Developing environmental quality standards for various pesticides and priority pollutants for French freshwaters

The French Ministry of the Environment and Water Agencies have derived environmental quality standards following the existing French framework called SEQ-Eau, for 28 pesticides and seven priority substances listed in the Water Framework Directive. Like other existing frameworks, SEQ-Eau relies upon the use of standard toxicity test results and assessment factors. This approach made it possible to derive the desired quality standards, but due to the lack of chronic toxicity data many of the standards are only provisional. In addition, emerging issues such as endocrine disruption should be taken into account in this framework. Depending on the available data, more flexible derivation approaches, such as the statistical distribution of NOECs, are recommended for future versions of SEQ-Eau. A comparison is made using SEQ-Eau and the methodology currently being discussed in Europe to develop environmental quality standards, showing that the European approach is more conservative. Conversely, the proposed approach under the Water Framework Directive does not cover the entire range of required quality classes.     

Modelling of silica diffusion experiments with 32Si in Boom Clay

A mathematical model describing the dissolution of nuclear glass directly disposed in clay combines a first-order dissolution rate law with the diffusion of dissolved silica in clay. According to this model, the main parameters describing the long-term dissolution of the glass are etaR, the product of the diffusion accessible porosity eta and the retardation factor R, and the apparent diffusion coefficient D(app) of dissolved silica in clay. For determining the migration parameters needed for long-term predictions, four Through-Diffusion (T-D) experiments and one percolation test have been performed on undisturbed clay cores. In the Through-Diffusion experiments, the concentration decrease after injection of 32Si (radioactive labelled silica) was measured in the inlet compartment. At the end of the T-D experiments, the clay cores were cut in thin slices and the activity of labelled silica in each slice was determined. The measured activity profiles for these four clay cores are well reproducible. Since no labelled silica could be detected in the outlet compartments, the Through-Diffusion experiments are fitted by two In-Diffusion models: one model assuming linear and reversible sorption equilibrium and a second model taking into account sorption kinetics. Although the kinetic model provides better fits, due to the sufficiently long duration of the experiments, both models give approximately similar values for the fit parameters. The single percolation test leads to an apparent diffusion coefficient value about two to three times lower than those of the Through-Diffusion tests. Therefore, dissolved silica appears to be strongly retarded in Boom Clay. A retardation factor R between 100 and 300 was determined. The corresponding in situ distribution coefficient K(d) is in the range 25-75 cm(3) g(-1). The apparent diffusion coefficient of dissolved silica in Boom Clay is estimated between 2 x 10(-13) and 7 x 10(-13) m(2) s(-1). The pore diffusion coefficient is in the range from 6 x 10(-11) to 1 x 10(-10) m(2) s(-1).     

Developing Statewide Indices of Environmental, Economic, and Social Sustainability: a look at Oregon and the Oregon Benchmarks

This research develops a method to transform the Oregon Benchmarks, a set of internationally recognized quantitative indicators designed to measure a broad array of state-level trends, into indices of social, economic, and environmental sustainability. Through multiple means, an original set of 90 Oregon Benchmarks has been narrowed into a smaller set of sustainability indicators in order to gain an integrated view of statewide sustainability as well as the capacity to look at social, environmental, and economic sustainability in isolation. The three-domain sustainability indices presented here are designed both to understand the current sustainability situation and to create a useful and informative tool for state-level policy makers interested in incorporating sustainability principles into their decision making.     

Field trial experiment: Phytoremediation with Salix sp. on a dredged sediment disposal site in Flanders,Belgium

Remediation of heavy metal contamination in soil is a widespread environmental issue. Conventional remediation techniques are invasive and often too expensive, particularly if large areas of soil are contaminated. Phytoremediation is the use of plants to remediate soil and groundwater. Phytoremediation of inorganic comtaminants such as metals can be further catagorized into phytostabilization and phytoextraction. These techniques have gained an increasing amount of attention and research over the last ten years. Phytoextraction of heavy metals and periodical removal of harvestable plant parts results in a gradual decrease of pollutant levels in the top soil. Woody species such as Salix sp. (willow) do not represent the fastest phytoextraction procedure compared to uptake by herbaceous species; however, they offer the added advantage of possible reuse of the produced biomass (wood) for the production of renewable energy. Here we present the results of a field experiment conducted to evaluate the use of Salix to remediate soil contaminated with cadmium and zinc at a dredged sediment disposal site in Flanders, Belgium. © 2003 Wiley Periodicals, Inc.     

