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81.
Effect of different types of elemental sulfur on bioleaching of heavy metals from contaminated sediments 总被引:6,自引:0,他引:6
The application of two different types of elemental sulfur (S0) was studied to evaluate the efficiency on bioleaching of heavy metals from contaminated sediments. Bioleaching tests were performed in suspension and in the solid-bed with a heavy metal contaminated sediment using commercial sulfur powder (technical sulfur) or a microbially produced sulfur waste (biological sulfur) as substrate for the indigenous sulfur-oxidizing bacteria and thus as acid source. Generally, using biological sulfur during suspension leaching yielded in considerably better results than technical sulfur. The equilibrium in acidification, sulfur oxidation and metal solubilization was reached already after 10-14 d of leaching depending upon the amount of sulfur added. The metal removal after 28 d of leaching was higher when biological sulfur was used. The biological sulfur added was oxidized with high rate, and no residual S0 was detectable in the sediment samples after leaching. The observed effects are attributable to the hydrophilic properties of the biologically produced sulfur particles resulting in an increased bioavailability for the Acidithiobacilli. In column experiments only poor effects on the kinetics of the leaching parameters were observed replacing technical sulfur by biological sulfur, and the overall metal removal was almost the same for both types of S0. Therefore, under the conditions of solid-bed leaching the rate of sulfur oxidation and metal solubilization is more strongly affected by transport phenomena than by microbial conversion processes attributed to different physicochemical properties of the sulfur sources. The results indicate that the application of biological sulfur provides a suitable means for improving the efficiency of suspension leaching treatments by shortening the leaching time. Solid-bed leaching treatments may benefit from the reuse of biological sulfur by reducing the costs for material and operating. 相似文献
82.
Morville S Scheyer A Mirabel P Millet M 《Journal of environmental monitoring : JEM》2004,6(12):963-966
A method using GC-MS and derivatization with N-(t-butyldimethylsilyl)-N-methyltrifluoroacetamide (MTBSTFA) was developed for the analysis of 20 phenolic compounds in atmospheric samples (gas and particles). Air sampling was carried out using a Hi-Vol sampler with glass fibre filter and XAD-2 resin at a flow rate of 60 m(3) h(-1). The particle and gas phases were collected separately over a period of 4 h. Samples were Soxhlet extracted, evaporated to dryness under nitrogen and refilled with acetonitrile. 100 microl of these extracts were derivatized with 100 microl of MTBSTFA at 80 degrees C for 1 h under strong stirring. Phenolic compounds were injected into a GC-MS in splitless mode and quantified as their TBDMS derivatives in the SIM mode. Mass spectral analysis of the derivatives of the 20 compounds studied indicates that the spectra are highly specific showing an ion at [M - 57]+ which is useful for structure confirmation or analysis at low levels using selected ion monitoring. Quantification limits varied between 5 microg l(-1) and 10 microg l(-1) which correspond to 20 pg m(-3) and 40 pg m(-3) for 250 m(3) of air sampled. This method was successfully applied to atmospheric samples. 相似文献
83.
Hashem A. Faidi Luis A. Garcia Maurice M. Albertson 《Environmental Modeling and Assessment》2002,7(3):191-206
A model for simulation of solute transport in a dynamic stream–aquifer system is developed by integrating four existing sub-models. Interface packages are created to link the sub-models. The developed model is successfully used to simulate chloride transport in the stream–aquifer system of the Arkansas River and the Equus Beds Aquifer in Kansas and demonstrates that chloride concentration in the aquifer decreases in the vicinity of the simulated channel over time. 相似文献
84.
85.
Tema Milstein Mariko Thomas Jeff Hoffmann 《Environmental Communication: A Journal of Nature and Culture》2019,13(1):104-117
In this unprecedented era of anthropogenic ecological destruction, this study illustrates inadequacies in conceptual language available in Western settings to think deeply and holistically about “nature.” At the same time, the study illustrates transformative potential of moments of ecocultural reflexivity. Using free write methodology, we examine ways participants in the United States, New Zealand, and Australia articulate what they mean when they say “nature.” We interpret participant streams of consciousness as representative of a wider Western river-way, a channel of dominant, multiple, and contradictory meanings in continuous movement. We identify conceptual obstructions that provide glimpses into ways Western ecological relations are bounded and dammed by binary, fragmented, and unconsidered meanings. Yet reflexivity in the face of such obstructions, and in potent ecocultural side streams of childhood remembering and ecocentric cosmology, provides some participants a lucid flow of regenerative narratives at a time such shared stories are urgently needed. 相似文献
86.
