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851.
Luis Cardona Mónica Revelles Mari Luz Parga Jesús Tomás Alex Aguilar Ferran Alegre Antonio Raga Xavier Ferrer 《Marine Biology》2009,156(12):2621-2630
Previous studies of loggerhead sea turtles have concluded that drifting longlines were the main threat for immature specimens
in the western Mediterranean, because immature loggerhead sea turtles mainly inhabit oceanic waters. However, recent aerial
surveys have revealed large numbers of immature loggerhead sea turtles over the continental shelf of eastern mainland Spain,
where turtles are exposed to neritic fishing gears but not to drifting longlines. We satellite-tracked seven loggerhead sea
turtles (minimum straight carapace length (SCLmin) range: 36.5–55.0 cm) to assess whether the turtles in this region are vagrants
from the adjoining oceanic regions or whether these loggerheads mostly inhabit the continental shelf. Satellite-tracking revealed
that six of the tagged turtles avoided the oceanic realm and made extended use of the continental shelf, whereas only one
individual could be considered a true vagrant as it avoided the continental shelf and primarily used the oceanic habitat.
These results are in sharp contrast with those previously reported for immature loggerhead sea turtles of similar size from
the south-western Mediterranean and fit well a relaxed ontogenic model that was recently proposed for loggerhead sea turtles
in the central Mediterranean. Furthermore, these results demonstrate the vulnerability of loggerhead sea turtles of eastern
mainland Spain to neritic fishing gears, as three of the seven turtles died and one was bycaught incidentally while being
tracked over the continental shelf. 相似文献
852.
Isabella Lancellotti Elie Kamseu Marco Michelazzi Luisa Barbieri Anna Corradi Cristina Leonelli 《Waste management (New York, N.Y.)》2010,30(4):673-679
Municipal solid waste incinerators every year produce tons of fly ashes which, differently from coal fly ashes, contain large amounts of toxic substances (heavy metals, dioxins, furans). The stabilization/solidification (S/S) technology known as geopolymerization is proposed with the purpose to bond physically and chemically incinerator fly ashes (IFA) in a solid matrix, in order to reduce pollutant mobility. The chemical stability of geopolymers with Si/Al ratio of 1.8–1.9 and Na/Al ratio of 1.0, synthesized by alkali activation of metakaolin and the addition of 20 wt% of two different kinds of IFA, is presented. The concentration of the alkaline solution, water to solid ratio and curing process have been optimized. The room temperature consolidation of IFA containing geopolymers has been tested for leachability in water for 1 day, accordingly to EN 12457 regulation and extended to 7 days to increase the water attack on solid granules. Leachable metals in the test solution, determined by ICP_AES, fall within limit values set by regulation for non-dangerous waste landfill disposal. Geopolymeric matrix evolution with leaching time has been also evaluated in terms of pH and electrical conductivity increase in solution. 相似文献
853.
854.
855.
Alexandre M. Martin Hélène Presseault-Gauvin Marco Festa-Bianchet Fanie Pelletier 《Behavioral ecology and sociobiology》2013,67(6):919-928
In males, the acquisition and development of behavioral and morphological secondary sexual traits typically depends on testosterone and correlates with mating success. Testosterone level could affect competition for mates and thus be a target of sexual selection. We sought to relate testosterone levels to male mating competitiveness, by teasing apart the relationships between testosterone, behavior, and growth before the mating period. We monitored 24 adult bighorn rams (Ovis canadensis) at Ram Mountain, Alberta, from 2008 to 2011. Using linear mixed models, we tested the relationships between testosterone metabolites in feces, social rank, and both growth and size of two sexually selected traits: horns and body mass. The correlation between testosterone and social rank varied with age. Testosterone and rank were weakly and negatively correlated for young rams, positively correlated for prime-aged rams, and negatively correlated for older rams. Although testosterone had an increasingly positive effect on total horn length until 8 years of age, we could not detect any effects on annual growth rate of horns or body mass. Testosterone may be related to male’s ability to compete for mates through its relationship with behaviors determining social rank, rather than by influencing the development of morphological traits. Differences in testosterone levels among competitors may be a proximate cause of variance in fitness. 相似文献
856.
Pâmela C. Oliveira Elizabete M. Maximiano Poliane A. Oliveira Junior S. Camargo Antonio R. Fiorucci 《Journal of environmental science and health. Part. B》2013,48(12):817-823
AbstractThis paper describes a simple, inexpensive, highly sensitive, selective, and efficient electrochemical method to determine glyphosate (GLY) in samples of milk, orange juice, and agricultural formulation. The oxidation reaction on the electrode surface was electrochemically characterised by cyclic voltammetry (CV) and square wave voltammetry (SWV). The investigation of GLY at carbon paste electrode revealed a non-reversible oxidation peak at +0.95 V versus Ag/AgCl, which was used for electrochemical detection of GLY. The operating parameters (pH, frequency, step potential, and amplitude) were optimised in relation to the peak current intensity, and a calibration curve was set up in a concentration range of 4.40?×?10?8–2.80?×?10?6 mol L?1, with a detection limit of 2?×?10?9 mol L?1. After calibration curve was plotted, the developed procedure was applied to determine GLY in previously contaminated samples: milk and orange juice, and in a commercial formulation, obtaining recovery values between 98.31% and 103.75%. These results show that the proposed method can be used for GLY quantification in different samples with high sensitivity, specificity, stability, and reproducibility. 相似文献
857.