FARM INCOME AND GROUND WATER QUALITY IMPLICATIONS FROM REDUCING SURFACE WATER SEDIMENT DELWERIES1

ABSTRACT: The potential surface water and ground water quality tradeoff implications from the nonpoint source provisions of the 1987 Water Quality Act are investigated in this paper using a national linear programming model developed at Iowa State University and modified by the Economic Research Service and the Leaching Evaluation of Agricultural Chemicals (LEACH) Handbook developed by the U.S. Environmental Protection Agency. The linear programming model is used to maximize net farm revenue using optimal combinations of crop rotations and tillage practices for each region of the United States given natural resource constraints. The LEACH handbook is used to determine the relative potential for pesticides to leach below the root zone for different soil types, hydrologic conditions, pesticides used, and tillage practices. The results indicate that imposing a surface water quality erosion constraint aimed at reducing sediment concentrations results in a larger decrease in farm income than imposing a uniform 5 ton per acre per year erosion constraint. Both constraints could result in regional improvement in ground water quality in some regions of the country while decreasing ground water quality in other regions.     

Land take and food security: assessment of land take on the agricultural production in Europe

Soil is a multifunctional, non-renewable natural resource for Europe as clearly expressed in the European Union (EU) Thematic Strategy for Soil Protection (COM (2006)231). Soil carries out multiple functions, including the support of food production. Urban development and its associated land take poses a major threat to soil and could have significant effects on agricultural production. This paper aims to evaluate the potential productivity losses in European agriculture due to land-take processes between 1990 and 2006. Agricultural land take was calculated using CORINE Land Cover maps of 1990, 2000 and 2006. For 21 of the 27 EU member states, agricultural land take was computed to be 752,973 ha for 1990–2000 and 436,095 ha for 2000–2006, representing 70.8% and 53.5%, respectively, of the total EU land take for these periods. The impact of this land take on the production capabilities of the agricultural sector for the period 1990–2006 for 19 of the 21 states was estimated to be equivalent to a loss of more than six million tonnes of wheat. The paper demonstrates that Europe's intense urbanisation has a direct impact on its capability to produce food.     

Turbulent kinetic energy budgets in a model canopy: comparisons between LES and wind-tunnel experiments

A comparative study of turbulence in a wind-tunnel model canopy is performed, using Large eddy simulation (LES) and experimental data from PIV and hot-wire anemometry measurements. The model canopy is composed of thin cylindrical stalks. In the LES, these are represented using a plant-scale approach, while the scale-dependent Lagrangian dynamic model is used as subgrid-scale model. LES predictions of turbulence statistics and energy spectra are found to be in good agreement with the experimental data. Turbulent kinetic energy (TKE) budgets from the LES simulation are analyzed to provide more information absent in the measurements. Results confirm that sloshing motions at the low levels of the canopy are mainly driven by pressure fluctuations. A difference between the energy flux obtained from the energy spectrum and the SGS dissipation rate is observed, consistent with a spectral bypass mechanism in which the real spectral flux due to cascade is smaller than that implied by the energy-spectrum level, due to direct drain by the canopy.     

A Bayesian state-space formulation of dynamic occupancy models

Species occurrence and its dynamic components, extinction and colonization probabilities, are focal quantities in biogeography and metapopulation biology, and for species conservation assessments. It has been increasingly appreciated that these parameters must be estimated separately from detection probability to avoid the biases induced by non-detection error. Hence, there is now considerable theoretical and practical interest in dynamic occupancy models that contain explicit representations of metapopulation dynamics such as extinction, colonization, and turnover as well as growth rates. We describe a hierarchical parameterization of these models that is analogous to the state-space formulation of models in time series, where the model is represented by two components, one for the partially observable occupancy process and another for the observations conditional on that process. This parameterization naturally allows estimation of all parameters of the conventional approach to occupancy models, but in addition, yields great flexibility and extensibility, e.g., to modeling heterogeneity or latent structure in model parameters. We also highlight the important distinction between population and finite sample inference; the latter yields much more precise estimates for the particular sample at hand. Finite sample estimates can easily be obtained using the state-space representation of the model but are difficult to obtain under the conventional approach of likelihood-based estimation. We use R and WinBUGS to apply the model to two examples. In a standard analysis for the European Crossbill in a large Swiss monitoring program, we fit a model with year-specific parameters. Estimates of the dynamic parameters varied greatly among years, highlighting the irruptive population dynamics of that species. In the second example, we analyze route occupancy of Cerulean Warblers in the North American Breeding Bird Survey (BBS) using a model allowing for site-specific heterogeneity in model parameters. The results indicate relatively low turnover and a stable distribution of Cerulean Warblers which is in contrast to analyses of counts of individuals from the same survey that indicate important declines. This discrepancy illustrates the inertia in occupancy relative to actual abundance. Furthermore, the model reveals a declining patch survival probability, and increasing turnover, toward the edge of the range of the species, which is consistent with metapopulation perspectives on the genesis of range edges. Given detection/non-detection data, dynamic occupancy models as described here have considerable potential for the study of distributions and range dynamics.     

Modelling aggregate exposure to pesticides from dietary and crop spray sources in UK residents

Environmental Science and Pollution Research - Human exposure to pesticide mixtures can occur from the diet and other sources. Realistic exposure and risk assessments should include multiple...