全文获取类型
收费全文 | 1284篇 |
免费 | 15篇 |
国内免费 | 15篇 |
专业分类
安全科学 | 32篇 |
废物处理 | 75篇 |
环保管理 | 122篇 |
综合类 | 191篇 |
基础理论 | 255篇 |
污染及防治 | 432篇 |
评价与监测 | 117篇 |
社会与环境 | 85篇 |
灾害及防治 | 5篇 |
出版年
2023年 | 20篇 |
2022年 | 42篇 |
2021年 | 31篇 |
2020年 | 22篇 |
2019年 | 19篇 |
2018年 | 45篇 |
2017年 | 48篇 |
2016年 | 64篇 |
2015年 | 38篇 |
2014年 | 76篇 |
2013年 | 123篇 |
2012年 | 93篇 |
2011年 | 112篇 |
2010年 | 64篇 |
2009年 | 71篇 |
2008年 | 82篇 |
2007年 | 67篇 |
2006年 | 59篇 |
2005年 | 62篇 |
2004年 | 36篇 |
2003年 | 39篇 |
2002年 | 17篇 |
2001年 | 14篇 |
2000年 | 12篇 |
1999年 | 4篇 |
1998年 | 4篇 |
1997年 | 5篇 |
1996年 | 7篇 |
1995年 | 2篇 |
1994年 | 6篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1986年 | 3篇 |
1982年 | 1篇 |
1978年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1954年 | 1篇 |
排序方式: 共有1314条查询结果,搜索用时 15 毫秒
81.
Fabjola Bilo Laura Borgese Davide Cazzago Annalisa Zacco Elza Bontempi Rita Guarneri Marco Bernardello Silvia Attuati Pranvera Lazo Laura E. Depero 《Environmental science and pollution research international》2014,21(23):13208-13214
Total reflection x-ray fluorescence spectroscopy (TXRF) is proposed for the elemental chemical analysis of crustal environmental samples, such as sediments and soils. A comparative study of TXRF with respect to flame atomic absorption spectroscopy and inductively coupled plasma optical emission spectroscopy was performed. Microwave acid digestion and suspension preparation methods are evaluated. A good agreement was found among the results obtained with different spectroscopic techniques and sample preparation methods for Cr, Mn, Fe, Ni, Cu, and Zn. We demonstrated that TXRF is suitable for the assessment of environmental contamination phenomena, even if the errors for Pb, As, V, and Ba are ingent. 相似文献
82.
Cristina Barazzetti Barbieri Jorge Eduardo Souza Sarkis Luiz Antonio Martinelli Isabella C. A. C. Bordon Horst Mitteregger Jr. Marcos Antônio Hortellani 《Environmental Forensics》2014,15(2):134-146
A forensic approach was used to evaluate sediments from Portão Stream, including analysis of metals, carbon (C) and nitrogen (N) stable isotopes, and C:N ratios. Samples collected at various points located along the stream were tested in order to investigate a possible illegal leachate input. The studied stream is heavily impacted by sewage and industrial discharges from two cities along its course. Among the metals analyzed, chromium (Cr) was noticeably the main pollutant, showing the highest levels, above regulatory limits, downstream from some potential sources of effluents enriched with this metal. Isotope analyses revealed a general trend of depletion in the heavier isotope along the stream for C and N. The exception was one point near a hazardous waste landfill, where relatively more enriched δ13C and δ15N values were found. The isotope and metal analysis results indicated that this site was affected by a particular source, demonstrating the combination of these parameters could be used for the discrimination of sources in a heavily polluted stream. Nevertheless, further investigations are necessary to provide a comprehensive evaluation of the biogeochemical processes involved in the incorporation of leachate in sediments to use this analysis as evidence for the illegal leachate discharge. 相似文献
83.
