The impact of urbanization on tropical mangroves (Fortaleza,Brazil): Evidence from PAH distribution in sediments

This investigation represents the first environmental diagnosis of the distribution and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments from a tropical mangrove in Fortaleza, northeastern Brazil. Sediment cores from six sampling stations in the Cocó and Ceará Rivers were retrieved in June-July 2006 to determine 17 priority PAHs. The total PAH concentrations (Σ_PAHs) ranged from 3.04 to 2234.76 μg kg^?1(Cocó River) and from 3.34 to 1859.21 μg kg^?1 (Ceará River). These levels are higher than those of other cities with more industrial development. PAH concentrations did not reach probable effect levels (PELs). However, from 4.5 to 87.5% of individual PAH concentrations can occasionally cause adverse biological effects for aquatic organisms. The PAH molecular ratios indicate that the PAHs in the sediment core were derived mainly from petroleum, wood, and charcoal combustion (pyrogenic source), and that atmospheric deposition and urban runoff may serve as important pathways for PAH input to the sediment. Clearly, the Σ_PAHs in sediments collected in the Cocó and Ceará Rivers indicate that ongoing pollution is more severe than past pollution.     

The modelling of a hybrid combined cycle with pressurised fluidised bed combustion and CO2 capture

This study investigates the possibility of capturing CO₂ from flue gas under pressurised conditions, which could prove to be beneficial in comparison to working under atmospheric conditions. Simulations of two hybrid combined cycles with pressurised fluidised bed combustion and CO₂ capture are presented. CO₂ is captured from pressurised flue gas by means of chemical absorption after the boiler but before expansion. The results show a CO₂ capture penalty of approximately 8 percentage points (including 90% CO₂ capture rate and compression to 110 bar), which makes the efficiency for the best performing cycle 43.9%. It is 5.2 percentage points higher than the most probable alternative, i.e. using a natural gas fired combined cycle and a pulverised coal fired condensing plant separately with the same fuel split ratio. The largest part of the penalty is associated with the lower mass flow of flue gas after CO₂ capture, which leads to a decrease in work output in the expander and potential for feed water heating. The penalty caused by the regeneration of absorbent is quite low, since the high pressure permits the use of potassium carbonate, which requires less regeneration heat than for example the more commonly proposed monoethanolamine. Although the efficiencies of the cycles look promising it will be important to perform a cost estimate to be able to make a fair comparison with other systems. Such a cost estimate has not been done in this study. A significant drawback of these hybrid cycles in that respect is the complex nature of the systems that will have a negative effect on the economy.     

Public participation in environmental monitoring: A means of attaining network capability

In the Puget Sound region of the United States a task force of community volunteers using bees monitored environmental pollution. This paper discusses advantages and limitations of public involvement in the assessment of regional environmental problems, particularly with respect to biological monitoring. This approach not only yielded extensive information about pollution levels but also was very cost effective.Work supported by Cooperative Agreement CR-810035-01-0 with the U.S. Environmental Protection Agency, Environmental Research Laboratory, Corvallis, Oregon, U.S.A.     

Indoor concentrations of carbon monoxide in selected urban microenvironments

CO concentrations were measured in five kindergartens, one children's hospital and two homes for aged, practically without indoor sources, all situated in the city centre, for ten random days in winter and ten in summer. The indoor CO concentrations were the result of the distance from and the traffic density in the nearest street, of general pollution level, seasonal differences, day-to-day variations and daily cycle of air pollution, the vicinity of traffic having a dominant influence. Therefore location of institutions for sensitive population groups in old city centres within a block of houses seems to be a suitable solution as far as exposure to CO is concerned.Revised version of a paper presented as poster at the VIth World Congress on Air Quality, Paris 1983.     

Population monitoring for genetic damage induced by environmental physical and chemical agents

The short-term tests performed in vitro on different systems, from phage to human cells, or in vivo, on laboratory animals, allow only a qualitative estimate of the action of mutagenic agents, and the extrapolation of such experimental results to man may encounter many difficulties.Direct biomonitoring of populations exposed to chemicals could represent a more realistic approach for an evaluation of the hazards to man. Certain methods are still under development. Nevertheless, other ones can already by used routinely, e.g. the cytogenetic observations on peripheral blood lymphocytes and the Ames test for mutagenic substances in urine, and can provide useful suggestions how to set threshold limits for chemical substances encountered in the working environment.     

