Utilization of Cellulosic Wastes in Textile and Garment Industries: 2. Synthesis and Characterization of Cellulose Acetate from Knitted Rag

Cellulose acetate (CA) was synthesized from knitted rag, a cellulosic waste of Textile and Garment industries, in the glacial acetic acid, and subsequently acetic anhydride (Ac₂O) in presence of concentrated H₂SO₄ reaction medium. A low to high substitution products were obtained from single step up to seven steps acetylation of cellulose. In this way, it was possible to produce low cost and different grades or substituted acetylation derivatives of cellulose. The synthesized CA was characterized and investigation of its physical characteristics was done. Solubility, acetyl content, acetic acid content, degree of substitution, and molecular weight of CA increased gradually with the increase of the number of reaction steps attaining optimum value at the fourth step. The acetyl and acetic acid content of CA were increased from 39.95 % to 44.25 %, and from 55.73 % to 61.73 % respectively. Similarly, degree of substitution and molecular weight of CA were increased from 2.47 to 2.94, and from 74,249 to 121,437 respectively.     

Simplified Fabrication of Optically Transparent Composites Reinforced with Nanostructured Chitin

Optically transparent films reinforced with micro to nano scale chitin particles were successfully developed in this study. Chitin composites based on micro scale particles which are larger than the optical wavelength do not cause light scattering provided that chitin particles are composed of nano structure networks which allow monomer impregnation and polymerization. This could lead a simplified process for fabricating transparent composites. The composites reinforced by the chitin micro particles not only retained the transparency of the plastic but also helped the effectiveness of its co-efficient of thermal expansion as similar to chitin nanofibers. Furthermore, chitin nanofibers transparent films are thermally stable against temperature as high as 200 °C for a long period of time. This could lead to number of important commercial applications, and is a significant move towards the sustainable utilization of marine bio-resources.     

Gasification characteristics of biomass for tar removal by secondary oxidant injection

Gasification experiments for sawdust were conducted using a fixed bed reactor at 900 °C by varying the secondary oxidant injection ratio to determine the optimal conditions for tar removal along with the enhancement of gasification efficiency. Secondary oxidant was injected as an oxidant at the top zone of the gasifier in varying ratios of 10–30% of the total amount of oxidant. This method was based on the primary method of tar removal and gasification efficiency improvement by thermal cracking of tar. Various gasification performance parameters were evaluated and tar content was estimated by measuring the fluctuation of weight of the activated carbon filter. The results showed that the concentration of tar in the producer gas decreased by injecting the secondary oxidant, even though syngas yield decreased. The recycling potential of the char produced in the gasification experiments was also assessed with the purpose of utilizing char as an adsorbent by determining its surface area and pore volume. The results demonstrated that the char produced from the gasification experiment had similar quality to that of the activated carbon used in this experiment.     

Performance of Cow Dung Reinforced Biodegradable Poly(Lactic Acid) Biocomposites for Structural Applications

In this work, performance of cow dung (CD) reinforced poly(lactic acid) (PLA) biocomposites was investigated for the potential use in load bearing application. CD of average 4 mm size was blended with PLA at different CD ratios (0–50 wt%) and their effects on the biocomposite properties were studied. The results showed an improvement in the flexural properties, while the tensile and impact strength dropped by 20 and 28% with the addition of 50% CD. The decline in the tensile and impact strength was due to micro-cracking and voids formation at higher CD content. Also, the incorporation of CD slightly decreased the thermal stability of the biocomposite. However, dynamic mechanical properties of the biocomposites generally improved. SEM analysis of tensile and impact fractured surfaces indicated that the CD had a reasonable adhesion with matrix. Moreover, the SEM micrographs of soil burial studies showed an accelerated degradation of higher CD wt% biocomposites.     

Impediments to River Rehabilitation

Rehabilitation of river ecosystems is generally initiated when a river is no longer able to provide benefits to humans and other living beings. The major purposes of river rehabilitation projects are improving water quality, conserving nature, rehabilitating fisheries and riparian habitats, flood mitigation, and creating recreational opportunities. For a river rehabilitation project to be successful, it must have specific and clearly explained objectives, although these objectives will vary for each project depending upon factors such as economics, public demand, ecosystem benefits, and the like. In this article, we provide a critical analysis of the purposes that drive river rehabilitation projects and we identify and discuss impediments that can cause a project to deviate from its intended goals. We also discuss major constraints on rehabilitation efforts that can result in failed projects.     

