人工湿地基质对NH4＋-N吸附性能

为研究建筑废物红砖和工业废物煤渣用作人工湿地脱氮基质的可行性,分别通过静态吸附实验和动态NHf—N去除效果实验进行考察。结果表明,红砖和煤渣对NH4＋-N最大静态吸附量分别为0．2533mg／g和0．0533mg／g,其吸附等温曲线均符合Freundlich型吸附方程,吸附常数分别为0．0419和0．0091;红砖煤渣组合对污水中NH4＋-N平均动态脱除率达到41．18％,高于红砖的37．63％和煤渣的30．92％。     

添加天然沸石和石灰对土壤镉形态转化的影响

采用土壤培养实验,研究镉污染土壤中添加沸石、石灰及两者配施对土壤pH值和土壤镉形态变化的影响。结果表明,土壤pH值随沸石用量的增加而增加,随培养时间呈现先增加后下降并逐渐趋于稳定的趋势,但均高于对照。高剂量石灰的处理对土壤pH的影响最大,与对照相比土壤pH提高了3.33个单位。在土壤5~50 d培养过程中,石灰处理的土壤交换态镉含量呈现先逐渐降低而后略有升高的趋势,其余处理均呈下降趋势。培养50 d后,高剂量的沸石、石灰及高剂量沸石与石灰配施处理的土壤交换态镉含量从5 d时的67.54、61.95和55.56 mg/kg降低至54.65、49.93和45.96mg/kg。相关分析表明,不同培养时期交换态镉含量与土壤pH值呈负相关关系。在10个处理中,L2Z3(石灰2 g/kg土和沸石60 g/kg土)组合处理效果最好,使土壤交换态镉含量下降了34.68%,碳酸盐结合态镉含量上升了4.30%,铁锰氧化结合态镉含量上升了16.97%,有机结合态镉含量上升了1.31%,残渣态镉含量上升了12.11%。     

Comparison of lignin peroxidase and horseradish peroxidase for catalyzing the removal of nonylphenol from water

Concentrations of aqueous-phase nonylphenol (NP), a well-known endocrine-disrupting chemical, are shown to be reduced effectively via reaction with lignin peroxidase (LiP) or horseradish peroxidase (HRP) and hydrogen peroxide. We systematically assessed their reaction efficiencies at varying conditions, and the results have confirmed that the catalytic performance of LiP toward NP was more efficient than that of HRP under experimental conditions. Mass spectrum analysis demonstrated that polymerization through radical–radical coupling mechanism was the pathway leading to NP transformation. Our molecular modeling with the assistance of ab initio suggested the coupling of NP likely proceeded via covalent bonding between two NP radicals at their unsubstituted carbons in phenolic rings. Data from acute immobilization tests with Daphnia confirm that NP toxicity is effectively eliminated by LiP/HRP-catalyzed NP removal. The findings in this study provide useful information for understanding LiP/HRP-mediated NP reactions, and comparison of enzymatic performance can present their advantages for up-scale applications in water/wastewater treatment.     

中国陆上油藏CO2封存潜力评估

CO2捕集与封存是减缓气候变化的一种关键的碳减排选择方案。将CO2注入油藏作为一种碳埋存方式引起广泛关注。作为判断某一国家、某一区域或某一具体储层是否适合CO2地质封存开展的重要依据之一,有必要在规划碳捕集与封存(CCS)项目前,对潜在的封存库进行封存潜力评估。本文在已有可公开的地质资料的基础上,评估了中国陆上216个油田实施CO2地质封存的潜力,并与相关研究结果进行了比较。结果表明:在满足埋存深度大于800 m的筛选条件下,当假设我国陆上油田全部用于CO2-EOR时,CO2封存潜力约3.6 Gt;当陆上油田全部视为废弃油藏处理时,CO2理论封存潜力约4.6 Gt。其中,东北和华北地区油藏封存CO2潜力巨大,占陆上油田CO2封存总量的60%以上;同时这里CO2集中排放源分布密集,排放源和封存地间的匹配性良好,可以减少CO2运输和封存成本。在这两个地区可以优先考虑实施油藏封存CO2项目。     

基于WebGIS三峡干流水质模拟平台研究

三峡蓄水成库后仍属于典型的河道型水库,其总体水流、水质运动特性符合一维水流水质运动规律。针对三峡库区总体水流、水质运动特性,采用一维水流水质模型对三峡库区水流和水质进行了模拟。以该模型为核心,利用Web Services技术开发并在互联网上发布了模型服务,在此基础上采用成熟的WebGIS和富客户端Flex等技术构建了适用于三峡库区的干流水质模拟平台;能够实现包括各计算断面流速、流量、水位以及污染物浓度时空过程在内的三峡库区干流流速场和浓度场的数值模拟。以库区干流清溪场至十里铺断面内的江段作为模拟实例,利用该平台模拟计算江段内水流和水质状况,并以水文水质同步观测数据对模拟结果进行验证,结果表明其具有较好的模拟效果;为三峡库区污染物总体输移扩散特性研究提供了有利工具,同时也为国家和地方政府进行库区水环境决策提供了技术支持     

