Investigation of acute toxicity of cadmium chloride (CdCl2 . H2O) metal salt and behavioral changes it causes on water frog (Rana ridibunda Pallas, 1771)

The 96-h LC(50) value of cadmium chloride (CdCl(2).H(2)O), a metal salt widely used in industry, was determined in the water frog (Rana ridibunda Pallas, 1771). The experiments were conducted in two series and a total of 140 frogs were used to determine acute toxicity. In addition, behavioral changes in the water frog were determined for each cadmium chloride concentration. Data obtained from the cadmium chloride investigation were evaluated by using the probit analysis statistical method and the 96 h LC(50) value for water frog was estimated to be 51.2 mg/l.     

Integrated assessment modeling of atmospheric pollutants in the Southern Appalachian Mountains. Part I: hourly and seasonal ozone

Recently, a comprehensive air quality modeling system was developed as part of the Southern Appalachians Mountains Initiative (SAMI) with the ability to simulate meteorology, emissions, ozone, size- and composition-resolved particulate matter, and pollutant deposition fluxes. As part of SAMI, the RAMS/EMS-95/URM-1ATM modeling system was used to evaluate potential emission control strategies to reduce atmospheric pollutant levels at Class I areas located in the Southern Appalachians Mountains. This article discusses the details of the ozone model performance and the methodology that was used to scale discrete episodic pollutant levels to seasonal and annual averages. The daily mean normalized bias and error for 1-hr and 8-hr ozone were within U.S. Environment Protection Agency guidance criteria for urban-scale modeling. The model typically showed a systematic overestimation for low ozone levels and an underestimation for high levels. Because SAMI was primarily interested in simulating the growing season ozone levels in Class I areas, daily and seasonal cumulative ozone exposure, as characterized by the W126 index, were also evaluated. The daily ozone W126 performance was not as good as the hourly ozone performance; however, the seasonal ozone W126 scaled up from daily values was within 17% of the observations at two typical Class I areas of the SAMI region. The overall ozone performance of the model was deemed acceptable for the purposes of SAMI's assessment.     

Removal of organophosphorus pesticides from water by electrogenerated Fenton's reagent

Aqueous solutions of organophosphorus pesticides were completely mineralized via in-situ generated hydroxyl radicals (HO^·) by the Electro-Fenton process. Formation of Fenton's reagent (H₂O₂, Fe²⁺) was carried out by simultaneous reduction of O₂ and Fe³⁺ on carbon cathode in acidic medium. The electrochemistry combined with Fenton's reagent provides an excellent way to continuously produce the hydroxyl radical, a powerful oxidant. We demonstrate the efficiency of the Electro-Fenton process to degrade three organophosphorus insecticides: malathion, parathion ethyl and tetra-ethyl-pyrophosphate (TEPP). Degradation kinetics and removals of chemical oxygen demand (COD) have been investigated. Here we show that the mineralization efficiency was over 80% for three organophosphorus pesticides.     

Removal of MCPA from aqueous solutions by acid-activated spent bleaching earth

The removal of MCPA (4-chloro-2-methyl phenoxyacetic acid) from aqueous solutions by activated spent bleaching earth (SBE) was studied as a function of time, initial concentration, adsorbent concentration, and temperature. The Langmuir and Freundlich isotherms were fitted by the adsorption data obtained. The values of Langmuir and Freundlich constants were determined. The adsorption kinetics was described by the Lagergren equation. Mass transfer coefficient and thermodynamic parameters were also calculated. Column experiments were conducted and brekthrough capacities were found for different concentrations and different flow rates. The study demonstrates that acid-treated SBE could be used as an efficient adsorbent for the removal of MCPA-bearing wastewater effluents.     

Investigation of acute toxicity and the effect of cadmium chloride (CdCl2 . H2O) metal salt on behavior of the guppy (Poecilia reticulata)

In this study 96-h LC50 value of cadmium chloride (CdCl2 . H2O), a metal salt widely used in industry, was determined for the guppy (Poecilia reticulata, Pallas, 1859). The experiments were planned in four series of a total of 440 guppies employing the static test method of acute toxicity. 10 fish were placed in each replicate of each dose. The experiments were performed as four replicates, and behavioral changes in the guppy were determined for each cadmium chloride metal salt concentration. The data obtained were statistically evaluated by the use of EPA computer program based on Finney's Probit Analysis Method and a 96-h LC50 value for P. reticulata was found to be 30.4 mg/l in a static bioassay test system. This value was estimated to be 30.6 mg/l with Behrens-Karber's method. The two methods were in good agreement. 95% lower and upper confidence limits for the LC50 were 29.3 and 31.7 mg/l, respectively. The water temperature was kept between 21 and 23 degrees C. The behavioral changes observed in fish were, swimming in imbalanced manner, capsizing, attaching to the surface, difficulty in breathing and gathering around the ventilation filter.     

Diurnal photosynthesis, water use efficiency and light use efficiency of wheat under Mediterranean field conditions

Photosynthesis and transpiration rates of wheat leaves (Triticum aestivum L.) were measured at 30 min intervals under Mediterranean field conditions, using Photosynthesis Monitor system (PM-48M). The dynamics of net photosynthetic rate (P(N)), transpiration rate (E(T)), water use efficiency (WUE), light use efficiency (LUE), stomatal conductance (g(s)), photosynthetically active radiation (PAR), air temperature (T), relative humidity (RH), and atmospheric CO2 concentration (Catm) were quantified at five rainfed wheat sites with the same stages of development (midflowering) along south-to-north and east-to-west transects for eight days in April. Diurnal P(N) (3.6 to 6.6 micromol m(-2) s(-1)), PAR (392 to 564 micromol m2 sec(-1)), LUE (0.006 to 0.015) and WUE (0.0001 to 0.011) did not vary significantly across all five wheat sites (p > 0.05). P(N) and E(T) were strongly coupled and highly correlated with PAR (p < 0.001). Best multiple linear regression (MLR) models accounted for 92% of variations in P(N) as a function of PAR and E(T), and 90% in E(T) as a function of PAR and RH (p < 0.001). P(N) exhibited a peak at mid-morning, and a photosynthetic midday depression under the limiting effects of high evaporative demand. Diurnal variations in WUE and LUE showed a bimodal behavior with the maximum values in early morning and late afternoon. As the impacts of global climate change become increasingly felt, continuous measurements of climate-crop-soil-managementinteractions under natural conditions play a pivotal role not only in exploring changes in ecophysiological properties of strategic crops for food security such as wheat but also in devising preventive and mitigative management practices to ensure sustained agricultural productivity.     

