Refined tunable methodology for characterization of contaminant-particle relationships in surface water

To understand contaminant transport in aquatic systems, it is essential to define the physical characteristics of the primary particulate carriers. The distribution of organic pollutants with particle-size class and particle morphology in a freshwater embayment (Hamilton Harbor, western Lake Ontario) was studied using a sequence of novel sample preparation and characterization techniques. Water samples (24 L) were fractionated according to particle-size distribution using differential cascade sedimentation and centrifugation methods. These size fractions were subsequently subjected to a physicochemical characterization using scanning transmission electron microscopy and energy-dispersive spectroscopy to identify flocs and individual colloidal particles in the size range of 1 nm to 1 mm in diameter. Analytical chemical analyses were performed to identify organic contaminants in extracts prepared from particle-size classes, including polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs). The contaminant distribution trends were very similar for all compound classes studied; contaminants were primarily associated with fractions containing particles less than 2 mum in diameter. Morphological characterization of these fractions showed the majority of the particulates to be humic fractals. The results of this study show that contaminants in aquatic systems can be preferentially associated with specific types of particle carriers, the characteristics of which can be clearly defined in terms of size and morphology.     

Relationship of work-family conflict,gender, and alcohol expectancies to alcohol use/abuse

Numerous studies have documented a positive relationship between work-family conflict and both psychological distress and somatic symptoms. Little research, however, has explored the relationship of work-family conflict to alcohol use/abuse. Consequently, this study investigated the relationship of work-family conflict to several indicators of abusive alcohol consumption. In addition, the moderating influence of gender and tension-reduction expectancies was examined. Data were obtained through household interviews with a random sample of 473 employed adults. As hypothesized, work-family conflict was positively related to abusive alcohol consumption. In addition, there was strong support for the moderating influence of tension-reduction expectancies. As anticipated, the positive relationship between work-family conflict and abusive alcohol consumption was found almost exclusively among individuals who believe that alcohol use promotes relaxation and tension reduction. In contrast, the hypothesis that gender moderates the relationship between work-family conflict and alcohol use/abuse was not supported. Implications for future research and intervention efforts aimed at reducing alcohol abuse in the workforce are discussed.     

Water resources management in small island countries Cost recovery and demand management

The concepts of cost recovery and demand management in the context of water resources for small island countries are introduced. Water pricing mechanisms which could be used to achieve the goal of cost recovery are discussed. Regulatory and economic measures, and pricing policies for limiting increases in demand ('demand management') are also presented. Examples from island countries are used to illustrate the policies discussed.     

EMPHASIS ON DISTRIBUTION: STRATEGIES FOR SMALL SCALE WATER RESOURCES DEVELOPMENT IN THAILAND1

This paper discusses strategies for the development of water resources, emphasizing the delivery of reliable water supplies, for both domestic and production purposes, to every village and to every farmer. This necessitates a shift of emphasis from the construction of large storage reservoirs to the construction, operation, and maintenance of water distribution systems capable of reaching the largest number of farms, and a shift from projects that benefit the few, to projects that benefit the many. Water distribution in this context takes on three interrelated meanings: a geographical meaning, a technical meaning, and an economic meaning. The geographical meaning focuses on the spatial distribution of the recipient population as a key to identifying the proper distribution of water projects in physical space. The technical meaning relates to the physical distribution of water through canal systems to the farmers' fields. The economic meaning refers to the equitable distribution of benefits from water projects. The paper provides an illustration of the need for an emphasis on distribution, using the state of development of water resources in northeast Thailand as an example, with a proposed program for the further development of these resources. The northeast, the poorest region in the country, has been recognized by the Government of Thailand as a priority area for accelerated regional development efforts.     

Impacts of market economy access and livelihood conditions on agro-food transition in rural communities in three macro-regions of Brazil

Environment, Development and Sustainability - Urbanization has threatened rural communities’ livelihoods worldwide, changing their agro-food systems from locally produced traditional items to...     

Prenatal diagnosis of a double heterozygote for two reciprocal translocations of familial origin

Two balanced reciprocal translocations were found in an amniotic fluid cell culture undertaken because of maternal age. One translocation had been inherited from each parent. Both translocations were traced through three generations of each family. The importance of banding techniques in diagnostic cytogenetics is stressed.     

A safety culture maturity model for petrochemical companies in Brazil

A framework to measure safety culture maturity in the Brazilian oil and gas companies was formulated based on the model of Hudson (2001). Following a review of the safety culture literature, a questionnaire was designed to measure five aspects of organisational safety indicative of five levels of cultural maturity. The questionnaire was completed by the safety managers of 23 petrochemical companies based in Camacari, Bahia, Brazil and they were interviewed one month later. The reliability of the questionnaire was tested by asking the same questions in an interview and comparing the results (alternate forms reliability). The correlation coefficients between the questionnaire and interview scores on each dimension ranged from r = 0.7 to 0.9, demonstrating good reliability of the measures used. The research findings demonstrated that the 23 companies studied showed characteristics of different levels of safety culture maturity. Most scores were at the level of proactive. The model of Hudson (2001) and the revised framework and questionnaire were found to be practical to use, making it possible to identify levels of safety culture maturity in the context of the Brazilian petrochemical industry.     