PHREATOPHYTE EVAPOTRANSPIRATION AND ITS POTENTIAL REDUCTION WITHOUT ERADICATION1

ABSTRACT: The continuous availability of ground water to riparian phreatophytic vegetation results in large evapotranspiration (ET) losses in summer. Chemical or physical eradication of this vegetation can have undesirable environmental side effects. Spraying phreatophyte foliage with a nontoxic antitranspirant (AT) may reduce transpiration without eradication. Transpiration rate per unit leaf area was similar for several phreatophyte species, but ET per unit land area of phreatophytes depneds more on stand density than species. The mean ET for saltcedar in June was 8.1 mm/day measured by Bowen ratio, compared with 7.9 mm by lysimeters. ATs and growth-retardants reduced transpiration by over 50 percent in laboratory tests where foliage was thoroughly sprayed. In the field AT sprayed by a back-pack mistblower reduced ET by 20–35 percent initially and 10 percent after a month. No ET reduction occurred when AT was sprayed by helicopter on saltcedar, because excessive droplet size and heavy salt deposits on the foliage resulted in poor spray adherence. Wax-based AT was relatively nontoxic to fish and wildlife. Dissolved oxygen could be reduced for aquatic life, but further AT dilution in streams and ponds would minimize this. Helicopter spraying may affect bird nests and egg hatchability. Although ATs significantly reduce ET, their high cost and spraying difficulties preclude current use on phreatophytes. With improvement they may economically help to conserve water in riparian areas in future years.     

EFFECTS OF SELECTED HERBICIDES ON BACTERIAL POPULATIONS IN NONTREATED AND TREATED WATER1

ABSTRACT: Bacterial populations in nontreated and herbicide-treated waters were subjected to three different herbicides. Diuron, dichlobenil, and diquat were added (100 mg/l) to water samples from two fresh water lakes and two herbicide-treated ponds. Total numbers of bacteria were monitored. Bacterial populations in fresh lake water decreased after herbicide additions; however, final populations were significantly greater than the controls. Similar observations were recorded for bacteria in dichlobenil- and diuron-treated waters. Selective enrichment is probably expressed in these experiments.     

COMPARATIVE EVALUATION OF THREE URBAN RUNOFF MODELS1

ABSTRACT: Three urban runoff models, namely, the Road Research Laboratory Model (RRLM), the Storm Water Management Model (SWMM) and the University of Cincinnati Urban Runoff Model (UCURM), were examined by comparing the model simulated hydrographs with the hydrographs measured on several instrumented urban watersheds. This comparison was done for the hydrograph peak points as well as for the entire hydrographs using such statistical measures as the correlation coefficient, the special correlation coefficient and the integral square error. The results of the study indicated that, when applying the three selected non-calibrated models on small urban catchments, the SWM model performed marginally better than the RRL model and both these models were more accurate than the UCUR model. On larger watersheds, the comparisons between the SWM model and the other two models would be likely even more favourable for the SWM model, because it has the most advanced flow routing scheme among the studied models.     

BACTERIAL RELATIONSHIPS IN STORMWATERS1

ABSTRACT: Data were developed within a three-year period for indicator bacteria and three species of bacterial pathogens following rural storm event hydrographs. The first flush concept was confirmed in all hydrographs. Bacterial density peaking occurred at or before the hydrograph peaks. FC and FS values were higher in more developed areas than the primary rural test site and their numerical ratios followed similar trends. Chlorine demand of storm waters varied between 8 and 16 mg/l and, the ozone requirement was greater than 32 mg/l in the same waters. Aftergrowth of total coliform bacteria occurred following chlorine and ozone doses of 16 mg/l and 32 mg/l respectively. Fecal coliform, fecal streptococci, Salmonella sp., and Pseudomonas sp. all were reduced to near detectable limits by the disinfectants up to 8 days. Staphylococcus sp. demonstrated a propensity to restablish their populations. Multiple regression analysis of the bacterial groups and species in storm waters suggested the fecal streptococci to have been the most useful group in evaluating bacterial storm water quality, with staphylocci have been closely related insofar as their statistical significance was concerned.