Synthesis of functionalized mesoporous material from rice husk ash and its application in the removal of the polycyclic aromatic hydrocarbons

Environmental Science and Pollution Research - The rice husk ash (RHA) was used as an alternative source of silica for the synthesis of the functionalized mesoporous material, which was used in the...     

An uptake and elimination kinetics approach to assess the bioavailability of chromium,copper, and arsenic to earthworms (Eisenia andrei) in contaminated field soils

The aim of this study was to determine the bioavailability of metals in field soils contaminated with chromated copper arsenate (CCA) mixtures. The uptake and elimination kinetics of chromium, copper, and arsenic were assessed in the earthworm Eisenia andrei exposed to soils from a gradient of CCA wood preservative contamination near Hartola, Finland. In soils contaminated with 1480–1590 mg Cr/kg dry soil, 642–791 mg Cu/kg dry soil, and 850–2810 mg Ag/kg dry soil, uptake and elimination kinetics patterns were similar for Cr and Cu. Both metals were rapidly taken up and rapidly excreted by Eisenia andrei with equilibrium reached within 1 day. The metalloid As, however, showed very slow uptake and elimination in the earthworms and body concentrations did not reach equilibrium within 21 days. Bioaccumulation factors (BAF) were low for Cu and Cr (< 0.1), but high for As at 0.54–1.8. The potential risk of CCA exposure for the terrestrial ecosystem therefore is mainly due to As.

     

A novel application of concentrated solar thermal energy in foundries

Scrap preheating in foundries is a technology that saves melting energy, leading to economic and environmental benefits. The proposed method in this paper utilizes solar thermal energy for preheating scrap, effected through a parabolic trough concentrator that focuses sunlight onto a receiver which carries the metallic scrap. Scraps of various thicknesses were placed on the receiver to study the heat absorption by them. Experimental results revealed the pattern with which heat is gained by the scrap, the efficiency of the process and how it is affected as the scrap gains heat. The inferences from them gave practical guidelines on handling scraps for best possible energy savings. Based on the experiments conducted, preheat of up to 160 °C and a maximum efficiency of 70 % and a minimum efficiency of 40 % could be achieved across the time elapsed and heat gained by the scrap. Calculations show that this technology has the potential to save around 8 % of the energy consumption in foundries. Cumulative benefits are very encouraging: 180.45 million kWh of energy savings and 203,905 t of carbon emissions cut per year across the globe. This research reveals immense scope for this technology to be adopted by foundries throughout the world.     

The ecology of the red fox (<Emphasis Type="Italic">Vulpes vulpes</Emphasis> L.) in the middle Lena River basin

The population of foxes in the central regions of Yakutia has grown by a factor of four to five during the period from 2000 to 2011–2012, following an increase in the abundance of voles from the genus Microtus. A total of 130 carcasses of foxes taken in 2007–2012 have been examined. Age- and sex-related variation in morphological features has been described. The demographic structure of the population has been studied by estimating animal age from annual layers in the recording structures. Changes in female fertility and involvement in reproduction depending on age and feeding conditions have been analyzed. Changes in the composition of fox diet caused by long-term population depression in the mountain hare and their effect on the dynamics of fox abundance have been revealed. Age- and sex-related characteristics of the condition factor in foxes and sex-related differences in their dietary preferences have been demonstrated.     

Spatial population structure of rare orchid species in rich fens in the central part of Murmansk oblast

The spatial structure of 10 populations of rare orchid species (Dactylorhiza incarnata, D. traunsteineri, Listera ovata) has been studied in rich fens sporadically occurring in Murmansk oblast. Two levels of plant aggregation within populations have been distinguished: (1) clusters of individuals and (2) isolated population subsets consisting of clusters. General spatial demographic features of orchid populations in the fens are small area (77 m²) and low ecological density (0.009 ind./m²). Characteristics of the population subsets (their number, area, composition, and distance to the neighboring subset) are species-specific and reflect the degree of species rarity in plant communities.     

