全文获取类型
收费全文 | 298篇 |
免费 | 2篇 |
国内免费 | 6篇 |
专业分类
安全科学 | 3篇 |
废物处理 | 8篇 |
环保管理 | 28篇 |
综合类 | 47篇 |
基础理论 | 67篇 |
环境理论 | 1篇 |
污染及防治 | 110篇 |
评价与监测 | 26篇 |
社会与环境 | 16篇 |
出版年
2023年 | 2篇 |
2022年 | 11篇 |
2021年 | 21篇 |
2020年 | 6篇 |
2019年 | 5篇 |
2018年 | 8篇 |
2017年 | 11篇 |
2016年 | 23篇 |
2015年 | 10篇 |
2014年 | 10篇 |
2013年 | 31篇 |
2012年 | 12篇 |
2011年 | 27篇 |
2010年 | 14篇 |
2009年 | 19篇 |
2008年 | 9篇 |
2007年 | 16篇 |
2006年 | 13篇 |
2005年 | 10篇 |
2004年 | 13篇 |
2003年 | 4篇 |
2002年 | 8篇 |
2001年 | 2篇 |
2000年 | 5篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1981年 | 2篇 |
1976年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有306条查询结果,搜索用时 31 毫秒
21.
Marina Isidori Maria Bellotta Margherita Cangiano Alfredo Parrella 《Environment international》2009,35(5):826-829
In the last years pharmaceuticals have aroused great interest as environmental pollutants for their toxic effects towards non target organisms. This study wants to draw attention to a further adverse effect of drugs, the endocrine interference. The most representative drugs of the widespread classes in environment were investigated. The YES-test and the E-screen assay were performed to detect the capability of these substances to bind the human estrogenic receptor α (hERα) in comparison with 17β-estradiol. Out of 14 tested pharmaceuticals, 9 were positive to YES-assay and 11 were positive to E-screen assay; in particular, Furosemide and the fibrates (Bezafibrate, Fenofibrate and Gemfibrozil) gave the maximal estrogenic response. Tamoxifen showed its dual activity as agonist and antagonist of hERα. 相似文献
22.
Spatial distribution of 238U and 226Ra activities in sediment columns along the Krka River and estuary, were studied using gamma spectrometry. Markedly different 238U and 226Ra activities between riverine, estuarine and marine sediments were observed. Distribution of these radionuclides, as well as their anthropogenic and natural origin, was evaluated by activity measurements, taking into account sedimentation rates estimated by 137Cs distribution in sediment columns. 相似文献
23.
The native carbon oxidation and PolyChloroDibenzo-p-Dioxins and PolyChloroDibenzoFurans, PCDD/F, formation were simultaneously studied at different temperatures (230-350 degrees C) and times (0-1440 min) in order to establish a direct correlation between the disappearance of the reagent and the formation of the products. The kinetic runs were conducted in an experimental set up where conditions were chosen to gain information on the role of fly ash deposits in cold zones of municipal solid waste incinerators in PCDD/F formation reaction. The carbon oxidation measured as the decrease of total organic carbon of fly ash was in agreement with the carbon evolved as sum of CO and CO(2). The carbon mass balance indicated an increase in the efficiency of carbon conversion in CO and CO(2) with temperature. The CO and CO(2) formation was the result of two parallel pseudo first order reactions thus giving significant information about the reaction mechanism. PCDD/F formation as a function of temperature showed that the maximum formation was achieved in a narrow range around 280 degrees C; the time effect at 280 degrees C was a progressive formation increase at least up to 900 min. The PCDF:PCDD molar ratio increased with temperature and time, and the most abundant homologues were HxCDD, HpCDD, OCDD for PCDD, and HxCDF, HpCDF within PCDF. These experimental results supported the hypothesis that the formation mechanism was the de novo synthesis. 相似文献
24.
