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排序方式: 共有288条查询结果,搜索用时 234 毫秒
111.
Wienold J Recknagel S Scharf H Hoppe M Michaelis M 《Waste management (New York, N.Y.)》2011,31(3):530-535
The EU RoHS Directive (2002/95/EC of the European Parliament and of the Council) bans the placing of new electrical and electronic equipment containing more than agreed levels of lead, cadmium, mercury, hexavalent chromium, polybrominated biphenyl (PBB) and polybrominated diphenyl ether (PBDE) flame retardants on the EU market. It necessitates methods for the evaluation of RoHS compliance of assembled electronic equipment. In this study mounted printed circuit boards from personal computers were analyzed on their content of the three elements Cd, Pb and Hg which were limited by the EU RoHS directive. Main focus of the investigations was the influence of sample pre-treatment on the precision and reproducibility of the results. The sample preparation steps used were based on the guidelines given in EN 62321. Five different types of dissolution procedures were tested on different subsequent steps of sample treatment like cutting and milling. Elemental analysis was carried out using ICP-OES, XRF and CV-AFS (Hg). The results obtained showed that for decision-making with respect to RoHS compliance a size reduction of the material to be analyzed to particles ?1.5 mm can already be sufficient. However, to ensure analytical results with relative standard deviations of less than 20%, as recommended by the EN 62321, a much larger effort for sample processing towards smaller particle sizes might be required which strongly depends on the mass fraction of the element under investigation. 相似文献
112.
Heidrun Moschitz Andrea Hrabalova Matthias Stolze 《Journal of Environmental Policy & Planning》2016,18(4):406-425
To better understand the potential for successful and long-term establishment of environmental policy, the aim of this paper is to explore the network dynamics of a policy field that has become well established in the EU: organic farming. We look at the dynamics of the organic farming policy network in the Czech Republic over a period of 10 years by applying a comparative formal network analysis. We focused in particular on the distribution of power between actors and how capacities of policy actors have evolved between 2004 (its year of accession to the EU) and 2014. We conclude that the organic farming policy network in the Czech Republic has been highly dynamic and has changed from one that was decidedly influenced by organic sector organizations to a network centralized around the Ministry of Agriculture. However, the organic farming organization managed to maintain its good reputation for competence in organic farming policy, which creates opportunities for the organization to remain active in the policy debate. 相似文献
113.
Georg von Arx Matthias Dobbertin Martine Rebetez 《Environmental monitoring and assessment》2013,185(6):4483-4489
Quality control of long-term monitoring data of thousands and millions of individual records as present in meteorological data is cumbersome. In such data series, sensor drifts, stalled values, and scale shifts may occur and potentially result in flawed conclusions if not noticed and handled properly. However, there is no established standard procedure to perform quality control of high-frequency meteorological data. In this paper, we outline a procedure to remove sensor drift in high-frequency data series using the example of 15-year-long sets of hourly relative humidity (RH) data from 28 stations subdivided into 202 individual sensor operation periods. The procedure involves basic quality control, relative homogeneity testing, and drift removal. Significant sensor drifts were observed in 40.6 % of all sensor operation periods. The drifts varied between data series and depended in a complex, usually inconsistent way on absolute RH values; within single series for instance, a drift could be negative in the lower RH range and positive in the upper RH range. Detrending changed RH values by, on average, 1.96 %. For one fifth of the detrended data, adjustments were 2.75 % and more of the measured value, and in one tenth 4.75 % and more. Overall, drifts were strongest for RH values close to 100 %. The detrending procedure proved to effectively remove sensor drifts. The principles of the procedure also apply to other meteorological parameters and more generally to any time series of data for which comparable reference data are available. 相似文献
114.
Schmitt C Oetken M Dittberner O Wagner M Oehlmann J 《Environmental pollution (Barking, Essex : 1987)》2008,152(2):322-329
The two UV screens 3-benzylidene-camphor (3-BC) and 3-(4'-methylbenzylidene)-camphor (4-MBC) were tested regarding their toxicity and estrogenic activity. The Yeast Estrogen Screen (YES) and two sediment assays with the freshwater invertebrates Lumbriculus variegatus and Potamopyrgus antipodarum were performed. In the YES, both substances activated the human estrogen receptor alpha with EC50 values of 44.2 microM for 3-BC and 44.3 microM for 4-MBC, whereby 4-MBC attained only 8% of the maximal response of 17beta-estradiol. For P. antipodarum embryo production increased after exposure to both substances (EC50 of 4.60 microM 4-MBC=1.17 mg kg(-1)dw) while mortality increased at high concentrations. The reproduction of L. variegatus was decreased by 3-BC with an EC50 of 5.95 microM (=1.43 mg kg(-1)dw) and also by 4-MBC, where no EC50 could be calculated. While reproduction decreased, the worms' weight increased after exposure to 3-BC with an EC50 of 26.9 microM (=6.46 mg kg(-1) dw), hence the total biomass remained unaffected. 相似文献
115.
