Influence of arsenic co-contamination on DDT breakdown and microbial activity

The impacts of arsenic co-contamination on the natural breakdown of 1,1,l1-trichloro-2,2-bis(4-chlorophenyl)ethane (DDT) in soil are investigated in a study of 12 former cattle dip sites located in northeastern NSW, Australia. This study examines the relationship between the intrinsic breakdown of DDT to 1,1 -dichloro-2,2-bis(4-chlorophenyl)ethane (DDD) and 1,l-dichloro-2,2-bis(4-chlorophenyl)ethylene (DDE), and the impacts of arsenic co-contamination on this breakdown. Between-site analysis demonstrated that arsenic at 2000 mg/kg gave a 50% reduction in the concentration of DDD compared to background arsenic of 5 mg/kg.Within-site analysis also showed the ratio of DDT:DDD increased in soils as arsenic concentrations increased. This within-site trend was also apparent with the DDT:DDE ratio, suggesting inhibition of DDT breakdown by arsenic co-contamination. Microbial activity was inhibited as residues of total DDTs and arsenic increased. Hence arsenic co-contamination and high concentrations of DDT in soil may result in an increased persistence of DDT in the environment studied.     

Gaseous and particulate emissions from a DC arc melter

Tests treating soils contaminated with metal compounds and radionuclide surrogates were conducted in a DC arc melter. The soil melted, and glassy or ceramic waste forms with a separate metal phase were produced. Tests were run in the melter plenum with either air or N2 purge gases. In addition to nitrogen, the primary emissions of gases were CO2, CO, oxygen, methane, and oxides of nitrogen (NO(x)). Although the gas flow through the melter was low, the particulate concentrations ranged from 32 to 145 g/m3. Cerium, a nonradioactive surrogate for plutonium and uranium, was not enriched in the particulate matter (PM). The PM was enriched in cesium and highly enriched in lead.     

Prediction of the fate of radioactive material in the South Pacific Ocean using a global high-resolution ocean model

We investigate the release of radioactive contaminants from Moruroa Atoll in a global high-resolution off-line model. The spread of tracer is studied in a series of simulations with varying release depths and time-scales, and into ocean velocity fields corresponding to long-term annual mean, seasonal, and interannually varying scenarios. In the instantaneous surface release scenarios we find that the incorporation of a seasonal cycle greatly influences tracer advection, with maximum concentrations still found within the French Polynesia region after 10 years. In contrast, the maximum trace is located in the southeast Pacific when long-term annual mean fields are used. This emphasizes the importance of the seasonal cycle in models of pollution dispersion on large scales. We further find that during an El Ni?o/Southern Oscillation (ENSO) event reduced currents in the region of Moruroa Atoll result in increased concentrations of radioactive material in French Polynesia, as direct flushing from the source is reduced. In terms of the sensitivity to tracer release time-rates, we find that a gradual input results in maximum concentrations in the near vicinity of French Polynesia. This contrasts the instantaneous-release scenarios, which see maximum concentrations and tracer spread across much of the South Pacific Ocean. For example, in as little as seven years radioactive contamination can reach the east coast of Australia diluted by only a factor of 1,000 of the initial concentration. A comparison of results is made with previous studies. Overall, we find much higher concentrations of radionuclides in the South Pacific than has previously been predicted using coarser-resolution models.     

STATIC WATER LEVEL MAPPING IN EAST CENTRAL MICHIGAN1

ABSTRACT: This paper presents a methodology for preparing a static water level map using a sample of water level measurements obtained from the well log records of private wells that are finished in glacial drift. The test was conducted in Tyrone Township, located in east central Michigan. A variety of selection criteria were examined and the resulting maps were compared with a ground truth map that was prepared from water level measurements obtained in the field. The map prepared from a random sample of wells at a density of two points per section best approximates the ground truth map. Using a sample of records from the Michigan Statewide Groundwater Database to create static water levels that are used in community ground water vulnerability analyses will provide a more accurate map than using the complete dataset or other selection criteria based on temporal groupings or seasonality.     

The Roles of Photooxidation and Biodegradation in Long-term Weathering of Crude and Heavy Fuel Oils

Although spilled oil is subject to a range of natural processes, only combustion, photooxidation and biodegradation destroy hydrocarbons and remove them from the biosphere. We present laboratory data that demonstrate the molecular preferences of these processes, and then examine some oil residues collected from previously documented releases to confirm the important roles that these processes play in removing spilled oil from both marine and terrestrial environments.     