858.
Amir E Azar Hosni Ghedira Peter Romanov Shayesteh Mahani Marco Tedesco Reza Khanbilvardi 《Journal of the American Water Resources Association》2008,44(6):1347-1362
Abstract: Flood forecast and water resource management requires reliable estimates of snow pack properties [snow depth and snow water equivalent (SWE)]. This study focuses on application of satellite microwave images to estimate the spatial distribution of snow depth and SWE over the Great Lakes area. To estimate SWE, we have proposed the algorithm which uses microwave brightness temperatures (Tb) measured by the Special Sensor Microwave Imager (SSM/I) radiometer along with information on the Normalized Difference Vegetation Index (NDVI). The algorithm was developed and tested over 19 test sites characterized by different seasonal average snow depth and land cover type. Three spectral signatures derived from SSM/I data, namely T19V‐T37V (GTV), T19H‐T37H (GTH), and T22V‐T85V (SSI), were examined for correlation with the snow depth and SWE. To avoid melting snow conditions, we have used observations taken only during the period from December 1‐February 28. It was found that GTH, and GTV exhibit similar correlation with the snow depth/SWE and are most should be used over deep snowpack. In the same time, SSI is more sensitive to snow depth variations over a shallow snow pack. To account for the effect of dense forests on the scattering signal of snow we established the slope of the regression line between GTV and the snow depth as a function of NDVI. The accuracy of the new technique was evaluated through its comparison with ground‐based measurements and with results of SWE analysis prepared by the National Operational Hydrological Remote Sensing Center (NOHRSC) of the National Weather Service. The proposed algorithm was found to be superior to previously developed global microwave SWE retrieval techniques. 相似文献
859.
Total mercury contents from both abiotic and biological compartments within several estuaries from Argentina have been studied since the 1980s. The assessment of mercury occurrence in surface sediments, suspended particulate matter and crab and fish species from Mar Chiquita coastal lagoon, Bahía Blanca estuary and Samborombón Bay (in La Plata river estuary) are included in the present study. All samples were analyzed through Cold Vapor-Atomic Absorption Spectroscopy, following internationally standardized methods. In all cases analytical quality was checked against international reference materials. During the 1980s, Hg contents in sediments and SPM, as well as in edible fish species from Bahía Blanca estuary were significantly higher (p<0.01) than those of the 1990s and 2000s, and the large industrial nucleus located in the northern margin of this estuary was elsewhere identified as the main source of this metal. A permanent monitoring program carried out in 1986 and that is being implemented up to the present has demonstrated that Hg concentration values have significantly decreased (p<0.01) compared to the values of the 1980s. Both, Mar Chiquita coastal lagoon and Samborombón Bay have intermediate mercury levels in their biological compartments. In both cases, the possible occurrence of remote sources of this metal was considered. Even though, Hg values as determined in sediments and suspended particulate matter from Samborombón Bay were the highest ones for the whole analyzed period. Both mercury bioaccumulation and biomagnification processes were evaluated in the studied estuaries, as well as the potential qualification of estuarine foodstuffs for human consumption. 相似文献
860.
Flox C Cabot PL Centellas F Garrido JA Rodríguez RM Arias C Brillas E 《Chemosphere》2006,64(6):892-902
The anodic oxidation of 1.8l of solutions with mecoprop (2-(4-chloro-2-methylphenoxy)-propionic acid or MCPP) up to 0.64 g l(-1) in Na2SO4 as background electrolyte within the pH range 2.0-12.0 has been studied using a flow plant containing a one-compartment filter-press electrolytic reactor with a boron-doped diamond (BDD) anode and a stainless steel cathode, both of 20-cm2 area. Electrolyses carried out in batch under steady conditions and operating at constant current density between 50 and 150 mA cm(-2) always yield complete mineralization due to the great concentration of hydroxyl radical generated at the BDD anode. The degradation rate is practically independent of pH and Na2SO4 concentration, but it becomes faster with increasing MCPP concentration, current density, temperature and liquid flow rate. The effect of these parameters on current efficiency and energy cost has also been investigated. Generated weak oxidants such as H2O2 and peroxodisulfate ion have little influence on the mineralization process. The kinetics for the herbicide decay follows a pseudo first-order reaction with a higher rate constant when current density increases. Aromatic products such as 4-chloro-o-cresol, 2-methylhydroquinone and 2-methyl-p-benzoquinone, and generated carboxylic acids such as maleic, fumaric, lactic, pyruvic, tartronic, acetic and oxalic, have been identified as intermediates by chromatographic techniques. The initial chlorine is completely released in the form of chloride ion, which is slowly oxidized to Cl2 at the BDD anode. A reaction pathway for MCPP mineralization involving all products detected is proposed. 相似文献