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41.
Patrik L. Andersson Peter Haglund Mats Tysklind 《Environmental science and pollution research international》1997,4(2):75-81
The internal barrier of rotation (Erot) was calculated for all 209 polychlorinated biphenyls (PCBs) by using a semi-empirical
method, viz. the Austin Model 1 (AMI) Hamiltonian. The difference in total energy between a forced planar state and an optimised
twisted structure was defined as Erot. The Erot values were in the range of 8.33 to 483 kj/mol, and were significantly influenced
by the number of chlorine atoms inortho position. An additional structural characteristic of the PCBs influencing Erot ofortho substituted congeners was substitution by chlorine atoms in vicinalmeta positions, which is assumed to prevent outward bending ofortho substituents. This so-called buttressing effect contributed with 4 to 31 kj/mol per added chlorine atom. In conclusion, the
internal barrier of rotation, calculated for all 209 PCBs, provides an important structure dependent physico-chemical parameter
for multivariate modelling of future quantitative structure-activity and structure-property relationships (QSARs/QSPRs). 相似文献
42.
43.
The geochemistry, mineralogy, acidity and electric conductivity of sulphide-bearing postglacial sediments located on the coastal plains of western Finland were studied. Grain size and mineralogical analysis (eight samples studied) indicated that the sediments are silts dominated by primary minerals (quartz, feldspars), and that the clay fraction (<2µm), which made up less than one-third of the bulk samples, is enriched in phyllosilicates but depleted in quartz and feldspars, relative to bulk samples. As compared to the metal contents of the fine-fraction of glacial till (data of the Geological Survey of Finland), the fine sediments appear to be enriched in sulphur (median = 0.54%) and trace metals such as Ni (31 µg g–1), Zn (90 µg g–1), Co (13 µg g–1), Cr (48 µg g–1) and V (50 µg g–1). Statistical analysis indicated that aluminosilicates are the principal carrier phases of trace metals, and that sulphides and organic matter only partially control the distribution of elements other than S and C. A 3-g portion of 232 samples was oxidised in the laboratory by atmospheric oxygen for a period of 1 year. After this period of oxidation, 15 ml of water was added, after which pH and electric conductivity of the suspensions (sediment:water, 1:5) were measured. The quantities of elements mobilised by the oxidation was calculated from the dissolved concentrations found in 3 g of oxidised sediment suspended in 30 ml of deionised water (eight samples studied). The results of the experiment showed that the impact of sulphide oxidation on the pH and conductivity of the sediments is large, and that a high proportion (>13%) of the aqua-regia extractable contents of several elements (Co, Mn, Ca, Ni, Zn, Sr, Na and B) are mobilised at oxidation. Because of the high quantities of acidity and metals liberated at oxidation, it is argued that stream-water quality, which is poor in the study area, will not improve unless artificial draining is restricted in areas of sulphide sediments. 相似文献
44.
Åke Berg Bengt Ehnström Lena Gustafsson Tomas Hallingbäck Mats Jonsell Jan Weslien 《Conservation biology》1995,9(6):1629-1633
45.
Mats Olsson 《Behavioral ecology and sociobiology》1994,34(3):169-173
A honey bee (Apis mellifera) queen mates with about ten haploid drones, thus producing colonies composed of about ten subfamilies of super-sisters. An increasing but controversial body of literature supports the views that: (1) Members of each subfamily within a colony can recognise each other, and distinguish supersisters from half-sisters. (2) Members of each subfamily use this recognition information and increase the reproductive fitness of their own subfamily at the expense of half-sisters through behaviour termed nepotism. A mathematical model is developed that shows that task specialisation by subfamilies, and bees that repeatedly undertake the behaviour within subfamilies, can influence the numbers of interactions among super-sisters, relative to the numbers of interactions between half-sisters. The model is then evaluated using a data set pertaining to trophallaxis behaviour in a two-subfamily colony. It is concluded that with this data set, task specialisation and subfamily recognition were indeed confounded, suggesting that the apparent subfamily recognition could easily have been an artefact of task specialisation.
Correspondence to: B.P. Oldroyd 相似文献
46.
Mats Olsson 《Behavioral ecology and sociobiology》1993,32(5):337-341
Summary Male sand lizards (Lacerta agilis) are polygynous and guard individual females for several hours to days after copulation. Even though the copulation itself only lasts 2–4 min, the total time that a male invests per female is considerably more and may constitute a substantial investment during a mating season. In such situations, when male copulation frequency is constrained, or when variation in female fecundity is high, mate choice by males may be adaptive. Large body size in female sand lizards is correlated with higher fecundity. In choice experiments performed in the laboratory, male sand lizards preferred to court large females rather than small females. In addition, when there was little difference in size between the females in the experiment, the males visited the two females more often before they started to court the preferred female. The results from a field study during 1984 and 1987–1990 showed that females are non-aggressive, have small neighboring home ranges (c. 100 m2) and may share burrows and sites for thermoregulation. This means that females can be found close together and thus gives males the opportunity to choose a mate. Assortative mating with respect to size was observed in a natural population, as well as a limited number of direct choices of females by males. These results support the results of the choice experiment. 相似文献
47.
48.
Charlotta Pers Lars Rahm Anders Jonsson Ann-Kristin Bergström Mats Jansson 《Environmental Modeling and Assessment》2001,6(3):159-172
The organic carbon balance of a lake with high input of allochthonous organic carbon is modelled integrating physical, chemical and biological processes. The physical model captures the behaviour of real thermal stratification in the lake for different flow situations during the period 1993–1997. The dissolved organic carbon model is based on simulated trajectories of water parcels. By tracking parcels, account is kept of environmental factors such as temperature and radiation as well as DOC quality for each parcel. The DOC concentration shows seasonal variations primarily dependent on inflow. The organic matter degradation (bacterial- and photodegradation) in the lake amounts to 1.5–2.5 mg C l–1 yr–1, where photooxidation is responsible for approximately 10%. The estimated DIC production in the lake is large compared to sediment mineralisation and primary production. The main conclusion is that the model with the selected parameterisations of the degradation processes reasonably well describes the DOC dynamics in a forest lake. 相似文献
49.
Martin Gullstrom Maricela de la Torre Castro Salomao O.Bandeira Mats Bjork Mattis Dahlberg Nils Kautsky Patrik Ronnback Marcus C.Ohman 《Ambio-人类环境杂志》2002,31(8)
海草是海洋被子植物,广泛分布在温带和热带的海岸带水域,是地球上水生生态系统中最具生产力的生物之一. 相似文献
50.
Cultivated and settlement areas were studied in a small area (14 km2) in South Wollo, Ethiopia, by aerial photos, satellite images, field observations and interviews. Areas for cultivation/rural settlement decreased a few per cent between 1958 and 2013. Cultivated land per household slowly decreased in 1958–2003 but in 2003–2013 the annual decrease was 3–4 times higher. New farm buildings are often built on cultivated land, and abandoned buildings areas return to cultivation. Rainwater harvesting ponds have increased the areas with perennial crops that are important as a source of income. Tin roofed buildings are signs of improved livelihood. Very small farm size and rain-dependent agriculture combined with climate variability make food security vulnerable. Land-use inventories including remote sensing and local knowledge would be a valuable approach to assess livelihood needs. Further, it should involve decision makers at different levels, but local agricultural extension officers may play a central role. 相似文献