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211.
Retention of arsenic on hydrous ferric oxides generated by electrochemical peroxidation 总被引:4,自引:0,他引:4
Electrochemical peroxidation (ECP), an emerging remediation technology, with direct electric current applied to steel electrode and small addition of H2O2, was used to remove As(III) from contaminated aqueous solutions. Bench scale experiments were conducted to evaluate the sorption and distribution of arsenic between the soluble and solid state hydrous ferric oxides (HFO) formed as part of the ECP process. ECP was effective in removing arsenic from the aqueous solution, with >98% of the applied As(III) adsorbed on HFO. Removal was complete within 3 min of ECP treatment and apparently independent of the initial pH of the water (3.5-9.5). In the absence of H2O2 more As(III) was adsorbed by solid state iron at pH 9.5 than at 3.5 (2600 vs. 1750 microg l(-1)). Thus H2O2 was crucial to oxidize As(III) to As(V) which is more strongly retained by HFO. Removal of As was not significantly affected by the concentration of H2O2 or by current processing time. The optimal operating conditions were pH < 6.5, H2O2 concentration of 10 mg l(-1) and current process time not exceeding 3 min. X-ray diffraction (XRD), diffuse-reflectance infrared Fourier transform (DRIFT) spectroscopy and transmission electron microscopy (TEM) were applied to study the HFO deposits. The XRD data indicated the prevalence of poorly ordered Fe minerals in the suspended ECP solids with a dominance of 5 line ferrihydrite in the absence of H2O2. At pH 3.5 and with 100 mg H2O2 l(-1), akaganeite was formed, whereas an incipient hematitic phase, reflection at 0.39 nm, occurred at pH 6.5. DRIFT data indicate that both As(III) and As(V) were specifically adsorbed onto HFO at acid and neutral pH. TEM observations indicated the presence of spherical shape ferrihydrite and provided evidence for possible formation of subrounded hematite and acicular shape goethite. 相似文献
212.
Distribution of endocrine disruptors in the Llobregat River basin (Catalonia, NE Spain) 总被引:9,自引:0,他引:9
The Llobregat basin is a Mediterranean fluvial system with major agricultural, urban and industrial impacts. We combined chemical quantification by liquid chromatography–mass spectrometry with electrospray interface (LC-ESI-MS) and the recombinant yeast assay (RYA) assays to estimate the loads of endocrine disrupting compounds (EDCs) along the basin. Chemical analysis revealed maximum concentrations (at μg l−1 level) of alkylphenols at the lower course of the Llobregat River, which correlated with high levels of estrogenic activity detected by RYA. Analysis by RYA and LC-ESI-MS of influent and effluent waters from four sewage treatment plants (STP) discharging into the basin showed the removal of 80–95% of EDCs by STP treatment. Chemical analysis data and RYA data showed a quasi-linear correlation, demonstrating the complementariness of both methods. Our data suggest that the concentrations of the analysed compounds were enough to explain the total estrogenicity of water and STP samples from the Llobregat basin. 相似文献
213.
Mart-Jan Schelhaas Geerten Hengeveld Marco Moriondo Gert Jan Reinds Zbigniew W. Kundzewicz Herbert ter Maat Marco Bindi 《Mitigation and Adaptation Strategies for Global Change》2010,15(7):681-701
Risks can generally be described as the combination of hazard, exposure and vulnerability. Using this framework, we evaluated
the historical and future development of risk of fire and wind damage in European forestry at the national level. Fire risk
is expected to increase, mainly as a consequence of an increase in fire hazard, defined as the Fire Weather Index in summer.
Exposure, defined as forest area, is expected to increase slightly as a consequence of active afforestation and abandonment
of marginal agricultural areas. Adaptation options to fire risk should therefore aim to decrease the vulnerability, where
a change in tree species from conifers to broadleaves had most effect. Risk for wind damage in forests is expected to increase
mainly as a consequence of increase in exposure (total growing stock) and vulnerability (defined by age class and tree species
distribution). Projections of future wind climate indicate an increase in hazard (storminess) mainly over Western Europe.