Degree of phosphorus saturation of an Oxisol amended with biosolids in a long-term field experiment 总被引:1,自引:0,他引:1
Luís Reynaldo Ferracciú Alleoni Antonio Rodrigues Fernandes Murilo de Campos 《Environmental science and pollution research international》2014,21(8):5511-5520
When applied to agricultural soils, phosphate fertilizers and the mineral or organic compounds present in solid and/or liquid waste may raise phosphorus (P) content and increase soil P saturation. The degree of phosphorus saturation (DPS) is a good indicator of potential P loss from agricultural soils. The purpose of this study was to calculate the DPS of samples from an Oxisol amended for 5 years with biosolids and mineral fertilizer. DPS was calculated based on P, iron, and aluminum extracted by ammonium oxalate and oxalic acid (DPSox) or by Mehlich-1 solution (DPSM1). Treatments included NPK mineral fertilization (175 kg ha?1 of P), B1?=?19.02 t ha?1 of biosolids (350 kg ha?1 of P), B2?=?38.17 t ha?1 of biosolids (703 kg ha?1 of P), B3?=?76.26 t ha–1 of biosolids (1,405 kg ha?1 of P), and a control (no P added). Water-extractable P (WEP) was also measured. Critical levels of DPSox and DPSM1 (21 and 24 %, respectively) were only achieved in the topsoil (0–0.1 m) at the highest biosolid dose. Concentration of WEP was positively correlated to DPSox and DPSM1. The DPSM1 method may be an alternative to DPSox for assessing the environmental risk of P loss from soil into surface runoff. 相似文献
84.
Ignasi Sirés Enric Brillas Mehmet A. Oturan Manuel A. Rodrigo Marco Panizza 《Environmental science and pollution research international》2014,21(14):8336-8367
In recent years, new advanced oxidation processes based on the electrochemical technology, the so-called electrochemical advanced oxidation processes (EAOPs), have been developed for the prevention and remediation of environmental pollution, especially focusing on water streams. These methods are based on the electrochemical generation of a very powerful oxidizing agent, such as the hydroxyl radical (?OH) in solution, which is then able to destroy organics up to their mineralization. EAOPs include heterogeneous processes like anodic oxidation and photoelectrocatalysis methods, in which ?OH are generated at the anode surface either electrochemically or photochemically, and homogeneous processes like electro-Fenton, photoelectro-Fenton, and sonoelectrolysis, in which ?OH are produced in the bulk solution. This paper presents a general overview of the application of EAOPs on the removal of aqueous organic pollutants, first reviewing the most recent works and then looking to the future. A global perspective on the fundamentals and experimental setups is offered, and laboratory-scale and pilot-scale experiments are examined and discussed. 相似文献
85.
Antonio C. Caputo Pacifico M. Pelagagge 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1362-1367
ABSTRACT This is the second part of a two-part paper dealing with the preliminary design and costing of polyfunctional waste treatment plants. In this article, we present some criteria for estimating capital investment and annual operating costs of polyfunctional plants for industrial waste treatment. The process and equipment design methods presented in Part I of this article, together with the economic approach proposed here, allow for complete technical/economic analyses. The overall mathematical model appears to be a useful tool in economic feasibility studies. The accuracy of the developed computer mathematical model has been demonstrated, referring to actual cost data from the literature. 相似文献
86.
Antonio C. Caputo Pacifico M. Pelagagge 《Journal of the Air & Waste Management Association (1995)》2013,63(12):1456-1462
ABSTRACT Cost-effectiveness of different plant solutions for glass furnace waste gas cleaning is compared in the present paper. Plant arrangements based on electrostatic precipi-tator or fabric filter dust collectors and wet, semi-dry, or dry processes for acid gas removal have been considered. A critical survey of each solution's advantages and disadvantages has been presented, taking into account both effectiveness and costs resulting from each available system. Finally, a quantitative assessment has been provided with reference to a case study involving actual float glass production lines at SIV plants located in northern and central Italy. 相似文献
87.
