Sequencing diurnal air flow patterns for ozone exposure assessment around Houston,Texas

Understanding the human health impacts of ground level ozone requires detailed knowledge of its spatial–temporal distribution beyond that provided by surface monitoring networks. Here, a novel methodology based on unsupervised multivariate statistical techniques has been developed and used to identify the transport and dispersion patterns of tropospheric ozone. The hierarchical clustering method is used to visualize air flow patterns at two time scales relevant for ozone buildup. Sequentially executed statistical methods consider hourly 1-h surface wind field measurements. First, clustering is performed at the hourly time scale to identify 1-h surface flow patterns. Then, sequencing is performed at the daily time scale to identify groups of days sharing similar diurnal cycles for the surface flow. Selection of appropriate numbers of air flow patterns allows inference of regional transport and dispersion patterns for understanding population exposure to ozone. The methods are applied to the Houston, Galveston, and Beaumont-Port Arthur, TX study domain. Representative hourly wind field patterns are determined for the entire 2004 ozone season. Then, sequencing is performed for the 32 days in exceedance of the NAAQS for 8-h ozone. Four diurnal flow patterns capturing different ozone exceedance scenarios are isolated; each scenario is associated with a distinct spatial distribution for atmospheric pollutants.     

Improving the Evaluation of Conservation Programs

Abstract: The evaluation of conservation programs is rare but increasingly important in improving their effectiveness. Regular evaluations of conservation programs and the implementation of recommendations resulting from such assessments are infrequent because of resistance by participants and lack of funding. Evaluations may be internal or external, depending on the purpose of the review and how broadly it is focused. We strongly recommend external peer review of long-term complex conservation programs every 5 years, supported by more frequent (annual) internal reviews. Criteria for success must encompass both biological and social measures and include learning and the application of new knowledge to management. Evaluations must also go beyond monitoring to assess the value of the program. We emphasize the need to include the organization and function of a conservation program (the process) in any evaluation in addition to substantive criteria for success, which usually involve biological measures (numbers). A dysfunctional program organization and process can as effectively cripple a conservation effort as can a major biological catastrophe. We provide examples of different types of conservation program evaluations, including moderated workshops and case-study analysis, and provide advice on the logistics and organization of the review, emphasizing the importance of the evaluation process itself to a successful outcome. One important aspect of an evaluation is having an individual with leadership ability and considerable expertise to organize the format and oversee the review process itself. Second, it is essential at the outset to ensure agreement among the program participants and the review committee on the goals and objectives of the conservation program, what is to be evaluated, and the criteria for defining success. Finally, the best evaluations are inclusive and involve all participants and stakeholders.     

Making Consistent IUCN Classifications under Uncertainty

Abstract: The World Conservation Union (IUCN) defined a set of categories for conservation status supported by decision rules based on thresholds of parameters such as distributional range, population size, population history, and risk of extinction. These rules have received international acceptance and have become one of the most important decision tools in conservation biology because of their wide applicability, objectivity, and simplicity of use. The input data for these rules are often estimated with considerable uncertainty due to measurement error, natural variation, and vagueness in definitions of parameters used in the rules. Currently, no specific guidelines exist for dealing with uncertainty. Interpretation of uncertain data by different assessors may lead to inconsistent classifications because attitudes toward uncertainty and risk may have an important influence on the classification of threatened species. We propose a method of dealing with uncertainty that can be applied to the current IUCN criteria without altering the rules, thresholds, or intent of these criteria. Our method propagates the uncertainty in the input parameters and assigns the evaluated species either to a single category (as the current criteria do) or to a range of plausible categories, depending on the nature and extent of uncertainties.     

Modeling Runoff Response to Land Cover and Rainfall Spatial Variability in Semi-Arid Watersheds

Hydrologic response is an integrated indicator of watershed condition, and significant changes in land cover may affect the overall health and function of a watershed. This paper describes a procedure for evaluating the effects of land cover change and rainfall spatial variability on watershed response. Two hydrologic models were applied on a small semi-arid watershed; one model is event-based with a one-minute time step (KINEROS), and the second is a continuous model with a daily time step (SWAT). The inputs to the models were derived from Geographic Information System (GIS) theme layers of USGS digital elevation models, the State Soil Geographic Database (STATSGO) and the Landsat-based North American Landscape Characterization classification (NALC) in conjunction with available literature and look up tables. Rainfall data from a network of 10 raingauges and historical stream flow data were used to calibrate runoff depth using the continuous hydrologic model from 1966 to 1974. No calibration was carried out for the event-based model, in which six storms from the same period were used in the calculation of runoff depth and peak runoff. The assumption on which much of this study is based is that land cover change and rainfall spatial variability affect the rainfall-runoff relationships on the watershed. To validate this assumption, simulations were carried out wherein the entire watershed was transformed from the 1972 NALC land cover, which consisted of a mixture of desertscrub and grassland, to a single uniform land cover type such as riparian, forest, oak woodland, mesquite woodland, desertscrub, grassland, urban, agriculture, and barren. This study demonstrates the feasibility of using widely available data sets for parameterizing hydrologic simulation models. The simulation results show that both models were able to characterize the runoff response of the watershed due to changes of land cover.     

