International cross-validation of a BOD5 surrogate

BOD5 dates back to 1912 when the Royal Commission decided to use the mean residence time of water in the rivers of England, 5 days, as a standard to measure the biochemical oxygen demand. Initially designed to protect the quality of river waters from extensive sewage discharge, the use of BOD5 has been quickly extended to waste water treatment plants (WWTPs) to monitor their efficiency on a daily basis. The measurement has been automatized but remains a tedious, time- and resource-consuming analysis. We have cross-validated a surrogate BOD5 method on two sites in France and in the USA with a total of 109 samples. This method uses a fluorescent redox indicator on a 96-well microplate to measure microbial catabolic activity for a large number of samples simultaneously. Three statistical tests were used to compare surrogate and reference methods and showed robust equivalence.     

Twenty Years of Change on Campsites in the Backcountry of Grand Canyon National Park

This article draws on three separate research and monitoring studies to describe 20-year trends in the number and condition of campsites in the backcountry of Grand Canyon National Park. Results are used to assess the effectiveness of a complex and innovative management program, adopted in 1983, that sought to concentrate use on designated campsites in popular places and disperse camping in more remote places. In 1984, conditions on 12 high-use campsites and 12 low-use campsites were carefully assessed. Conditions on 22 of these campsites were reassessed in 2005. In addition, campsite-monitoring surveys were conducted between 1985 and 1992 and again in 2003 and 2004. In these surveys, all campsites were located and their condition rapidly assessed. The detailed assessment of a sample of sites suggests relatively little change in condition during the 20-year period. The high-use sites were more highly disturbed than the low-use sites, but they did not change more during the study period. In contrast, changes at larger scales were dramatic. The total number of campsites more than doubled during the study period. Surprisingly, the proliferation of new campsites was greater in places where camping was only allowed on designated campsites than in places where camping was allowed anywhere. Concern that concentration of use on designated sites would cause unacceptable impact was unfounded. Management implications for other internationally significant protected areas that allow backcountry camping are explored.     

Laser cleaning of historical limestone buildings in Bordeaux appraisal using cathodoluminescence and electron paramagnetic resonance

BACKGROUND: Most historical buildings in Bordeaux city are made of limestone. This yellowish-white rock is rather porous and highly sensitive to pollution. As a consequence of local weathering conditions, these buildings present a dark appearance due to the development of a superficial dark grey to black crust. METHODS: For the last decade, a campaign has been underway to clean these buildings. Eleven techniques of surface treatment have been used, including laser beam technology. As a contribution to the study of laser beam effects on stone buildings, two analytical methods have been used on clean versus unclean surfaces: Cathodoluminescence (CL) and Electron Paramagnetic Resonance (EPR), in addition to SEM-EDX and XRD. RESULTS: The black crust is composed of different types of particles: carbon porous micro-particles of industrial origin, atmospheric dust due to the erosion of soils and rocks, alumino-silicate particles from urban pollution; all these particles being cemented by gypsum. DISCUSSION: As far as heritage conservation is concerned, the laser surface treatment not only preserves the original patina of the stone, but also leaves surface smoothness unaltered. CONCLUSIONS AND PERSPECTIVES: CL and EPR data confirm that lasers--with highly controlled parameters--only get rid of the black crust and, thus, reveal the underneath layer, the so-called patina. This patina shows no luminescence, whereas the limestone on which it has grown shows a bright orange emission of CL. This indicates CL to be a fast and easy way to provide a high quality control for the restoration of polluted ancient stones.     

Meta-analysis of environmental contamination by phthalates

Phthalate acid esters (PAE), commonly named phthalates, are toxics classified as endocrine-disrupting compounds; they are primarily used as additives to improve the flexibility in polyvinyl chloride. Many studies have reported the occurrence of phthalates in different environmental matrices; however, none of these studies has yet established a complete overview for those compounds in the water cycle within an urban environment. This review summarizes PAE concentrations for all environmental media throughout the water cycle, from atmosphere to receiving waters. Once the occurrences of compounds have been evaluated for each environmental compartment (urban wastewater, wastewater treatment plants, atmosphere, and the natural environment), we reviewed data in order to identify the fate of PAE in the environment and establish whether geographical and historical trends exist. Indeed, geographical and historical trends appear between Europe and other countries such as USA/Canada and China, however they remain location dependent. This study aimed at identifying both the correlations existing between environmental compartments and the processes influencing the fate and transport of these contaminants into the environment. In Europe, the concentrations measured in waterways today represent the background level of contamination, which provides evidence of a past diffuse pollution. In contrast, an increasing trend has actually been observed for developing countries, especially for China.     

