Alum amendment effects on phosphorus release and distribution in poultry litter-amended sandy soils

Increased poultry production has contributed to excess nutrient problems in Atlantic Coastal Plain soils due to land application of poultry litter (PL). Aluminum sulfate [alum, Al(2)(SO(4))(3).14H(2)O] amendment of PL effectively reduces soluble phosphorus (P) in the PL; however, the effects of these litters when added to acidic, sandy soils are not well understood. The objective of this study was to investigate the efficacy of alum-amended poultry litter in reducing P release from three Delaware Coastal Plain soils: Evesboro loamy sand (Ev; excessively drained, mesic, coated Typic Quartzipsamments), Rumford loamy sand (Ru; well drained, coarse-loamy, siliceous, subactive, thermic Typic Hapludults), and Pocomoke sandy loam (Pm; very poorly drained, coarse-loamy, siliceous, active, thermic Typic Umbraquults). Long-term (25 d) and short-term (24 h) desorption studies were conducted, in addition to chemical extractions and kinetic modeling, to observe the changes that alum-amended versus unamended PL caused in the soils. The Ev, Ru, and Pm soils were incubated with 9 Mg ha(-1) of alum-amended or unamended PL. Long-term desorption (25 d) of the incubated material resulted in approximately 13.5% (Ev), 12.7% (Ru), and 13.3% (Pm) reductions in cumulative P desorbed when comparing soil treated with unamended and alum-amended PL. In addition, the P release from the soil treated with alum-amended litter was not significantly different from the control (soil alone). Short-term desorption (24 h) showed 7.3% (Ev), 15.4% (Ru), and 20% (Pm) reductions. The overall implication from this study is that the use of alum as a PL amendment is useful in coarse-textured soils of the Coastal Plain. With increased application of alum-amended PL, more significant decreases may be possible with little or no effect on soil quality.     

Effects of mineral surfaces on pyrene partitioning to well-characterized humic substances

Mineral surfaces can alter the ability of humic substances (HS) to bind hydrophobic organic contaminants. In this study, complete adsorption (i.e., to avoid HS adsorptive fractionation effects) of a small subset of well-characterized terrestrial and aquatic HS on kaolinite and hematite significantly changed their subsequent organic carbon-normalized partition coefficients K(ads)(oc) for pyrene relative to their original respective dissolved organic carbon-normalized partition coefficients K(dis)(oc). Parallel experiments with ultrafiltration (UF) fractions obtained from purified Aldrich humic acid (PAHA) (Aldrich Chemical, Milwaukee, WI) gave similar results. The heterogeneity among the PAHA UF fractions was examined via their mineral surface adsorption characteristics and their subsequent ability to bind pyrene. As expected, variations in maximum adsorption densities (q(max)), Langmuir adsorption constants (K(q)), and pyrene K(ads)(oc) values were observed among the PAHA UF fractions. However, general trends of q(max), K(q), and pyrene log K(ads)(oc) values for the PAHA UF fractions versus the logarithm of their weight-average molecular weights (MW(w)) did not typically match the corresponding trends obtained with the four aquatic and terrestrial HS. In general, an ideal mixture competitive adsorption model gave reasonable predictions for PAHA sorption to kaolinite and hematite based on their corresponding UF isotherm parameters. Ideal mixture predictions of pyrene partitioning to adsorbed PAHA from the corresponding UF fraction results were better for kaolinite versus hematite, indicating that the underlying mineral surface can alter the effects of HS heterogeneity on hydrophobic organic contaminant sorption.     

Field dissipation of acetochlor in two New Zealand soils at two application rates

The persistence of pesticides in soils has both economic and environmental significance and is often used as a key parameter in pesticide risk assessment. Persistence of acetochlor [2'-ethyl-6'-methyl-N-(ethoxymethyl)-2-chloroacetylanilide] in two New Zealand field soils was measured over two years and the data were used to identify models that adequately describe acetochlor persistence in the field. Acetochlor was sprayed onto six fallow plots (3 x 9 m each) at each site at the recommended rate (2.5 kg a.i. ha(-1)) and at twice that rate. Acetochlor concentrations were measured in soil cores. Simple first-order kinetics (Model 1) adequately described acetochlor persistence in Hamilton clay loam soil (Humic Hapludull, Illuvial Spadic) at the high application rate, but overestimated it at the low application rate. A quadratic model (Model 2), a first-order double-exponential model (Model 3), a first-order biphasic model (Model 4), or a two-compartment model (Model 5) better described acetochlor persistence at the low application rate. The time for 50% (DT50) and 90% (DT90) of initial acetochlor loss was approximately 9 and 56 d, and 18 and 63 d at low and high application rates, respectively. The more complex Models 2 through 5 also better described the biphasic dissipation of acetochlor in Horotiu sandy loam soil (Typic Orthic Allophanic) than Model 1, with Model 1 significantly underestimating acetochlor concentrations on the day of application at both application rates. The DT50 and DT90 values were 5 and 29 d and 7 and 31 d at low and high application rates, respectively. Overall, application rate significantly affected the DT50 and DT90 values in the Hamilton soil, but not in the Horotiu soil. Faster acetochlor loss in the Horotiu soil possibly resulted from the higher soil organic carbon content that retained more acetochlor near the soil surface where higher temperature and photolysis accelerated the loss.     

