全文获取类型
收费全文 | 290篇 |
免费 | 2篇 |
国内免费 | 6篇 |
专业分类
安全科学 | 3篇 |
废物处理 | 8篇 |
环保管理 | 27篇 |
综合类 | 45篇 |
基础理论 | 64篇 |
环境理论 | 1篇 |
污染及防治 | 108篇 |
评价与监测 | 26篇 |
社会与环境 | 16篇 |
出版年
2023年 | 2篇 |
2022年 | 10篇 |
2021年 | 21篇 |
2020年 | 6篇 |
2019年 | 4篇 |
2018年 | 7篇 |
2017年 | 11篇 |
2016年 | 23篇 |
2015年 | 10篇 |
2014年 | 9篇 |
2013年 | 31篇 |
2012年 | 12篇 |
2011年 | 27篇 |
2010年 | 14篇 |
2009年 | 19篇 |
2008年 | 9篇 |
2007年 | 16篇 |
2006年 | 13篇 |
2005年 | 10篇 |
2004年 | 13篇 |
2003年 | 4篇 |
2002年 | 7篇 |
2001年 | 2篇 |
2000年 | 5篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1981年 | 2篇 |
排序方式: 共有298条查询结果,搜索用时 15 毫秒
31.
Marina Isidori Elio Coppola Maria Rosaria Iesce Flavio Cermola Giovanni Papa Alfredo Parrella 《Journal of environmental science and health. Part. B》2013,48(9):891-900
The microcrustacean Thamnocephalus platyurus was used to detect the toxicity reduction of carboxin in abiotic degradation compared to biotic degradation. The abiotic degradation was obtained using two sterilized Entisols with different surface properties while the biotic degradation by Pseudomonas aeruginosa was obtained using the fungicide as the only C source. The results showed that the highest toxicity reduction rates for the abiotic degradation were achieved in 20 days with 49.2% for the coarser soil, 60.7% for the soil with a finer texture, whereas for the biotic degradation, 60.6%. Analysis (1H NMR) showed that the soils transformed carboxin to produce sulfoxide and enol in different concentrations depending on the soil properties, while P. aeruginosa metabolized the fungicide to produce inorganic compounds such as ammonium and nitrite, minor degradation pathways were oxidized to sulfoxide and hydrolytic ring-opening to 2-[(2-hydroxyethyl)thio]acetoacetanilide enol. These results indicated that the degradation of carboxin occurred via abiotic catalytic processes as well as via biotic transformation leading to less toxic derivatives and such phenomena are caused by exchange/surface features of soils, rather than by the mere content of clay or organic matter fractions. 相似文献
32.
33.
34.
35.
Gualtieri M Andrioletti M Vismara C Milani M Camatini M 《Environment international》2005,31(5):723-730
Data on the indicators of environmental impact of tire debris, originated from the tire abrasion on roads, are extremely scarce, while it is well known that tires may produce deleterious effects. Tire debris contains significant quantities of zinc (Zn) which may be released by tire rubber. We have used tire particles (TD) produced in laboratory from new rubber. Two sets of experiments were set up to obtain eluates. One set used 50 and 100 g/L TD to produce eluates at pH 3-7. The Zn quantity was measured with a Inductively Coupled Plasma-Atomic Emission Spectrometry. The eluates at 1%,10%,50%,100% concentrations in culture media were tested on Raphidocelis subcapitata, Daphnia magna and Xenopus laevis embryos (FETAX test). The other set of experiments was performed putting 250 mg/L TD in a column with glass beads to control particle dispersion during the elution process. We demonstrate that factors such as pH, size and particles aggregation deeply influence the elution process, that the amount of Zn leached from particles is related to their aggregation rather than their quantity. These results, even though do not reflect the real environmental toxicity of the leachates, can be successfully used for comparative purposes allowing an initial assessment of the potential effect of tire derived particles. 相似文献
36.