Antonio C. Caputo Pacifico M. Pelagagge 《Journal of the Air & Waste Management Association (1995)》2013,63(7):1009-1020
ABSTRACT Glass manufacturing, like other process industries, is faced with air pollution compliance problems due to ever stricter emission limits. Several waste gas cleaning equipment options are available for air pollution control (APC) in glass plants, the most common arrangements being based on electrostatic precipitator (ESP) or fabric filter (FF) dust collectors and semi-wet or dry processes for acid gas removal. However, several counteracting aspects affect the choice of gas cleaning technologies, which are confirmed by the discrepancies encountered in actual suppliers' bids. In this paper, the main pollution control options are analyzed by carrying out a critical comparison under the cost-effectiveness point of view to select the lowest cost arrangement considering capital investment, operating expenses, and energy-saving revenues from heat recovery processes. The analysis is carried out with reference to a case study involving actual float glass production lines at Pilkington plants in Italy. 相似文献
88.
William C. Malm Bret A. Schichtel Michael G. Barna Kristi A. Gebhart Marco A. Rodriguez Jeffrey L. Collett Jr. 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1245-1263
Changes in ecosystem function at Rocky Mountain National Park (RMNP) are occurring because of emissions of nitrogen and sulfate species along the Front Range of the Colorado Rocky Mountains, as well as sources farther east and west. The nitrogen compounds include both oxidized and reduced nitrogen. A year-long monitoring program of various oxidized and reduced nitrogen species was initiated to better understand their origins as well as the complex chemistry occurring during transport from source to receptor. Specifically, the goals of the study were to characterize the atmospheric concentrations of nitrogen species in gaseous, particulate, and aqueous phases (precipitation and clouds) along the east and west sides of the Continental Divide; identify the relative contributions to atmospheric nitrogen species in RMNP from within and outside of the state of Colorado; identify the relative contributions to atmospheric nitrogen species in RMNP from emission sources along the Colorado Front Range versus other areas within Colorado; and identify the relative contributions to atmospheric nitrogen species from mobile sources, agricultural activities, and large and small point sources within the state of Colorado. Measured ammonia concentrations are combined with modeled releases of conservative tracers from ammonia source regions around the United States to apportion ammonia to its respective sources, using receptor modeling tools.
Implications: Increased deposition of nitrogen in RMNP has been demonstrated to contribute to a number of important ecosystem changes. The rate of deposition of nitrogen compounds in RMNP has crossed a crucial threshold called the “critical load.” This means that changes are occurring to park ecosystems and that these changes may soon reach a point where they are difficult or impossible to reverse. Several key issues need attention to develop an effective strategy for protecting park resources from adverse impacts of elevated nitrogen deposition. These include determining the importance of previously unquantified nitrogen inputs within the park and identification of important nitrogen sources and transport pathways. 相似文献
89.
Nutrient leaching in highly weathered tropical soils often poses a challenge for crop production. We investigated the effects of applying 20 t ha biochar (BC) to a Colombian savanna Oxisol on soil hydrology and nutrient leaching in field experiments. Measurements were made over the third and fourth years after a single BC application. Nutrient contents in the soil solution were measured under one maize and one soybean crop each year that were routinely fertilized with mineral fertilizers. Leaching by unsaturated water flux was calculated using soil solution sampled with suction cup lysimeters and water flux estimates generated by the model HYDRUS 1-D. No significant difference ( > 0.05) was observed in surface-saturated hydraulic conductivity or soil water retention curves, resulting in no relevant changes in water percolation after BC additions in the studied soils. However, due to differences in soil solution concentrations, leaching of inorganic N, Ca, Mg, and K measured up to a depth of 0.6 m increased ( < 0.05), whereas P leaching decreased, and leaching of all nutrients (except P) at a depth of 1.2 m was significantly reduced with BC application. Changes in leaching at 2.0 m depth with BC additions were about one order of magnitude lower than at other depths, except for P. Biochar applications increased soil solution concentrations and downward movement of nutrients in the root zone and decreased leaching of Ca, Mg, and Sr at 1.2 m, possibly by a combination of retention and crop nutrient uptake. 相似文献
90.
Suciu NA Ferrari T Ferrari F Trevisan M Capri E 《Environmental science and pollution research international》2012,19(4):1229-1236