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951.
Martínez-Lladó X Gibert O Martí V Díez S Romo J Bayona JM de Pablo J 《Environmental pollution (Barking, Essex : 1987)》2007,149(1):104-113
Sediments have long been recognised as a sink for many contaminants like polycyclic aromatic hydrocarbons (PAHs) and tributyltin (TBT), which by virtue of their nature can strongly adsorb onto sediments affecting the benthic community inhabiting them. Using geographical information systems, this study reports and combines the results of several already existing studies along Barcelona harbour in order to assess the potential ecological impacts of these contaminants on the benthos of the harbour ecosystem. Chemical analysis indicated low to moderate contents of PAHs and high contents of TBT in sediments in Barcelona harbour. Comparison against existing sediment quality guidelines (SQGs) indicated that acutely toxic effects would not be expected for PAHs but for TBT, which represents a serious environmental threat for the benthic community. Benthos surveys revealed a deterioration of the benthic community throughout the harbour, especially in the inner port. 相似文献
952.
Branco V Vale C Canário J Santos MN 《Environmental pollution (Barking, Essex : 1987)》2007,150(3):373-380
Muscle, liver and stomach contents of 64 blue sharks and 52 swordfishes, caught between September 2004 and February 2005 near the Azores (area A) and the Equator (area E), were analysed for mercury and selenium. Levels of mercury were relatively high (blue shark: 0.032-2.5microgg(-1); swordfish: 0.031-9.8microgg(-1)) and comparable to values reported in the literature. However, mercury and organic mercury concentrations in muscle and liver of specimens from E were significantly higher than those from A. A similar trend was registered in stomach contents, suggesting higher uptake of Hg in specimens from E. This difference was also observed in the relationship between concentration in muscle and size, indicating a higher accumulation rate in specimens from E. The accumulation of Se in the liver of both species showed a positive correlation with inorganic mercury concentrations, pointing to a detoxifying mechanism of organic mercury in these species through Se-Hg liasons. 相似文献
953.
Marchettini N Niccolucci V Pulselli FM Tiezzi E 《Environmental science and pollution research international》2007,14(4):227-228
The aim of this paper is to propose a research framework, based on the joint use of three widely used methods: EMergy Evaluation
(EME), Ecological Footprint Analysis (EFA) and Greenhouse Gas Inventory (GHGI), that are applied to assess the environmental
sustainability of a region. The results of application of these methods to several Italian Provinces enabled us to compare
their sustainability, and to test the methods with respect to sustainability requirements at local and global level.
The outcomes suggest that the proposed framework provides an organic evaluation of regional systems based on key aspects,
such as resources depletion, consumption patterns, waste production and absorption. 相似文献
954.
The concentration of sixteen individual polycyclic aromatic hydrocarbons (PAHs) was measured in the clam Ruditapes decussatus whole soft tissues from several places of the Ria Formosa lagoon (Portugal). Total PAH (tPAH) concentrations were higher in the summer (August) and winter (January) than in the other months and the distribution pattern of the individual PAHs was generally dominated by the 4 aromatic ring PAHs, followed by the 2 + 3 aromatic rings PAHs. Benzo[a]anthracene and acenaphthene were the most representative PAHs of the two fractions. Principal components analysis (PCA) revealed that, in the Ria Formosa, seasonal variations are more important than spatial variations, due to changes in PAH source. These sources ranged from petrogenic to pyrolytic or a mixture of both. The origin of clam PAHs was also assessed by partial least squares (PLS) analysis using nineteen different PAH signatures, taken from the literature. It was possible to identify boat traffic, especially in the summer, as one of the most relevant PAH sources to the Ria Formosa. The influence of boat traffic was revealed by several signatures including diesel soot, oil and weathered oil and a mixture of different individual PAHs usually found in harbour sediments. Other relevant sources included combustion of organic matter such as forest fires and diverse domestic activities, occurring mainly in the summer. Most of the clams were considered safe for human consumption, except for some point samples, which presented unusually high PAH concentrations, suggesting the need for a regular survey of PAHs in clam tissues. 相似文献
955.