Shimabukuro VG Alexandre NM Coluci MZ Rosecrance JC Gallani MC 《International journal of occupational safety and ergonomics》2012,18(1):15-26
Physical therapists engage in work tasks that expose them to occupational risk factors related to musculoskeletal disorders. Due to the gap in the literature on instruments focused on those workers, this study adapted a job factors questionnaire to physical therapists, and assessed its psychometric properties. The questionnaire was adapted and its content validity was established. The psychometric properties were evaluated among 142 physical therapists. Reliability was verified using the temporal-stability design and internal consistency. Construct validity was assessed with the known-groups technique. Test-retest results demonstrated intraclass correlation coefficients between .82 and .90 (p < .001). Cronbach's α of .91 verified the reliability of the questionnaire. The known-groups technique demonstrated a statistically significant difference on the scores of the items when physical therapists were compared to office workers. The results indicated that the adapted questionnaire had acceptable psychometric properties for assessing problematic job factors among physical therapists working in hospitals. 相似文献
37.
Valeria Marina Nurchi Costantino Floris Rosalba Pinna Núria Fiol Isabel Villaescusa 《Water environment research》2007,79(11):2363-2367
The use of biomasses that result from the agriculture and food industries in removing heavy metals from wastewaters is attracting increasing interest. We present a joined potentiometric and cross polarization magic angle spinning (CP-MAS) carbon-13 (13C) nuclear magnetic resonance (NMR) study on the interaction of olive stones with copper(II), nickel(II), and cadmium(II). The potentiometric measurements allow both to distinguish two kind of basic sites in the olive stones and to postulate the coordination models for the three studied metals. The NMR spectral analysis allows the attribution of the different signals to the components of the olive stone matrix. A comparison of CP-MAS 13C NMR spectra of the samples after metal treatment suggests a specific complexation between metal ions and hydroxyl groups on guaiacyl and syringyl moieties. 相似文献
38.
39.
Marina ACCORNERO Lin JIANG Eugenio NAPOLI Marco CREMONINI Giovanni FERRO Federica BELLORO Maosheng ZHONG 《Frontiers of Environmental Science & Engineering》2015,9(3):465
A probabilistic analysis was performed on soil arsenic concentration data from 4 brownfield sites at Beijing (Chaoyang and Haidian Districts), involved in environmental assessment studies. The available data sets were processed to provide a statistical characterization of the background populations and differentiate “anomalous data” from the natural range of variation of arsenic concentrations in soil. The site-specific background distributions and the existing wide-scale background values defined for the Beijing area were compared, discussing related implications for the definition of metal contamination soil screening levels (SSLs) in site assessment studies. The statistical analysis of As data sets discriminated site-specific background populations, encompassing 88% to 94% of the sample data, from outliers values, associated with either subsoil natural enrichments or possible anthropogenic releases. Upper Baseline Concentration (UBC) limits (+ 2σ level), including most of the site-specific metal background variability, were derived based on the statistical characterization of the background populations. Sites in the Chaoyang South District area had UBC values in the range 10.4–12.6 mg·kg-1. These ranges provide meaningful SSL values to be adopted for As in local site assessment studies. Using the wide-scale background value for the Beijing area would have erroneously classified most of the areas in the subject sites as potentially contaminated. 相似文献
40.
Mauro Mecozzi Demetria Cardarilli Eva Pietrantonio Marina Amici 《Chemistry and Ecology》2013,29(4):239-254
In this paper a method for the study of the qualitative similarity of extractable humic substance (EHS) in marine sediments based on the realisation of UV spectral library of EHS is described. the spectral library was built including the digitised spectra of humic substance extracted from several marine sediments (46 samples) and two samples of standard materials (lignin sulphonate and humic substance) in a Statistica data file. the data matrix was elaborated by means of different multivariate statistic techniques such as Cluster Analysis (CA), Principal Components Analysis (PCA) and the univariate technique Spectral Correlation Analysis (SCA). This approach allows us to show the contribution of different organic compounds (aromatic, lipid and acid) to the composition of EHS and moreover it evidences also the structural characteristics of EHS in terms of similarities in the qualitative composition of samples such as presence of terrestrial and/or vegetal contributions. the UV library is an objective tool to study the qualitative composition of EHS and it represents a complementary approach to the most common methods based on the application of spectroscopic (IR, 13CNMR), potentiometric and chromatographic techniques. 相似文献