On ecotones as foci of ant species richness in a forest nature reserve (case study of the Voronezh Biosphere Reserve)

The role of ecotones with different (sharp or smooth) spatial boundaries between forest and meadow in ant biodiversity preservation was studied at the right-of-way of a power line in the Voronezh Reserve. The ecotone with a sharp boundary between forest and meadow (transitional zone 2 m wide) had higher species richness of ants compared to the ecotones (also 2 m wide) with smooth boundary between forest and meadow.     

Characteristics of stone moroko population dynamics at different stages of naturalization in lake- and steam-type Dnieper reservoirs

The probable source of stone moroko, Pseudorasbora parva (Temminck & Schlegel, 1846), populations in lake- and stream-type Dnieper reservoirs was revealed. The dynamics and specific growth rates of these populations over 20 years were analyzed. The dynamic phase portrait method was used to determine the timing of stages in the process of invader naturalization and the periods when its populations were in equilibrium. The potential growth rates of P. parva populations in the Kremenchug and Dneprodzerzhinsk reservoirs were estimated.     

A review of vulnerability indicators for deltaic social–ecological systems

The sustainability of deltas worldwide is under threat due to the consequences of global environmental change (including climate change) and human interventions in deltaic landscapes. Understanding these systems is becoming increasingly important to assess threats to and opportunities for long-term sustainable development. Here, we propose a simplified, yet inclusive social–ecological system (SES)-centered risk and vulnerability framework and a list of indicators proven to be useful in past delta assessments. In total, 236 indicators were identified through a structured review of peer-reviewed literature performed for three globally relevant deltas—the Mekong, the Ganges–Brahmaputra–Meghna and the Amazon. These are meant to serve as a preliminary “library” of potential indicators to be used for future vulnerability assessments. Based on the reviewed studies, we identified disparities in the availability of indicators to populate some of the vulnerability domains of the proposed framework, as comprehensive social–ecological assessments were seldom implemented in the past. Even in assessments explicitly aiming to capture both the social and the ecological system, there were many more indicators for social susceptibility and coping/adaptive capacities as compared to those relevant for characterizing ecosystem susceptibility or robustness. Moreover, there is a lack of multi-hazard approaches accounting for the specific vulnerability profile of sub-delta areas. We advocate for more comprehensive, truly social–ecological assessments which respond to multi-hazard settings and recognize within-delta differences in vulnerability and risk. Such assessments could make use of the proposed framework and list of indicators as a starting point and amend it with new indicators that would allow capturing the complexity as well as the multi-hazard exposure in a typical delta SES.     

Spatiotemporal dynamics of geographical ranges of red deer (<Emphasis Type="Italic">Cervus elaphus</Emphasis>, Cervidae) and Siberian roe deer (<Emphasis Type="Italic">Capreolus pygargus</Emphasis>, Cervidae) in Yakutia

Patterns of expansion of geographical ranges of red deer and Siberian roe deer in Yakutia during the 20th century are considered. The area inhabited by red deer in Yakutia has increased almost fourfold over the past 50 years, with an expansion of over 200000 km² toward the northwest. The geographical range of roe deer in the Lena–Amga interfluve has also changed considerably during the same period. Roe deer sightings in the subarctic zone were reported. The structure of geographical ranges of the species under investigation in different ecological and geographical regions of Yakutia is discussed, and the factors influencing the transformation of geographical range borders are characterized.     

Dynamics of snowmelt water composition in conifer forests exposed to airborne industrial pollution

An analysis is made of the spatial variability of snowmelt water composition (within and between biogeocenoses), with regard to its long-term dynamics, in pine and spruce forests exposed to airborne industrial pollution from the Europe’s largest Severonikel Copper–Nickel Smelter Complex. Snowmelt waters from under the tree canopy, compared to those from intercrown areas, contain higher concentrations of chemical elements due to their washing and leaching from tree crowns. This is especially true of spruce forests, since the crowns of spruce trees have a high sorption capacity. Distinct trends in the long-term dynamics of snowmelt water composition, related to reduction of industrial emissions, are observed in background forest areas and defoliating forests but not in the vicinity of pollution sources. It is shown that the main factors determining these dynamics in forests of the Kola Peninsula are edificator tree species, airborne industrial pollution, and, possibly, an increase in the number of days with above-zero temperatures in the period of snow accumulation, which facilitates washing and leaching of chemical compounds from tree crowns.