Concentrations and loadings of polybrominated diphenyl ethers in dust from low-income households in California

California residents may experience the highest polybrominated diphenyl ether (PBDE) flame retardant exposures in the United States, the nation with the highest body burdens worldwide. It is hypothesized that Californians' high exposures are due to the state's strict furniture flammability standards. Ingestion of PBDE-contaminated dust, to which children may be particularly susceptible, is a dominant exposure pathway. Low-income populations may also face disparately high exposures due to the presence of older, deteriorated or poorly manufactured furniture treated with PBDEs. We collected up to two dust samples per home (54 samples total), several days apart, from low-income California households in the urban community of Oakland (n=13 homes) and the agricultural community of Salinas (n=15 homes). We measured BDE-47, BDE-99 and BDE-100, the major constituents of the penta-PBDE flame retardant formulation commonly used in furniture. All three PBDE congeners were detected in every sample with concentrations (loadings) ranging from 185 to 126,000ng/g (621-264,000ng/m(2)), 367-220,000ng/g (1550-457,000ng/m(2)), and 84-41,100ng/g (257-85,700ng/m(2)) for BDE-47, BDE-99 and BDE-100, respectively. Median concentrations (loadings) observed in Salinas homes for BDE-47, BDE-99 and BDE-100 were 3100ng/g (10,800ng/m(2)), 5480ng/g (19,500ng/m(2)), and 1060ng/g (3810ng/m(2)), respectively, and in Oakland homes 2780ng/g (10,700ng/m(2)), 4450ng/g (19,100ng/m(2)), and 1050ng/g (4000ng/m(2)), respectively. Maximum concentrations for BDE-47 and BDE-99 are the highest reported to date. Indoor concentrations and loadings did not significantly differ between communities; concentrations and loadings were strongly correlated between collections for all three congeners (Spearman rho=0.79-0.97, p<0.002). We estimated non-dietary ingestion of each congener for one child in each home (n=28 children) and found that estimated intake for BDE-47 and BDE-99 exceeded the U.S. Environmental Protection Agency's recommended chronic reference dose for three and five children, respectively. Children's estimated intake via dust ranged from 1.0 to 599ng/kg/day, 2.0-1065ng/kg/day and 0.5-196ng/kg/day for BDE-47, BDE-99 and BDE-100, respectively. In order to mitigate these exposures, future research must address the factors that contribute to PBDE exposures in low-income homes.     

Studies on degradation of glyphosate by several oxidative chemical processes: Ozonation,photolysis and heterogeneous photocatalysis

Several different Advanced Oxidation Processes (AOPs) including ozonation at pH 6.5 and 10, photolysis and heterogeneous photocatalysis using TiO₂ as semiconductor and dissolved oxygen as electron acceptor were applied to study the degradation of glyphosate (N-phosphonomethyl glycine) in water. The degree of glyphosate degradation, the reactions kinetic and the formation of the major metabolite, aminomethyl phosphonic acid (AMPA), were evaluated. Ozonation at pH 10 resulted in the maximum mineralization of glyphosate. It was observed that under the experimental conditions used in this study the degradation of glyphosate followed the first-order kinetics. The half-life obtained for glyphosate degradation in the O₃/pH 10 process was 1.8 minutes.     

Psychoactive drugs: occurrence in aquatic environment,analytical methods,and ecotoxicity—a review

This review focused on seven psychoactive drugs being six benzodiazepines (alprazolam, bromazepam, clonazepam, diazepam, lorazepam, and oxazepam) and one antidepressant (citalopram) widely consumed by modern society and detected in different aqueous matrices (drinking water, surface water, groundwater, seawater, estuary water, influent and effluent of wastewater treatment plants). The review included 219 selected scientific papers from which 1642 data/entries were obtained, each entry corresponding to one target compound in one aqueous matrix. Concentrations of all investigated drugs in all aqueous matrices varied from 0.14 to 840,000 ng L^?1. Citalopram presented the highest concentrations in the aqueous matrices. Based on the Wilcoxon-Mann-Whitney test, differences between wastewater influents and effluents were not significant for most wastewater categories, suggesting that conventional wastewater treatment systems as such do not remove or remove partially these compounds. High-income countries showed much lower concentrations in surface water than the group formed by upper-middle-, lower-middle-, and low-income countries. Regarding analytical methods, solid-phase extraction (SPE) was by far the most used extraction method (83%) and performance liquid chromatography (HPLC) (73%) coupled to mass spectrometry (99%) the most common analytical method. Changes in behavior and in survival rates were the most common effects reported on bioindicators (aquatic species) due to the presence of these drugs in water. Concentrations of psychoactive drugs found in surface waters were most of the time within the range that caused measurable toxic effects in ecotoxicity assays.