MULTISCALE INFLUENCES ON PHYSICAL AND CHEMICAL STREAM CONDITIONS ACROSS BLUE RIDGE LANDSCAPES1

ABSTRACT: Streams integrate biogeochemical processes operating at broad to local spatial scales and long term to short term time scales. Humans have extensively altered those processes in North America, with serious consequences for aquatic ecosystems. We collected data on Upper Tennessee River tributaries in North Carolina to: (1) compare landuse and landscape geomorphology with respect to their ability to explain variation in water quality, sedimentation measures, and large woody debris; (2) determine if landscape change over time contributed significantly to explaining present stream conditions; and (3) assess the importance of spatial scale in examining landuse influences on streams. Stream variables were related to both landuse and landscape geomorphology. Forest cover accounted for the most variation in nearly all models, supporting predictions of nutrient enrichment, thermal pollution, and sedimentation caused by landscape disturbance. Legacy effects from past catchment disturbance were apparent in sedimentation measures. Nitrogen and phosphorus concentrations, as well as stream temperature, were lower where riparian buffers had reforested. Models of stream physicochemistry fit better when predictors were catchment wide rather than more localized (i.e., within 2 km of a site). Cumulative impacts to streams due to changes in landuse must be managed from a watershed perspective with quantitative models that integrate across scales.     

Software,shareware and freeware: multiplex commitment to an electronic social exchange system

We observe the behavior of 37 authors of shared (i.e., non‐commercial) software for the Apple Newton in terms of multiplex commitment (committed to multiple related targets) and the helping behaviors directed at these multiple related targets. The behavior of these shared software authors show a pattern of commitment to related targets consistent with our expectations of multiplex commitment and relationships to two helping behaviors (the number of shared software programs produced, and the degree of sacrifice expected with that shared software). The related targets of commitment were the users of the software, other shared software authors, and the newsgroup that served as the electronic social exchange system, but not the FTP site that enabled the exchange or the Listserv that served as an additional electronic social exchange system. Copyright © 2002 John Wiley & Sons, Ltd.     

Energy planning and wood balances

Woodfuel balances are commonly used by energy planners in developing countries to determine the adequacy of woodfuel resources. Recently, critics have argued that wood balances are misleading in their simplicity, exaggerating both the severity of the woodfuel shortage and the need for planned interventions to solve that problem. This paper examines four different wood balances developed for Tanzania. While the four studies all indicate that areas with miombo woodlands are in the greatest wood surplus, the specific estimates for any given region may differ widely. Despite their shortcomings, energy planners need woodfuel balances to give an impression of the adequacy of woodfuel resources. However, if energy planning is to have any effect, these balances must represent the beginning, and not the end result, of the planning process. Planners must follow the wood-energy balance analysis with work utilizing local people to solve local problems.     

Benefits of protective fencing to plant and rodent communities of the western Mojave Desert,California

Human disturbance in the western Mojave Desert takes many forms. The most pervasive are livestock grazing and off-highway vehicle use. Over the past few decades several areas within this region have been fenced to preclude human disturbance. These areas provide opportunities to study the impact of human activities in a desert ecosystem. This paper documents the response of plant and small mammal populations to fencing constructed between 1978 and 1979 at the Desert Tortoise Research Natural Area, Kern County, California. Aboveground live annual plant biomass was generally greater inside than outside the fenced plots during April 1990, 1991, and 1992. The alien grassSchismus barbatus was a notable exception, producing more biomass in the unprotected area. Forb biomass was greater than that of alien annual grasses inside the fence during all three years of the study. Outside the fence, forb biomass was significantly higher than that of alien grasses only during spring 1992. Percent cover of perennial shrubs was higher inside the fence than outside, while no significant trend was detected in density. There was als more seed biomass inside the fence; this may have contributed to the greater diversity and density of Merriam's kangaroo rats (Dipodomys merriami), long-tailed pocket mice (Chaetodipus formosus), and southern grasshopper mice (Onychomys torridus) in the protected area. These results show that protection from human disturbance has many benefits, including greater overall community biomass and diversity. The significance and generality of these results can be further tested by studying other exclosures of varying age and configurations in different desert regions of the southwestern United States.     

ESTIMATING THE VALUE OF WATER AMONG REGIONAL ECONOMIC SECTORS USING THE 1972 NATIONAL INTERINDUSTRY FORMAT1

ABSTRACT: Recent growth in irrigated agriculture and metropolitan areas of the Western United States suggests that if growth continues, there will be a potential shortage in future water resources. Compound the expansion of agriculture and municipal demands with possible enaction of instream flow requirements, a method to allocate water among alternative economic sectors in the West is needed. In this study, an interindustry-linear programming model based on the 1972 national model format is used to allocate scarce water supplies among competing regional economic sectors. The shadow price of water and the sectorial value of water at different availabilities for each competing sector is derived. Also, economic sectors are ranked by value of water at different water availabilities.