Interaction of different forms of graphene with chicken embryo red blood cells

With the rapid development of graphene synthesis and functionalization approaches, graphene and its related derivatives have shown great potential in many applications in material science, including biomedical applications. Several in vitro and in vivo studies clearly showed no definitive risks, while others have indicated that graphene might become health hazards. In this study, we explore the biocompatibility of graphene-related materials with chicken embryo red blood cells (RBC). The hemolysis assay was employed to evaluate the in vitro blood compatibility of reduced graphene, graphene oxide, and reduced graphene oxide, because these materials have recently been used for biomedical applications, including injectable graphene-related particles. This study investigated structural damage, ROS production and hemolysis of chicken embryo red blood cells. Different forms of graphene, when incubated with chicken embryo RBC, were harmful to cell structure and induced hemolysis.     

The preparation of calcium phosphate adsorbent from natural calcium resource and its application for copper ion removal

Environmental Science and Pollution Research - Using the hen eggshells (biowaste) as a source of calcium and an environmentally friendly approach, the nanopowder composed of 74% of hydroxyapatite...     

The future of sustainability in the context of COVID-19

The COVID-19 pandemic is a global crisis emanating both from a virus (SARS-CoV-2) and from the drastic actions to contain it. Here, we reflect on the immediate responses of most world powers amid the pandemic chaos: totalitarian surveillance and nationalist isolation. Drawing on published literature, we consider measures such as wildlife-use bans, lockdowns and travel restrictions, along with their reverberations for people, economies and the planet. Our synthesis highlights significant shortfalls of applying command-and-control tactics in emergencies. For one, heavy-handed bans risk enormous unintended consequences and tend to fail if they lack legitimacy or clash with people’s values. Furthermore, reactive and myopic strategies typically view the pandemic as a stand-alone crisis, rather than unravelling the complex interplay of nature-society interactions through which zoonotic diseases originate. A return to adaptive management approaches that recognise root causes and foster socio-ecological resilience will be essential to improve human and planetary health and mitigate future pandemics.     

Seasonality of Soil Erosion Under Mediterranean Conditions at the Alqueva Dam Watershed

The Alqueva reservoir created the largest artificial lake of Western Europe in 2010. Since then, the region has faced challenges due to land-use changes that may increase the risk of erosion and shorten the lifetime of the reservoir, increasing the need to promote land management sustainability. This paper investigates the aspect of seasonality of soil erosion using a comprehensive methodology that integrates the Revised Universal Soil Loss Equation (RUSLE) approach, geographic information systems, geostatistics, and remote-sensing. An experimental agro-silvo pastoral area (typical land-use) was used for the RUSLE factors update. The study confirmed the effect of seasonality on soil erosion rates under Mediterranean conditions. The highest rainfall erosivity values occurred during the autumn season (433.6 MJ mm ha^?1 h^?1), when vegetation cover is reduced after the long dry season. As a result, the autumn season showed the highest predicted erosion (9.9 t ha^?1), contributing 65 % of the total annual erosion. The predicted soil erosion for winter was low (1.1 t ha^?1) despite the high rainfall erosivity during that season (196.6 MJ mm ha^?1 h^?1). The predicted annual soil loss was 15.1 t ha^?1, and the sediment amount delivery was 4,314 × 10³ kg. Knowledge of seasonal variation would be essential to outline sustainable land management practices. This model will be integrated with World Overview of Conservation Approaches and Technologies methods to support decision-making in that watershed, and it will involve collaboration with both local people and governmental institutions.     

Constructing genuine savings indicators for Ireland, 1995-2005

In this paper we compute the genuine savings indicators for the Republic of Ireland over the period 1995-2005. We expand and improve existing World Bank's estimates by: a) using data collected from official Irish sources; b) employing the net present value method to assess resource depreciation; c) including external costs from SO(2) and NOx emissions; and d) estimating human capital accumulation using the returns to education. We also perform a sensitivity analysis to check the robustness of our estimates to different assumptions and parameters. Our estimates are consistently smaller than the World Bank's and negative in the first years of the period considered.     

Numerical and experimental analysis of wind erosion on a sinusoidal pile

Erosion is a common phenomenon in nature, and it may cause a wide range of problems such as air pollution, and destruction of agricultural land, shelters and stockpiles. The present work deals with stockpiles, which have their profiles described by a sinus function or by similar trigonometric functions. Analysis of the erosion by air flow over these piles will provide for further understanding of the erosion underlying mechanisms and, moreover, how to control them and eventually to prevent them. To this purpose, different experimental tests are conducted for a pile with a sinuous profile, and particular attention is given to the time development of the profile due to the erosion process; the effect of the air velocity is also studied by selecting different velocities. In addition, the flow over several deformed piles is numerically predicted using the CFX software; the results clearly show the erosion process is strongly dependent upon time, velocity field and surface disturbances. A correlation between the erosion rate and the velocity is proposed.     