Recent changes in ecosystem services and human well-being in the Bangladesh coastal zone

This study takes an historical approach in order to establish how the form and function of the social-ecological system that represents the Bangladesh south-western coastal zone has changed over recent decades. Time series data for a range of ecosystem services and drivers are analysed to define the range of trends, the presence of change points, slow and fast variables and the significant drivers of change. Since the 1980s, increasing gross domestic product and per capita income mirror rising levels of food and inland fish production. As a result, the size of population below the poverty line has reduced by ~17 %. In contrast, non-food ecosystem services such as water availability, water quality and land stability have deteriorated. Conversion of rice fields to shrimp farms is almost certainly a factor in increasing soil and surface water salinity. Most of the services experienced statistically significant change points between 1975 and 1980, and among the services, water availability, shrimp farming and maintenance of biodiversity appear to have passed tipping points. An environmental Kuznets curve analysis suggests that the point at which growing economic wealth feeds back into effective environmental protection has not yet been reached for water resources. Trends in indicators of ecosystem services and human well-being point to widespread non-stationary dynamics governed by slowly changing variables with an increased likelihood of systemic threshold changes/tipping points in the near future. The results will feed into simulation models and strategies that can define alternative and sustainable paths for land management.     

Removal of thiobencarb in aqueous solution by zero valent iron

A cost-effective method with zero valent iron (ZVI) powder was developed for the purification of thiobencarb (TB)-contaminated water. The removal treatment was performed in the batch system. A sample solution of 10 ml containing 10 microg ml(-1) of TB could be almost completely treated by 100mg of ZVI at 25 degrees C for 12h of treatment time. Since the formation of chloride ion in the aqueous solution during the treatment of TB was observed, the removal of TB with ZVI may contain two processes: reduction (degradation) and adsorption. Because the present treatment for TB is simple, easy handling and cheap, the developed technology with ZVI can contribute to the treatment of agricultural wastewaters.     

Arsenic in shallow aquifer in the eastern region of Bangladesh: insights from principal component analysis of groundwater compositions

Probable sources and mechanisms of arsenic (As) release in shallow aquifer in eastern Bangladesh are evaluated using statistical analysis of groundwater compositions. Dissolved As in 39 samples ranged from 8.05 to 341.5 μg/L with an average of 95.14 μg/L. Ninety seven percent of wells exceed the WHO limit (10 μg/L) for safe drinking water. Principal component analysis is applied to reduce 16 measured compositional variables to five significant components (principal components—PCs) that explain 86.63% of the geochemical variance. Two component loadings, namely PC 1 and PC 2 (45.31% and 23.05%) indicate the natural processes within the aquifers in which organic matter is a key reactant in the weathering reactions. Four groups of wells are defined by the PCA and each group of wells represents distinct physicochemical characteristics. Among them, group III groundwater shows higher As concentration together with high concentrations of Fe, Mn, dissolved organic carbon, $\text{PO}_{4}^{3-}$ and $\text{HCO}_{3}^{-}$ than groups I and II. Speciation calculations suggest that only wells of group III are saturated with respect to siderite, and all groups of samples are supersaturated with respect of rhodochrosite. The relationship of As with these parameters in the different groups of wells of the study area suggests that reductive dissolution of Fe–Mn oxyhydroxides with microbially mediated degradation of organic matter is considered to be the dominant processes to release As in groundwater.     

Mercury contamination in the estuaries and coastal sediments of the Strait of Malacca

Fishers’ local ecological knowledge (LEK) is an additional tool to obtain information about cetaceans, regarding their local particularities, fishing interactions, and behavior. However, this knowledge could vary in depth of detail according to the level of interaction that fishers have with a specific species. This study investigated differences in small-scale fishers’ LEK regarding the estuarine dolphin (Sotalia guianensis) in three Brazilian northeast coastal communities where fishing is practiced in estuarine lagoons and/or coastal waters and where dolphin-watching tourism varies from incipient to important. The fishers (N?=?116) were asked about general characteristics of S. guianensis and their interactions with this dolphin during fishing activities. Compared to lagoon fishers, coastal fishers showed greater knowledge about the species but had more negative interactions with the dolphin during fishing activities. Coastal fishing not only offered the opportunity for fishers to observe a wider variety of the dolphin’s behavior, but also implied direct contact with the dolphins, as they are bycaught in coastal gillnets. Besides complementing information that could be used for the management of cetaceans, this study shows that the type of environment most used by fishers also affects the accuracy of the information they provide. When designing studies to gather information on species and/or populations with the support of fishers, special consideration should be given to local particularities such as gear and habitats used within the fishing community.