Paul R.J. Saey Matthias Auer Emmy Hoffmann Anders Ringbom Clemens Schlosser 《Journal of environmental radioactivity》2010,101(9):730-738
Medical isotope production facilities (MIPF) have recently been identified to emit the major part of the environmental radioxenon measured at many globally distributed monitoring sites deployed to strengthen the radionuclide component of the Comprehensive Nuclear-Test-Ban Treaty (CTBT) verification regime. Efforts to raise a global radioxenon emission inventory revealed that the yearly global total emission from MIPF’s is around 15 times higher than the total radioxenon emission from nuclear power plants (NPP's).Given that situation, from mid 2008 until early 2009 two out of the ordinary hemisphere-specific events occured:1) In the Northern hemisphere, a joint temporary suspension of operations of the three largest MIPF's made it possible to quantify the effects of the emissions related to NPP’s. The average activity concentrations of 133Xe measured at a monitoring station close to Freiburg, Germany, went down significantly from 4.5 ± 0.5 mBq/m3 to 1.1 ± 0.1 mBq/m3 and in Stockholm, Sweden, from 2.0 ± 0.4 mBq/m3 to 1.05 ± 0.15 mBq/m3.2) In the Southern hemisphere the only radioxenon-emitting MIPF in Australia started up test production in late November 2008. During eight test runs, up to 6.2 ± 0.2 mBq/m3 of 133Xe was measured at the station in Melbourne, 700 km south-west from the facility, where no radioxenon had been observed before, originating from the isotopic production process.This paper clearly confirms the hypothesis that medical isotope production facility are at present the major emitters of radioxenon to the atmosphere. Suspension of operations of these facilities indicates the scale of their normal contribution to the European radioxenon background, which decreased two to four fold. This also gives a unique opportunity to detect and investigate the influence of other local and long distance sources on the radioxenon background. Finally the opposing effect was studied: the contribution of the start-up of a renewed radiopharmaceutical facility to the build up of a radioxenon background across Australia and the Southern hemisphere. 相似文献
87.
Rick Tinker Blake Orr Emmy Hoffmann Stephen Solomon 《Journal of environmental radioactivity》2010,101(5):353-361
The origin of a series of atmospheric radioxenon events detected at the Comprehensive Test Ban Treaty Organisation (CTBTO) International Monitoring System site in Melbourne, Australia, between November 2008 and February 2009 was investigated. Backward tracking analyses indicated that the events were consistent with releases associated with hot commission testing of the Australian Nuclear Science Technology Organisation (ANSTO) radiopharmaceutical production facility in Sydney, Australia. Forward dispersion analyses were used to estimate release magnitudes and transport times. The estimated 133Xe release magnitude of the largest event (between 0.2 and 34 TBq over a 2 d window), was in close agreement with the stack emission releases estimated by the facility for this time period (between 0.5 and 2 TBq). Modelling of irradiation conditions and theoretical radioxenon emission rates were undertaken and provided further evidence that the Melbourne detections originated from this radiopharmaceutical production facility. These findings do not have public health implications. This is the first comprehensive study of atmospheric radioxenon measurements and releases in Australia. 相似文献
88.
Krein A Audinot JN Migeon HN Hoffmann L 《Environmental science and pollution research international》2007,14(1):3-4
Background, Aim and Scope
Current scientific studies and evaluations clearly show that an increase of urban dust loads, alone or combined with other
pollutants und certain meteorological conditions lead to different significant health effects. Premature death, increased
hospital admissions and increased respiratory symptoms and diseases as well as decreased lung function can be observed in
combination with high pollutant levels. Sensitive groups like elderly people or children and persons with cardiopulmonary
diseases such as asthma are more strongly affected. Because of the direct contact between fine particles and lung tissue more
information concerning the surface structure (mapping of toxic elements) is required.
Materials and Methods:
The NanoSims50 ion microprobe images the element composition at the surface of sub-micrometer air dust particles and documents
hot spots of toxic elements as a possible threat for human health.
Results:
The atmospheric fine dust consists of a complex mixture of organic and inorganic compounds. Heavy metals are fixed on airborn
particles in the form of hot spots in a nanometer scale. From a sanitary point of view, the hot spots consisting of toxic
elements are particularly relevant as they react directly with the lung tissues.
Discussion:
To what extent particles can penetrate the various areas of the lungs and be deposited there depends on the one hand on their
physical characteristics and on the other on breathing patterns and the anatomy of the lung, which is subject to change as
the result of growth, ageing or illness. Once inhaled, some particles can reach the pulmonary alveoli and thus directly expose
the lung tissues to toxic elements.
Conclusions:
Especially the mapping of toxic arsenic or heavy metals like copper on the dust particles shows local hot spots of pollution
in the dimension of only 50 nanometers.
Recommendations and Perspectives:
Imaging of elements in atmospheric particles with NanoSIMS will help to identify the material sources. 相似文献
89.
Vincent G Kopferschmitt-Kubler MC Mirabel P Pauli G Millet M 《Environmental monitoring and assessment》2007,133(1-3):25-30
Quaternary Ammonium Compounds (QACs) are widely found in disinfectants used in hospitals. Benzalkonium chloride (BAC) and didecyldimethylammonium chloride (DDAC) predominate in the disinfecting formulations. These compounds are strong irritants and can play a role in the induction of Occupational Asthma among the professionals of health and cleaning. In order to evaluate the potential health effect of these quaternary ammonium compounds to hospital employers, the development of an analytical method for their quantification in indoor air was developed. DDAC aerosols are trapped by adsorption on XAD-2 resin SKC tube. The air in hospital buildings was sampled using a constant debit Gillian pump at a flow of 1.0 l/min (+/-5%). Ion Chromatography (IC) was chosen for the analysis of DDAC especially for its high sensitivity and specificity. The Limit of Detection (LOD) by IC for DDAC is 0.56 mug/ml. Therefore the LOD of atmospheric DDAC is 28 microg/m(3) with an air volume of 100 l and a desorption volume of 5 ml. All DDAC air samples were lower than the LOD of the analytical method by IC. Under the standard conditions of use of the disinfecting solutions (Surfanios, Ampholysine Plus and Amphospray 41), the insignificant volatility of DDAC would not seem to be able to contaminate the indoor hospital atmosphere during the disinfection process. However, the DDAC can contaminate working atmospheres if it is put in suspension by aerosolisation. 相似文献
90.
Delhomme O Millet M 《Environmental science and pollution research international》2012,19(5):1791-1799