Reducing atrazine losses: water quality implications of alternative runoff control practices

Water quality is being affected by herbicides, some allegedly harmful to human health. Under scrutiny is atrazine (1-chloro-3-ethylamino-5-isopropylamino-2,4,6-triazine), a commonly used herbicide in corn (Zea mays L.) and sorghum [Sorghum bicolor (L.) Moench] production. Concentrations of soluble and adsorbed atrazine losses sometimes exceed the safe drinking water standard of 3 microg L(-1) established by the USEPA. This study assesses the protective implications of runoff control structures and alternative crop farming practices to minimize atrazine losses. Using a computerized simulation model, APEX, the following four practices were the most effective with respect to the average atrazine loss as a percent of the amount applied: (i) constructing sediment ponds, 0.09%; (ii) establishing grass filter strips, 0.14%; (iii) banding a 25% rate of atrazine, 0.40%; and (iv) constructing wetlands, 0.45%. Other atrazine runoff management options, including adoption of alternative tillage practices such as conservation and no-till as well as splitting applications between fall and spring, were marginally effective.     

Assessment of manure phosphorus export through turfgrass sod production in Erath County, Texas

A best management practice (BMP) for exporting manure phosphorus (P) in turfgrass sod from the North Bosque River (NBR) watershed in central Texas was assessed using a geographic information system (GIS). The NBR watershed has a mandate to reduce the total annual P load to the NBR by 50% as a result of total maximum daily load regulation. Since dairy waste applications to fields are identified as the major nonpoint source of P to the river, innovative BMPs, such as export of manure P in turfgrass, will be needed to achieve the 50% reduction. However, methods are needed to evaluate the feasibility of these innovative management practices prior to their implementation. A geospatial database of suitable turfgrass production sites was developed for Erath County using GIS. Erath County largely encompasses the upper portion of the NBR watershed. Information from field experiments, production practices, and ground-truthing was used to search, analyze, and verify a geospatial database developed from national and regional sources. The integration and analyses of large databases supports the search by turf producers for sites suitable for turfgrass sod production in Erath County. In addition, GIS enables researchers and regulators to estimate manure P exports and reduced P loading due to implementation of the manure export BMP on a county scale. Under optimal conditions 198,000 kg manure P yr(-1) could be used and 114,840 kg manure P yr(-1) exported from the NBR watershed through implementation of a system using dairy manure to produce turfgrass sod. This is the equivalent of the manure P applied from 10,032 dairy cows yr(-1) and exported from 5808 dairy cows yr(-1). Application of GIS to large-scale planning and decision-making transcends traditional field-scale applications in precision agriculture.     

Does the selection of ISO 14001 registrars matter? Registrar reputation and environmental policy statements in China

This study investigates the relationship between characteristics of environmental policy statements and the reputations of ISO 14001 registrars who had performed certification audits of firms operating in mainland China. Three characteristics of environmental policy statements were examined: (1) The conformance of the policy to strict interpretations of the international standard; (2) The policy statement's adherence to the good practice guidelines specified in ISO 14004; and, (3) Self-reported evaluations of the policy statement's effectiveness as implemented. Data from 106 facilities in Beijing, Shanghai and Guangzhou reveal that registrar quality has a relatively weak, positive relationship with conformance to both ISO 14001 standards and to ISO 14004 guidelines, but no relationship was observed with the self-reported data. Additional findings are that the use of foreign registrars is significantly associated with the adoption of ISO 14004 guidelines and that conformance with ISO 14001 standards is somewhat higher for international joint ventures and foreign-owned firms than for state-owned enterprises.     

Anatomical and experimental evidence for particulate feeding in<Emphasis Type="Italic"> Lucinoma aequizonata</Emphasis> and<Emphasis Type="Italic"> Parvilucina tenuisculpta</Emphasis> (Bivalvia: Lucinidae) from the Santa Barbara Basin

Previous nutritional models for adults of the lucinid bivalve Lucinoma aequizonata contend that symbiotic chemoautotrophic bacteria provide most of the organic carbon for the host. The existence of this symbiosis, coupled with the hosts distinctive anatomical features, shaped the impression that particulate feeding was not a significant part of L. aequizonata nutrition. Here, we use several techniques to show that particulate feeding is a consistent and important part of the L. aequizonata nutritional strategy. Histological and scanning electron microscopy observations reveal that the gills of L. aequizonata, like those of the lucinid Parvilucina tenuisculpta, have functional mucociliary epithelia, able to transport captured particles to the mouth. Observations of gut content and radiolabeled feeding experiments indicate that L. aequizonata does ingest and assimilate carbon from particulate organic matter. Furthermore, molecular identification of a broad spectrum of organisms in the guts of native adult specimens demonstrates that L. aequizonata is non-selective when ingesting organic material, and has a mixotrophic diet.Electronic Supplementary Material Supplementary material is available in the online version of this article at Communicated by P.W. Sammarco, Chauvin     

Patterns in swimming by a scyphomedusa: a novel approach to quantifying behavior in individuals

Behavior is commonly studied at the group level using several individuals, but there is increasing evidence that the behavior of a few individuals often has a disproportionate effect on the response of a population to its environment. The present study used a suite of statistical techniques, random series analysis, analysis of variance, spectral analysis, and goodness-of-fit tests of frequency histograms, to quantitatively describe the time-dependent changes in individual behavior. Each technique reveals a different facet of the behavior and, when simultaneously applied to the data, distinguishes significant differences among the behaviors of several individuals. The approach was developed and tested on the swimming behavior of four specimens of the scyphomedusa Aurelia aurita (Linnaeus, 1758), which were observed for 19 days, beginning 16 January 1998, and videotaped under identical environmental conditions during that period. The analyses showed that each medusa swam in a unique pattern, varying swimming at characteristic frequencies. Application of the approach to individual-based numerical modeling, to the role of endogenous stimuli in the behavioral repertoire, and to in situ studies of animal behavior is discussed.Communicated by J.P. Grassle, New Brunswick