Distinguishing between effects of natural and anthropogenic environmental factors on ecosystems is a fundamental problem in environmental science. In river systems the longitudinal gradient of environmental factors is one of the most relevant sources of dissimilarity between communities that could be confounded with anthropogenic disturbances. To test the hypothesis that in macroinvertebrate communities the distribution of species' sensitivity to organic toxicants is independent of natural longitudinal factors, but depends on contamination with organic toxicants, we analysed the relationship between community sensitivity SPEARorganic (average community sensitivity to organic toxicants) and natural and anthropogenic environmental factors in a large-scale river system, from alpine streams to a lowland river. The results show that SPEARorganic is largely independent of natural longitudinal factors, but strongly dependent on contamination with organic toxicants (petrochemicals and synthetic surfactants). Usage of SPEARorganic as a stressor-specific longitude-independent measure will facilitate detection of community disturbance by organic toxicants. 相似文献
116.
117.
Henner Hollert Ingo Haag Matthias Dürr Bernhard Wetterauer Roman Holtey-Weber Ulrich Kern Bernhard Westrich Harald F?rber Lothar Erdinger Thomas Braunbeck 《Umweltwissenschaften und Schadstoff-Forschung》2003,15(1):5-12
Schwebstoffgebundene Schadstoffe werden durch Sedimentation der Wasserphase und damit der Verfügbarkeit für viele aquatischen Organismen entzogen. W?hrend bei durchschnittlichen hydrologischen. Verh?ltnissen die Freisetzung von Schadstoffen aus stabil gelagerten Sedimenten meist weitgehend unterbunden wird, besteht bei Hochwassereignissen die Gefahr einer Remobilisierung von kontaminierten Ablagerungen. In diesem Beitrag wird ein kombiniertes ?kotoxikologisches und hydraulisches Untersuchungssystem zur Untersuchung der ?kotoxikologischen Belastung und des Erosionsrisikos von Sedimenten vorgestellt. Der integrierte Ansatz wurde am staugeregelten Neckar angewendet, um das Sch?digungspotenzial und die Gefahr einer Remobilisierung an Sedimentbohrkernen der Stauhaltung Lauffen sowie an Schwebstoffen zweier extremer Hochwasser zu überprüfen. Für die Bohrkernsegmente unterhalb einer Erosionsdiskordanz konnte eine sprunghafte Zunahme der ?kotoxikologischen Belastung ermittelt werden. Bei Hochwasserereignissen mit einer 5-j?hrlichen Wiederkehrwahrscheinlichkeit (=HQ5) k?nnen prinzipiell alle Sedimente, auch die st?rker kontaminierten und erosionsresistenteren Altsedimente, remobilisiert werden. W?hrend der Hochwasserereignisse (HQ15 bis HQ20) kam es zu einer deutlichen Erh?hung des cytotoxischen und mutagenen Sch?digungspotenzials der Schwebstoffe im Vergleich zu einem mittleren Hochwasser im Jahre 1995/96 (HQ1) Dies schien zumindest teilweise auf die Remobilisierung hochkontaminierter Altsedimente zurückzuführen zu sein. 相似文献
118.
119.
Temporal Segmentation of Human Short-Term Behavior in Everyday Activities and Interview Sessions 总被引:1,自引:0,他引:1
Human behavior is structured by serial order and timing of functionally related groups of movements with a duration of a
few seconds. These elementary action units have been described in ethological studies during unstaged everyday behavior, but
not during interview sessions. Psychomotor alterations are relevant for differential diagnosis and treatment, and psychiatric
patients are generally evaluated during interview sessions. Therefore the time structure of upper limb movements (n=764) of healthy subjects (n=22) were studied using videotaped interviews and frame-by-frame analysis and compared to movements (n=530) of unstaged human everyday behavior (n=154). The number of action units, but not their duration, was correlated inversely with self-reported impairment of mood
and pleasure experience in healthy persons. The temporal distribution of movements in interview sessions did not differ from
the time patterns of everyday behavior. This method could be a promising tool to investigate time patterns of movements and
psychomotor alterations in psychiatric patients during interview sessions.
Received: 29 October 1998 / Accepted in revised form: 29 December 1998 相似文献
120.
激光诱导荧光技术测量大气OH自由基的研究进展 总被引:2,自引:0,他引:2
大气氢氧自由基(OH)是对流层大气中最重要的氧化剂,对酸雨,平流层臭氧的损耗等有重要影响,激光诱导荧光技术是目前测定大气OH自由基中使用最多的测量方法。文章总结了20多年来国内外的研究成果,论述了激光诱导荧光技术用于测定大气OH自由基的基本原理和研究进展,讨论了测量中不确定因素及其对策,并着重介绍了目前最常用的基于气体扩张的低压荧光技术。 相似文献