Jordão CP Ribeiro PR Matos AT Bastos RK Fernandes RB Fontes RL 《Environmental monitoring and assessment》2007,127(1-3):315-326
A study was performed to evaluate the environmental contamination in the Turvo Limpo River basin which receives effluent discharges from domestic (residential and commercial) activities. The watercourses examined were the São Bartolomeu Stream, Turvo Sujo River, and Turvo Limpo River, located in the Minas Gerais State, Brazil. Water samples were collected at the river-side and analyzed for evaluation of pollutant inputs. The pH, temperature, electrical conductivity, redox potential (Eh), dissolved oxygen (DO), total and settleable solids, visual color, hardness, chemical oxygen demand (COD), biochemical oxygen demand (BOD), chloride, total phosphate, total nitrogen, ammonia nitrogen, nitrate, total coliforms and E. coli, as well as the Cd, Pb, Cu, and Zn speciation were determined in the watercourses. The data obtained were compared with those of the Brazilian Environmental Standards and with data from non-contaminated areas. River water characteristics in some sites were far from the limit values established for superficial waters with satisfactory quality. For instance, the BOD values reached 411 mg L?1 for a maximum limit of 10.0 mg L?1, while the ammonia nitrogen concentration reached 28 mg L?1 for a maximum limit of 13.3 mg L?1. Some sites showed E. coli values above those of non-contaminated regions. Besides the effects of sewage discharges into the water-courses, agriculture activities and the use of the area for cattle husbandry influenced the quality of the river waters, for instance, the pH of a spring-water sample reached the value of 4.3. The São Bartolomeu Stream has been contributing to the deterioration of the water quality of the Turvo Sujo River, while the Turvo Limpo River has also been affected by anthropogenic discharges in the Turvo Sujo River. The speciation of Cd, Cu and Pb showed that these metals were mainly found in the particulate fraction (i. e., associated with the suspended material). Fifty five percent of the water samples showed labile Zn concentrations greater than that of the nonlabile Zn. 相似文献
956.
Marilia Vilela Junqueira Günther Friedrich Paulo Roberto Pereira de Araujo 《Environmental monitoring and assessment》2010,163(1-4):545-554
Based upon several years of experience in investigations with macrozoobenthos in rivers in the states of Minas Gerais and Rio de Janeiro, a biological assessment system has been developed to indicate pollution levels caused by easily degradable organic substances from sewers. The biotic index presented here is aimed at determining water’s saprobic levels and was, therefore, named the “Saprobic Index for Brazilian Rivers in Minas Gerais and Rio de Janeiro states” (ISMR). For this purpose, saprobic valences and weights have been established for 122 taxa of tropical macrozoobenthos. Investigations were carried out in little, medium sized and big rivers in mountains and plains. Through ISMR, a classification of water quality and the respective cartographic representation can be obtained. Data collection and treatment methods, as well as the limitations of the biotic index, are thoroughly described. ISMR can also be used as an element to establish complex multimetric indexes intended for an ecological integrity assessment, where it is essential to indicate organic pollution. 相似文献
957.
Giuseppa Grazia Aprile Mina Di Salvatore Giovanna Carratù Antonio Mingo Anna Maria Carafa 《Environmental monitoring and assessment》2010,162(1-4):291-299
We compared the capacity to accumulate airborne heavy metals of two lichens (Flavoparmelia caperata and Parmotrema chinense) and one higher plant (Nerium oleander) at a very densely populated urban site near Naples. After 15, 45, 75, and 120 days of exposure at four sites with different levels of air pollution, equal portions of thalli and 20 leaves were collected, and four environmentally significant elements, Fe, Cu, Zn, and Pb, were measured by inductively coupled plasma analysis. To compare the accumulation rates of lichens and the vascular plant, we determined an index of relative accumulation rate of pollutants during time and the ratio between the concentrations of each element in exposed samples to that of control samples (exposed-to-control ratio). Our data indicate F. caperata as being the most suitable bioaccumulator, followed by P. chinense. N. oleander was also found to be a useful heavy metal biomonitor though not suitable as a bioaccumulator. 相似文献
958.