Evaluation of the Effectiveness of The Lead Peroxide Method for Atmospheric Monitoring of Sulfur Dioxide

This paper presents a simplified analysis to determine the variables that affect the empirical correlation factor used in the lead peroxide method. The rate of sulfation has been determined from two different models. In the first model, the mass transfer rate is calculated from the gas phase resistance alone whereas in the second model, the diffusion resistance in the gel phase is assumed to be the rate limiting step. Although the gas phase and the gel phase resistances may be both important in the actual case, it has been found that the correlation factor based on the first model is adequate to describe general experimental observations. Reasonable agreement has been obtained between the measured and the calculated va|ue of the correlation factor.     

The influence of mariculture on mercury distribution in sediments and fish around Hong Kong and adjacent mainland China waters

To study the influence of mariculture on mercury (Hg) speciation and distribution in sediments and cultured fish around Hong Kong and adjacent mainland China waters, sediment samples were collected from six mariculture sites and the corresponding reference sites, 200-300 m away from the mariculture sites. Mariculture activities increased total mercury, organic matter, carbon, nitrogen and sulfur concentrations in the surface sediments underneath mariculture sites, possibly due to the accumulation of unconsumed fish feed and fish excretion. However, methylmercury (MeHg) concentrations and the ratio of MeHg to THg (% MeHg) in sediments underneath mariculture sites were lower than the corresponding reference sites. The % MeHg in sediments was negatively correlated (r = −0.579, p < 0.05) with organic matter (OM) content among all sites, indicating that OM may have inhibited Hg methylation in surface sediments. Three mariculture fish species were collected from each mariculture site, including red snapper (Lutjanus campechanus), orange-spotted grouper (Epinephelus coioides) and snubnose pompano (Trachinotus blochii). The average MeHg concentration in fish muscle was 75 μg kg⁻¹ (wet weight), and the dietary intake of MeHg through fish consumption for Hong Kong residents was 0.37 μg kg⁻¹ week⁻¹, which was lower than the corresponding WHO limits (500 μg kg⁻¹ and 1.6 μg kg⁻¹ week⁻¹).     

中国西部矿产资源产业集聚度与竞争力研究

促进矿产资源产业集聚是推动我国西部矿产资源产业发展的主要路径之一,开展我国西部矿产资源产业集聚度与产业竞争力相关性的研究可以为西部矿产资源产业竞争力提升提供相关决策指导.为分析矿产资源产业集聚对矿产资源产业竞争力和区域经济的推动作用,本文选取区位熵反映矿产资源产业集聚度,具体地,选择企业数量区位熵反映矿产资源产业区域集聚度.选取产业产值区位熵反映矿产资源产业经济集聚度;矿产资源产业竞争力则选取产值利润率借以反映.通过衡量我国西部9个矿产资源产业的区域集聚度、经济集聚度和产值利润率,得出我国西部大部分矿产资源产业仍停留于企业"扎堆"的区域集聚,经济集聚不足,尤其是下游加工业,这导致我国西部矿产资源产业集聚效应难以充分发挥,产值利润率低下;进一步的相关性分析表明,西部矿产资源产业集聚度与产业竞争力正相关,且经济集聚对产业竞争力的推动作用更强.因而,不仅要发展下游加工业,而且要提高产业集聚度尤其是经济集聚度,以更有效地推动我国西部矿产资源产业竞争力的提升.     

完善我国医疗废物集中处置收费政策的思考和建议

医疗废物处置收费政策是医疗废物处置产业化发展的重要前提和保障。当前,医疗废物处置收费政策执行难,欠费、漏费等问题非常突出,医疗废物集中收集十分困难。在对我国医疗废物处置收费政策进行全面分析和评估的基础上,对当前收费政策存在的主要问题和产生的原因进行了分析。以加快完善医疗废物处置收费政策为目标,从完善政策体系、加强监管执法、提高标准合理性、综合确定费用承担方、制定鼓励性的经济政策、提高宣传和缴费意识等方面,提出医疗废物处置收费政策改革完善的若干建议。     

三峡库区区域经济形势及其发展战略探讨

长江三峡工程是举世瞩目的大型水利水电工程,库区的经济发展问题与相关生态环境问题同样引人关注。三峡库区经济的发展不仅有利于整个长江上游地区的全面发展,而且关系到库区百万移民的生计和社会稳定的大局。基于区域经济理论,运用SWOT方法对三峡库区经济发展的现状进行了分析评价。通过库区经济发展优势、劣势、机遇和挑战因素的客观分析,结果发现,特色生态农业、沿江旅游、物流业将成为库区产业的优先发展方向,与民生相关的移民安稳致富、城乡统筹发展等政策则成为库区经济战略的重要选择。旨在进一步整合库区资源、优化产业结构、提高经济增长质量、提升整体经济实力,为库区制定具针对性的区域经济发展战略提供有益参考。