Phelipe Manoel Oller Costa Marina Alessandra Gomes de Araújo Cristina Maria de Souza-Motta Elaine Malosso 《Environment, Development and Sustainability》2017,19(4):1189-1203
High litter inputs in agroforestry systems contribute to soil microbial activity, soil fertility and productivity. Considering that the cycling of organic matter is essential to the maintenance of physical–chemical and microbiological properties of the soil, the aims of this work were to estimate the production, accumulation and decomposition of litter, and assess soil microbial respiration in a complex multistrata agroforestry system located in the north-east of Brazil. This agroforestry system has three strata formed by forest and fruit trees and species of multiple uses. During 3 years (2011–2013), leaf litter was sampled monthly to account for litterfall and quarterly to account for litter accumulation. The rates of litter decomposition were estimated using the ratio produced-to-accumulated litter, and the correlation between litter fall and rainfall was calculated. Precipitation data were provided by the water and climate agency of Pernambuco (APAC). Soil samples (0–15 cm) were also taken quarterly, simultaneously with the litter accumulation samples, and soil microbial respiration was assessed using the capture, by a KOH solution, of the evolved CO2. The annual production of leaf litter was stable in the 3 years of study in this agroforestry system, and the monthly input of litter to the soil was influenced by rainfall, being higher in the dry seasons. The accumulated litter on the ground was constant, as was microbial activity (respiration) through time. The estimated litter decomposition rates were 1.49 (first year), 1.33 (second year) and 1.42 (third year), being considered rapid rates of decomposition. This guarantees (to the farmer) that this system is capable of maintaining soil fertility and eliminates the need for chemical fertilizers. 相似文献
25.
Bettinetti R Quadroni S Manca M Piscia R Volta P Guzzella L Roscioli C Galassi S 《Chemosphere》2012,88(3):344-351
Concentrations of DDTs and PCBs were determined in the zooplankton and in three different fish species (shad, whitefish and roach) collected seasonally during 2009 and 2010 in three sites in Lake Maggiore, a south-alpine lake that has been contaminated by DDT since 1996. As previously observed in 2008, even during 2009 DDTs concentrations were higher in zooplankton than in fish, probably due to the very unstable situation of the lake still influenced by local inputs. The situation changed in 2010, when all DDT compounds increased in fish to levels much higher than those measured in zooplankton. Biomagnification was statistically demonstrated for pp′DDE in all the three fish species, indicating a probable signal of recovery of the lake.Although with respect to total PCBs we observed that the contamination levels varied across time periods and across fish species, biomagnification was evident from zooplankton to fish both in 2009 and in 2010. As concern individual PCBs, biomagnification from zooplankton to all three fish species was significant for PCB 153 and PCB 138. 相似文献
26.
27.
28.
Liquid household hazardous wastes in the United States: Identification,disposal, and management plan
David K. Robertson Jude Akagha Jon Belasco Jane Bullis Gloria Byrne Joan Di Patria Wayne Fisher James Fonzino Jeffrey Hsu Lucy Merchan David Oster Jon Rosenberg Sabine Von Aulock Barry Vroeginday 《Environmental management》1987,11(6):735-742
Present methods of disposal of today's hazardous household chemicals in the United States are frequently not acceptable because of pathways to groundwater, surface water, and the atmosphere. This report identifies potentially hazardous liquid waste in the household, notes current disposal practices, and recommends an improved management plan that utilizes consumer education, manufacturer cooperation, and governmental intervention. Laws requiring uniform disposal labeling on packaging are critical. Local, county, and state governments must be encouraged to coordinate the necessary infrastructure. Managing hazardous household wastes now will mitigate potential disposal problems. 相似文献
29.
Marina?Della?Greca Maria?Rosaria?Iesce Lucio?PreviteraEmail author Maria?Rubino Fabio?Temussi 《Environmental Chemistry Letters》2004,2(3):155-158
The solar phototransformation of furosemide has been investigated in aqueous media. Irradiation of the drug in distilled water, in water and humic acids or nitrate ions, and in sewage sludge water affords a new dehalogenated dimer. The formation of the dimer has been explained by the formation of a cation radical intermediate. The low-measured environmental concentration of furosemide with respect to predicted environmental concentration in the Po and Lambro Rivers could be justified by its phototransformation. 相似文献
30.