Corona P Agrimi M Baffetta F Barbati A Chiriacò MV Fattorini L Pompei E Valentini R Mattioli W 《Environmental monitoring and assessment》2012,184(3):1409-1422
Urban areas are continuously expanding today, extending their influence on an increasingly large proportion of woods and trees
located in or nearby urban and urbanizing areas, the so-called urban forests. Although these forests have the potential for
significantly improving the quality the urban environment and the well-being of the urban population, data to quantify the
extent and characteristics of urban forests are still lacking or fragmentary on a large scale. In this regard, an expansion
of the domain of multipurpose forest inventories like National Forest Inventories (NFIs) towards urban forests would be required.
To this end, it would be convenient to exploit the same sampling scheme applied in NFIs to assess the basic features of urban
forests. This paper considers approximately unbiased estimators of abundance and coverage of urban forests, together with
estimators of the corresponding variances, which can be achieved from the first phase of most large-scale forest inventories.
A simulation study is carried out in order to check the performance of the considered estimators under various situations
involving the spatial distribution of the urban forests over the study area. An application is worked out on the data from
the Italian NFI. 相似文献
959.
Martins LD da Silva Júnior CR Solci MC Pinto JP Souza DZ Vasconcellos P Guarieiro AL Guarieiro LL Sousa ET de Andrade JB 《Environmental monitoring and assessment》2012,184(5):2663-2676
In this study, particulate matter (PM) were characterized from a place impacted by heavy-duty vehicles (Bus Station) fuelled
with diesel/biodiesel fuel blend (B3) in the city of Londrina, Brazil. Sixteen priority polycyclic aromatic hydrocarbons (PAH)
concentrations were analyzed in the samples by their association with atmospheric PM, mass size distributions and major ions
(fluorite, chloride, bromide, nitrate, phosphate, sulfate, nitrite, oxalate; fumarate, formate, succinate and acetate; lithium,
sodium, potassium, magnesium, calcium and ammonium). Results indicate that major ions represented 21.2% particulate matter
mass. Nitrate, sulfate, and ammonium, respectively, presented the highest concentration levels, indicating that biodiesel
may also be a significant source for these ions, especially nitrate. Dibenzo[a,h]anthracene and indeno[1,2,3,-cd]pyrene were the main PAH found, and a higher fraction of PAH particles was found in diameters lower than 0.25 μm in Londrina bus station. The fine and ultrafine particles were dominant among the PM evaluated, suggesting that biodiesel
decreases the total PAH emission. However, it does also increase the fraction of fine and ultrafine particles when compared
to diesel. 相似文献
960.
Most agronomic situations involve a sequence of herbicide, fungicide, and insecticide application. On the other hand, use
of pesticidal combinations has become a standard practice in the production of many agricultural crops. One of the most important
processes influencing the behavior of a pesticide in the environment is its degradation in soil. It is known that due to several
pesticide applications in one vegetation season, the pesticide may be present in mixtures with other pesticides or xenobiotics
in soil. This study examines the role which a mixture of chemicals plays in pesticide degradation. The influence of other
pesticides on the rate of pendimethalin (PDM) degradation in soil was measured in controlled conditions. Mixtures of PDM with
mancozeb or mancozeb and thiamethoxam significantly influenced the degradation of pendimethalin under controlled conditions.
The second type of mixtures, with metribuzin or thiamethoxam, did not affect the behavior of pendimethalin in soil. Also,
we determined the influence of water content on the rate of pendimethalin degradation alone in two soils and compared it to
the rate in three pesticide mixtures. We compared two equations to evaluate the predictors of the rate of herbicide dissipation
in soil: the first-order kinetic and the non-linear empirical models. We used the non-linear empirical model assuming that
the degradation rate of a herbicide in soil is proportional to the difference of the observed concentration of herbicide in
soil at time and concentration of herbicide in the last day of measurement. 相似文献