Characterization of soil erosion and its implication to forest management

Forests have traditionally been managed to maximize timber production or economic profit, completely neglecting other forest values. Nowadays, however, forests are being managed for multiple uses. The basic requirement of multiple use forestry is to identify and quantify forest values and to determine management objectives. The priorities of management objectives, however, must be decided. In this study, a model predicting the soil loss for multi objective forest management was developed. The model was based on data from remeasurement of permanent sample plots. The data were gathered from 132 sample plots. Approximately 80% of the observations were used for model development and 20% for validation. The model was designed for even aged and uneven aged forests, as well as for forests with mixed and pure species composition. The explicatory variables in the model were mean diameter and number of trees. All parameter estimates were found highly significant (p < 0.001) in predicting soil loss. The model fit and validation tests were fairly good. The soil loss model presented in this paper was considered to have an appropriate level of reliability. It can be used in the overall multi-objective forest management planning, but, it should be limited to the conditions for which the data were gathered.     

Teil II: Analytik von Toxaphenrückst?nden (UWSF 2/1998)

Zusammenfassung  Die Rückstandsanalytik des Insektizides Toxaphen galt früher als problematisch wegen der gro?en Anzahl an Komponenten mit ?hnlicher Struktur und unterschiedlichem Chlorgehalt. Erschwerend kam hinzu, da? die Zusamensetzung von Toxaphenrückst?nden in Umweltproben sich von der des technischen Standards signifikant unterscheidet. Deshalb war die Quantifizierung einzelner Komponenten früher nicht m?glich. Seit jedoch eine ganze Reihe von Toxaphenkomponenten in ausreichenden Mengen isoliert wurden, von denen einige für Umweltproben repr?sentativ sind, besteht die M?glichkeit, Toxaphenrückst?nde in Umweltkompartimenten zuverl?ssig zu bestimmen. In der letzten Zeit konzentriert sich die Entwicklung vor allem auf die Trennung der chiralen Bestandteile des Gemisches, um anhand der Zusammensetzung der Rückst?nde Verteilungswege und Abbaumechanismen besser identifizieren zu k?nnen.

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Residue analysis of toxaphene has been difficult because of the complexicity of the technical mixture consisting of a high number of compounds with very similar structure and differing chloro content. Furthermore, the composition of toxaphene in environmental samples varies widely and is normally not like that of the technical mixture. Therefore, quantification of single components in environmental samples was impossible. After the isolation and identification of a great number of components during the last decade, enough standards are available for reliable quantification of toxaphene in all environmental compartments. Recently, most research has been done on the separation of chiral components of toxaphene with a view to identify degradation mechanisms and distribution pathways.

     

The occurrence and environmental effect of persistent organic pollutants (POPs) in Taurus Mountains soils

Purpose  

Persistent organic pollutants (POPs) are of global concern due to their ubiquitous presence and toxicity. The occurence of polychlorinated dibenzo-p-dioxins (PCDDs), -dibenzofurans (PCDFs), co-planar biphenyls (PCBs), hexachlorocyclohexanes (HCH), dichlorodiphenyltrichloroethanes (DDT), and organochlorine pesticides (OCPs) in forest soil collected from Taurus mountains may have adverse effects on the environment and health. The aim of the study was to investigate the outcome and distribution of POPs in the environment and the possible grasshopper effect along an altitude transect from sea level up to nearly 2,000 m a.s.l at a spatial distance of about 60 km in the southeastern Turkish Mediterranean Sea.     

Assessment of imidacloprid toxicity on reproductive organ system of adult male rats

In the current study it was aimed to investigate the toxicity of low doses of imidacloprid (IMI) on the reproductive organ systems of adult male rats. The treatment groups received 0.5 (IMI-0.5), 2 (IMI-2) or 8 mg IMI/kg body weight by oral gavage (IMI-8) for three months. The deterioration in sperm motility in IMI-8 group and epidydimal sperm concentration in IMI-2 and IMI-8 groups and abnormality in sperm morphology in IMI-8 were significant. The levels of testosterone (T) and GSH decreased significantly in group IMI-8 compared to the control group. Upon treatment with IMI, apoptotic index increased significantly only in germ cells of the seminiferous tubules of IMI-8 group when compared to control. Fragmentation was striking in the seminal DNA from the IMI-8 group, but it was much less obvious in the IMI-2 one. IMI exposure resulted in elevation of all fatty acids analyzed, but the increases were significant only in stearic, oleic, linoleic and arachidonic acids. The ratios of 20:4/20:3 and 20:4/18:2 were decreased and 16:1n-9/16:0 ratio was increased. In conclusion, the present animal experiments revealed that the treatment with IMI at NOAEL dose-levels caused deterioration in sperm parameters, decreased T level, increased apoptosis of germ cells, seminal DNA fragmentation, the depletion of antioxidants and change in disturbance of fatty acid composition. All these changes indicate the suppression of testicular function.