Modeling organizational processes across hierarchical levels: climate,leadership, and group process in work groups

Perceptions of organizational climate, leadership, and group processes were aggregated within hierarchically nested work groups. Relationships across hierarchical boundaries were examined for two samples at different hierarchical levels in a military organization. Perceptions of climate were positively related across levels in both samples. There was evidence that the pattern of relationship among the other constructs was different in the two samples. The results have implications for the process which organizational interventions can be expected to flow through hierarchical levels of an organization. © 1997 John Wiley & Sons, Ltd.     

Validation of FLACS against experimental data sets from the model evaluation database for LNG vapor dispersion

The siting of facilities handling liquefied natural gas (LNG), whether for liquefaction, storage or regasification purposes, requires the hazards from potential releases to be evaluated. One of the consequences of an LNG release is the creation of a flammable vapor cloud, that may be pushed beyond the facility boundaries by the wind and thus present a hazard to the public. Therefore, numerical models are required to determine the footprint that may be covered by a flammable vapor cloud as a result of an LNG release. Several new models have been used in recent years for this type of simulations. This prompted the development of the “Model evaluation protocol for LNG vapor dispersion models” (MEP): a procedure aimed at evaluating quantitatively the ability of a model to accurately predict the dispersion of an LNG vapor cloud.This paper summarizes the MEP requirements and presents the results obtained from the application of the MEP to a computational fluid dynamics (CFD) model – FLACS. The entire set of 33 experiments included in the model validation database were simulated using FLACS. The simulation results are reported and compared with the experimental data. A set of statistical performance measures are calculated based on the FLACS simulation results and compared with the acceptability criteria established in the MEP. The results of the evaluation demonstrate that FLACS can be considered a suitable model to accurately simulate the dispersion of vapor from an LNG release.     

Combining chemical sequential extractions with 3D fluorescence spectroscopy to characterize sludge organic matter

The design and management of anaerobic digestion of sewage sludge (SS) require a relevant characterisation of the sludge organic matter (OM). Methods currently used are time-consuming and often insufficiently informative. A new method combining chemical sequential extractions (CSE) with 3D fluorescence spectroscopy was developed to provide a relevant SS characterisation to assess both OM bioaccessibility and complexity which govern SS biodegradability. CSE fractionates the sludge OM into 5 compartments of decreasing accessibility. First applied on three SS samples with different OM stability, fractionation profiles obtained were in accordance with the latter. 3D fluorescence spectroscopy revealed that the bioaccessible compartments were mainly constituted of simple and easily biodegradable OM while the unaccessible ones were largely made of complex and refractory OM. Then, primary, secondary and anaerobically digested sludge with different biodegradabilities were tested. Complexity revealed by 3D fluorescence spectroscopy was linked with biodegradability and chemical accessibility was correlated with sludge bioaccessibility.     

On the wind resource mapping of Burkina Faso

In this work, mesoscale wind resource maps, at 5-km resolution, of the country of Burkina Faso (274,200 km²) were developed using the Anemoscope and mesoscale compressible community models. Results show that the northeast region of Burkina Faso has a good wind regime at 80 m above ground level (agl), while the wind regime in other parts of the country is generally low, even at 80 m agl. In addition, the technical power potential and the potential annual energy production that can be generated from the wind in Burkina Faso are identified using analysis tools based on geographical information systems and economic constraints. Results from the technical power potential at 80 m agl show that a total of 312 MW of wind farms, generating annually a total of 741 GWh of energy, could be installed in Burkina Faso. On the other hand, a total of 4411 MW of small wind turbines (50 kW) could be installed over the territory, corresponding to an annual energy production of 7843 GWh. The Wind Atlas of Burkina Faso provides an opportunity for local stakeholders to consider wind energy for the electricity portfolio of the country.