Adaptation options should aim to limit the increase in exposure and vulnerability. Only an increase in harvest level can stop
the current build-up of growing stock, while at the same time it will lower vulnerability through the reduction of the share
of old and vulnerable stands. Changing species from conifers to broadleaves helps to reduce vulnerability as well. Lowering
vulnerability by decreasing the rotation length is only effective in combination with a high demand for wood. Due to data
limitations, no forecast of future fire area or damaged timber amount by storms was possible. 相似文献
214.
Alberto?Sanz-CobenaEmail author Diego?Abalos Ana?Meijide Laura?Sanchez-Martin Antonio?Vallejo 《Mitigation and Adaptation Strategies for Global Change》2016,21(7):1131-1144
Among the mitigation strategies to prevent nitrogen (N) losses from ureic fertilizers, urease inhibitors (UIs) have been demonstrated to promote high N use efficiency by reducing ammonia (NH3) volatilization. In the last few years, some field experiments have also shown its effectiveness in reducing nitrous oxide (N2O) losses from fertilized soils under conditions of low soil moisture. An incubation experiment was carried out with the aim of assessing the main biotic mechanisms behind N2O emissions once that the UIs N-(n-butyl) thiophosphoric triamid (NBPT) and phenil phosphorodiamidate (PPDA) were applied with Urea (U) under different soil moisture conditions (40, 60 and 80 % water-filled pore space, WFPS). In the same study we tried to analyze to what extent soil WFPS regulates the effect of these inhibitors on N2O emissions. The use of PPDA in our study allowed us to compare the effect of NBPT with that of another commercially available urease inhibitor, aiming to see if the results were inhibitor-specific or not. Based on the results from this experiment, a WFPS (i.e. 60 %) was chosen for a second study (i.e. mesocosm experiment) aiming to assess the efficiency of the UIs to indirectly affect N2O emissions through influencing the pool of soil mineral N. The N2O emissions at 40 % WFPS were almost negligible, being significantly lower from all fertilized treatments than that produced at 60 and 80 % WFPS. When compared to U alone, NBPT+U reduced the N2O emissions at 60 % WFPS but had no effect at 80 % WFPS. The application of PPDA significantly increased the emissions with respect to U at 80 % WFPS whereas no significant effect was found at 60 %. At 80 % WFPS, denitrification was the main source of N2O emissions for all treatments. In the mesocosm study, the application of NBPT+U was an effective strategy to reduce N2O emissions (75 % reduction compared to U alone), due to a lower soil ammonium (NH4 +) content induced by the inhibitor. These results suggest that adequate management of the UI NBPT could provide, under certain soil conditions, an opportunity for mitigation of N2O emissions from fertilized soils. 相似文献
215.
Eullia Planas-Cuchi Juan Antonio Vílchez Joaquim Casal 《Journal of Loss Prevention in the Process Industries》1999,12(6):453-483
Loading and unloading operations produce 8% of all accidents which occur in process plants and in the transportation of hazardous materials. A survey of 738 accidents was performed, allowing the identification of the accident type distribution and of their cause. Some considerations on flammable mixtures are also presented, and the procedures to avoid these mixtures occurring when filling or emptying a tank are briefly discussed. 相似文献
216.
