryegrass (Lolium multiflorum Lam), winter rape (Brassica napus L.) and fodder radish (Raphanus sativus L.)) to reduce soil sulphate concentrations in autumn and make it available to a succeeding crop was investigated in 1996–1998 on sandy loam soil in Denmark. All catch crops reduced soil sulphate concentrations in the autumn compared to bare soil. Especially, the cruciferous catch crops had the ability to deplete efficiently soil sulphate levels and thus, reduce the sulphate leaching potential. The S uptake in aboveground catch crop was 8, 22 and 36 kg S per ha for ryegrass, winter rape and fodder radish, respectively. In the following spring, sulphate levels of the autumn bare soil were low in the top 0.5 m and a peak of sulphate was found at 0.75–1 m depth. In contrast, where a fodder radish catch crop had been grown, high sulphate levels were present in the top 0.5 m, but only small amounts of sulphate were found at 0.5–1.5 m depth. In spring barley (Hordeum vulgare L.), that followed catch crops, S concentrations at heading and maturity revealed that the availability of soil S increased following winter rape and fodder radish, whereas there were indications that following ryegrass, the S availability was reduced compared to bare soil. This initial study showed that catch crops have a high potential for reducing sulphate leaching and may be used to synchronise S availability with plant demand in a crop rotation.     

Uranium enrichment by the separation-nozzle process

The Science of Nature - The development of reliable manufacturing methods for commercial separation elements, the successful operation of separative stages, and extensive tests performed on plant...     

Ecoprofit-Styria-prepare Thirteen pollution prevention case studies in the Styrian industry

The paper focuses upon the organization of a federal state-funded pollution prevention project in the Styrian industry. The project includes 13 companies from the textile, pulp and paper, machine building, wood working and printed circuit board manufacturing industries, covering most of the sectors and sizes in the Styrian industry. It started in January 1994 and will last for one year. It will demonstrate the possibilities of pollution prevention and the need for further research work. This project will make use of the methods and tools that were refined in the Austrian Prepare project. As a first step, a systematic balance of all the inputs and outputs of a company is made, after which the weak points and inefficiencies of material and energy use are identified and the options for improvements, both economical and ecological, are defined. Consequently, modifications in products and production lead to a situation with less waste and emissions. The preliminary lessons from these projects are presented: as a rule, the utilities (consumption of process materials and water, cleaning, energy, preparatory and finishing steps) are treated as black boxes and usually represent a considerable optimization potential. In these areas especially there is usually a lack of information and coordination as well as a need for a systematic and comprehensive approach. Leadership in the company and creative consultants are needed for starting lasting successful pollution prevention projects.     

Integrated nutrient management and waste recycling for restoring soil fertility and productivity in Japanese mint and mustard sequence in Uttar Pradesh, India

Supplementing the nutrient requirement of crops through organic manures plays a key role in sustaining soil fertility, and crop productivity and reducing use of fossil fuels. Field experiments were conducted for 2 years at two different locations (i.e. Lucknow and Pantnagar) in Uttar Pradesh, India. The objectives of the study were to assess the herb and essential oil yields of Japanese mint (Mentha arvensis cv. Hy 77), and its nutrient accumulation under single and combined applications of organic manures and inorganic fertilizers (NPK). Changes in physical and chemical characteristics of the soils (Fluvisols, Mollisols) were also determined. Eight treatments comprising different combinations of NPK through inorganic fertilizers and farm yard manure (FYM) were compared. The distilled waste of mint after extraction of essential oil was recycled to soils in the plots to supplement the nutritional requirement of the succeeding mustard crop (Brassica juncea cv. Pusa Bold). Herb and essential oil yield of mint were significantly higher with combined application of organic and inorganic sources of nutrients as compared to single applications. Accumulation of N and P was at par under full inorganic and combined supply whereas, K accumulation was higher with the former. Soil organic C and pH after harvest of mint did not significantly differ among the treatments, but the level of mineralizable N, Olsen-P and NH₄OAc extractable K were higher in soil with integrated supply of nutrients. Significant increase in soil water stable aggregates, organic C, available NPK and microbial biomass, and decrease in soil bulk density were observed with waste recycling over fertilizer application. These benefits were reflected in the seed and stubble yield of mustard which succeeded mint. This study indicates that combined application of inorganic fertilizers with organics helps in increasing the availability of nutrients and crop yield and provides a significant effect to the succeeding crop. Similarly, recycling crop residues reduces the need for fossil fuel based fertilizer, and helps in sustaining and restoring soil fertility in terms of available nutrients and major physical and chemical characteristics of the soil.     

Non-random nectar unloading interactions between foragers and their receivers in the honeybee hive

Nectar acquisition in the honeybee Apis mellifera is a partitioned task in which foragers gather nectar and bring it to the hive, where nest mates unload via trophallaxis (i.e. mouth-to-mouth transfer) the collected food for further storage. Because forager mates exploit different feeding places simultaneously, this study addresses the question of whether nectar unloading interactions between foragers and hive-bees are established randomly, as it is commonly assumed. Two groups of foragers were trained to exploit a different scented food source for 5 days. We recorded their trophallaxes with hive-mates, marking the latter ones according to the forager group they were unloading. We found non-random probabilities for the occurrence of trophallaxes between experimental foragers and hive-bees, instead, we found that trophallactic interactions were more likely to involve groups of individuals which had formerly interacted orally. We propose that olfactory cues present in the transferred nectar promoted the observed bias, and we discuss this bias in the context of the organization of nectar acquisition: a partitioned task carried out in a decentralized insect society.     

Synthesis and structure-activity relationship of diene modified analogs of<Emphasis Type="Italic"> Matsucoccus</Emphasis> sex pheromones

The biological activity of the Matsucoccus spp. sex pheromones and diene modified analogs has been tested in forests of Israel and Portugal in order to explore the structure-activity relationship of the pine bast scale pheromone/kairomone system. The response of the adult predatory bugs, Elatophilus hebraicus and E. crassicornis and of the brown lacewing, Hemerobius stigma is more selective than that of the conspecific Matsucoccus males. The removal of the terminal methyl group from the diene terminus of both pheromones 1 and 2 eliminates all kairomonal activity but retains moderate pheromonal activity. Addition of a methyl group to the diene terminus of pheromones 1 and 2 sustains full pheromonal and kairomonal activities of the Elatophilus spp. but eliminates entirely the kairomonal activity of H. stigma. Subtle designed alterations in the structure of the diene group, typical of all Matsucoccus pheromones, change the mode of the kairomonal activity markedly.     

Biologie und Biochemie des Elements Selen

The importance of selenium as an essential trace element has progressively emerged during the last years due to the analysis of selenium deficiency diseases and to the identification and characterization of a number of selenoenzymes. Selenium is incorporated in the catalytic site of the enzymes as an integral selenocysteine residue. The pathway of selenocysteine biosynthesis and incorporation has been elucidated recently for Escherichia coli. This article presents an overview on these subjects and describes the mechanisms which confer selenocysteine specificity in the framework of protein biosynthesis. In addition, some considerations concerning the phylogeny of selenocysteine incorporation are presented and a model for the evolution of the selenocysteine pathway is proposed.