Structural design of a natural windbreak using computational and experimental modeling

Computational and experimental approaches are employed for the structural design of a natural windbreak. It is intended to find the optimum tree shelterbelt to obviate the uneven wind speed distribution across the width dimension of a high-level competition rowing channel. The experimental results, obtained in a wind tunnel, and consisting of erosion-technique images and local wind-speed measurements, are used to benchmark the computational model. A good agreement between the two sets of results is obtained. Several windbreak configurations, considering one or two rows of different cross-sectional shape and porosity, are computationally modeled. For the shortest row a rectangular shape, with porosity of 35%, is considered; for the tallest row, which aims the modeling of a poplar tree, a porosity of 87% is assumed at the trunk level, and 60% at the crown. The optimum shelterbelt consists of two rows, composed by bamboo and poplar trees, which allows the attainment of a low and nearly uniform wind flow across the width of the channel.     

Influence of americium-241 on the microbial population and biodegradation of organic waste

The present study investigated the influence of ²⁴¹Am on microbial growth and the degradation of organic waste. Leachate samples collected in a lysimeter were periodically analyzed for bacterial growth, under both aerobic and anaerobic conditions. ²⁴¹Am inhibited bacterial growth, and the degradation of organic matter was delayed in comparison with the control. Minimal inhibitory concentration assays and survival curves revealed that it inhibits the growth of Pseudomonas putida F1. The assay also revealed that ²⁴¹Am is more toxic than ²³⁸U, Zn²⁺ and Cd²⁺. This study further led to the finding of four new radionuclide-tolerant bacterial strains: Flavobacterium spp., Pseudomonas gladioli, Chryseobacterium indologenes and Ochrobactrum anthropi. The survival curves of P. gladioli, C. indologenes revealed that these bacteria are resistant to metal as consortia.     

Oxidative stress in Nile tilapia (Oreochromis niloticus) and armored catfish (Pterygoplichthys anisitsi) exposed to diesel oil

Considering that diesel oil is one of the most common aquatic contaminants, we compare the oxidative stress between two species of fish with different habitats (Pterygoplichthys anisitsi, benthic and Oreochromis niloticus, nektonic) exposed to diesel oil. Malondialdehyde concentrations (MDA) and the activities of ethoxyresorufin-O-deethylase (EROD), glutathione S-transferase (GST), catalase (CAT), superoxide dismutase (SOD), and glutathione peroxidase were all analyzed in the fishes' livers and gills after 2 and 7 days of exposure to different concentrations of diesel (0.1 and 0.5 mL/L). In the tilapia, MDA levels and the activities of EROD and GST activity in the liver, as well as MDA levels and the activities of GST and SOD in the gill had statistically significant differences between the treatments and between the times of exposure. For the catfish, the same occurred in the case of MDA, EROD, and SOD in the liver and in CAT and SOD in the gills. There were significant differences in the enzyme activity and lipid peroxidation between the species. Although the activity of most enzymes seemed to be more expressive and responsive to diesel in O. niloticus, diesel oil also caused significant effects on oxidative stress parameters in P. anisitsi, even though this species is benthic and thus has less access to insoluble fractions of diesel oil. Therefore, both species can be used as sentinel organisms in environmental biomonitoring of diesel contamination.     

Human health risk assessment of environmental and dietary exposure to natural radionuclides in the Catalan stretch of the Ebro River, Spain

This study was aimed at assessing the levels of ²¹⁰Pb and ²¹⁰Po concentrations as well as gross alpha and beta activities in environmental monitors from the Catalan stretch of the Ebro River (Spain), potentially influenced by the presence of sediments with high concentrations of ²³⁸U and its decay chain daughters in the Flix reservoir. The chronic daily intake of ²¹⁰Pb and ²¹⁰Po through ingestion and inhalation of soils was evaluated, and the derived non-carcinogenic and carcinogenic risks were characterized. The low concentration of radioisotopes in soils resulted in a negligible annual effective dose. The levels of ²¹⁰Pb and ²¹⁰Po were determined in various groups of highly consumed food (fish and seafood, vegetables, fruits, and rice), and their dietary intake was calculated. The annual effective dose for the adult people from food intake was estimated in 3.3 × 10^???2 mSv, mostly due to ²¹⁰Po. Overall, the current radioactivity levels in the Catalan stretch of the Ebro River should not mean any additional health risk for the population living nearby. However, an integral assessment of the risks derived from exposure to other pollutants (e.g., metals and organochlorine compounds) jointly with radionuclides could be of great interest.