Lucas Ferrante Augusto Getirana Fabricio Beggiato Baccaro Jochen Schöngart Ana Cristina Monteiro Leonel Renato Gaiga Michel Varajão Garey Philip Martin Fearnside 《Conservation biology》2023,37(3):e14033
Given the speed at which humans are changing the climate, species with high degrees of endemism may not have time to avoid extinction through adaptation. We investigated through teleconnection analysis the origin of rainfall that determines the phylogenetic diversity of rainforest frogs and the effects of microclimate differences in shaping the morphological traits of isolated populations (which contribute to greater phylogenetic diversity and speciation). We also investigated through teleconnection analysis how deforestation in Amazonia can affect ecosystem services that are fundamental to maintaining the climate of the Atlantic rainforest biodiversity hotspot. Seasonal winds known as flying rivers carry water vapor from Amazonia to the Atlantic Forest, and the breaking of this ecosystem service could lead Atlantic Forest species to population decline and extinction in the short term. Our results suggest that the selection of morphological traits that shape Atlantic Forest frog diversity and their population dynamics are influenced by the Amazonian flying rivers. Our results also suggest that the increases of temperature anomalies in the Atlantic Ocean due to global warming and in the Amazon forest due to deforestation are already breaking this cycle and threaten the biodiversity of the Atlantic Forest hotspot. 相似文献
217.
Marco Dellavedova Lucia Gigante Angelo Lunghi Christian Pasturenzi Paolo Cardillo Niccolò P. Gerosa Renato Rota 《Journal of Loss Prevention in the Process Industries》2010,23(4):515-521
Nowadays many chemical industries are SMEs where multi-purpose batch or semi-batch reactors are commonly used. Vent sizing for realistic runaway scenario is not an easy task for such enterprises since they have usually few resources and use multi-purpose reactors with fast process turnovers. As a consequence these batch and semi-batch reactors are usually equipped with emergency relief systems sized once forever when the reactor is designed. This can lead to a large underestimation of the vent area in case of runaway reactions occurring when processes different from the ones considered for originally sizing the vent are carried out.The approach proposed in this work aims to identify the maximum reactor load leading to safe conditions even in case of runaway phenomena to be handled with the emergency relief system already installed (or even with a smaller vent area). This approach allows avoiding the change of the emergency relief system with a larger vent area (as required every time a new more hazardous process has to be carried out on existing reactors) at the price of lower plant productivity. 相似文献
218.
Spatial Relationships of Levees and Wetland Systems within Floodplains of the Wabash Basin,USA
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Ryan R. Morrison Erin Bray Fernando Nardi Antonio Annis Quan Dong 《Journal of the American Water Resources Association》2018,54(4):934-948
Given the unique biogeochemical, physical, and hydrologic services provided by floodplain wetlands, proper management of river systems should include an understanding of how floodplain modifications influence wetland ecosystems. The construction of levees can reduce river–floodplain connectivity, yet it is unclear how levees affect wetlands within floodplains, let alone the cumulative impacts within an entire watershed. This paper explores spatial relationships between levee and floodplain wetland systems in the Wabash Basin, United States. We used a hydrogeomorphic floodplain delineation technique to map floodplain extents and identify wetlands that may be hydrologically connected to river networks. We then spatially examined the relationship between levee presence, wetland area, and other river network attributes within discrete subbasins. Our results show that cumulative wetland area is relatively constant in subbasins that contain levees, regardless of maximum stream order within the subbasin. In subbasins that do not contain levees, cumulative wetland area increases with maximum stream order. However, we found that wetland distributions around levees can be complex, and further studies on the influence of levees on wetland habitat may need to consider finer resolution spatial scales. 相似文献
219.
Pironti Concetta Ricciardi Maria Motta Oriana Venier Marta Faggiano Antonio Cucciniello Raffaele Proto Antonio 《Environmental science and pollution research international》2023,30(2):3112-3120
Environmental Science and Pollution Research - Thermo-mineral springs are widely spread over the volcanic areas of Salerno, a city in southern Italy. Although the water of thermal structures... 相似文献
220.
Rolim Silvia Beatriz Alves Veettil Bijeesh Kozhikkodan Vieiro Antonio Pedro Kessler Anita Baldissera Gonzatti Clóvis 《Environmental science and pollution research international》2023,30(8):19602-19616
Environmental Science and Pollution Research - A large number of freshwater lakes around the world show recurring harmful algal blooms, particularly cyanobacterial blooms, that affect public health... 相似文献