Biological responses to sediment remediation based on thin layer placement near a former pulp mill in Ward Cove, AK (USA)

In 2001, 28 acres of the bottom of Ward Cove, AK (USA) were remediated using thin layer placement, to enhance the natural recovery of contaminated sediments. The remediated areas were part of an 80-acre area of concern identified offshore from the site of a former sulfite pulp mill. The primary chemicals of concern were those commonly associated with organic enrichment near pulp mills: ammonia and 4-methylphenol. The primary remedial objectives were to reduce the toxicity of the contaminated sediments and to stimulate colonization of the remediated areas by benthic macroinvertebrates. In 2004, the initial monitoring event for the remediated areas was conducted, and included evaluations of physical/chemical sediment variables (i.e., total organic carbon, grain size distribution, ammonia, and 4-methylphenol), sediment toxicity (i.e., using the 10-day amphipod survival test with Eohaustorius estuarius), and in situ benthic macroinvertebrate communities. Results of the monitoring event showed that conditions in the remediated areas had improved considerably in the 3 years since thin layer placement had occurred. At most stations, concentrations of both ammonia and 4-methylphenol were very low, and amphipod survival was >or=90%. In addition, benthic macroinvertebrates appeared to be rapidly colonizing the remediated areas, based on evaluations of several community metrics (i.e., taxa richness, diversity, and dominance), as well as key indicator species of organic enrichment and associated transitional areas (i.e., primarily the polychaetes Capitella capitata and Nephtys cornuta, and the bivalve molluscs Axinopsida serricata and Parvilucina tenuisculpta). In general, colonization was consistent with the patterns identified for areas recovering from organic enrichment on the continental shelf of southern California and elsewhere. Based on these results, thin layer placement was considered successful in enhancing the natural recovery of the remediated sediments in Ward Cove.     

Externalization of employment in a service environment: the role of organizational and customer identification

This study investigates the impact of employment externalization (in the form of limited‐term vs. permanent employment status) on customer‐oriented service behavior, and how identification processes may help to resolve the ‘paradox of externalization’ (i.e., organizations relying more on potentially disenfranchised employees to maintain strong connections with their customers). Survey data were obtained from 369 sales, service, and technical support personnel from the Canadian subsidiary of a large international service organization in the high technology sector. Organizational and customer identification fully mediate the relationship between employment status and customer‐oriented service behavior. Additionally, the perceived external image of the organization and the visibility of one's affiliation with the organization moderate the relationships between employment status and organizational and customer identification. Copyright © 2007 John Wiley & Sons, Ltd.     

A Systematic Review of Wild Burro Grazing Effects on Mojave Desert Vegetation,USA

Wild burros (Equus asinus), protected by the 1971 Wild Free-Roaming Horse and Burro Act on some federal lands but exotic animals many ecologists and resource mangers view as damaging to native ecosystems, represent one of the most contentious environmental management problems in American Southwest arid lands. This review synthesizes the scattered literature about burro effects on plant communities of the Mojave Desert, a center of burro management contentions. I classified 24 documents meeting selection criteria for this review into five categories of research: (i) diet analyses directly determining which plant species burros consume, (ii) utilization studies of individual species, (iii) control-impact comparisons, (iv) exclosure studies, and (v) forage analyses examining chemical characteristics of forage plants. Ten diet studies recorded 175 total species that burros consumed. However, these studies and two exclosure studies suggested that burros preferentially eat graminoid and forb groups over shrubs. One study in Death Valley National Park, for example, found that Achnatherum hymenoides (Indian ricegrass) was 11 times more abundant in burro diets than expected based on its availability. Utilization studies revealed that burros also exhibit preferences within the shrub group. Eighty-three percent of reviewed documents were produced in a 12-year period, from 1972 to 1983, with the most recent document produced in 1988. Because burros remain abundant on many federal lands and grazing may interact with other management concerns (e.g., desert wildfires fueled by exotic grasses), rejuvenating grazing research to better understand both past and present burro effects could help guide revegetation and grazing management scenarios.     

Cell preparation methods influence Escherichia coli D21g surface chemistry and transport in saturated sand

The effect of cell preparation methods on the surface chemistry and retention of Escherichia coli D21 g was investigated over a range of ionic strength conditions. The cell preparation methods that were considered included filtration and centrifugation (at various speeds and for different durations). For a given ionic strength condition, it was found that cells prepared by filtration were more negatively charged and hydrophobic than cells prepared by centrifugation. Increasing the centrifugation speed (force imposed) or duration produced cells with a higher zeta potential (less negative) and a lower hydrophobicity. Column transport experiments for E. coli D21 g were also conducted with ultra pure quartz sand and the same solution chemistries. The first-order retention rate coefficient for E. coli D21 g increased with increasing speed and duration of centrifugation, and was lowest in the case of filtered cells. Moreover, the influence of cell preparation method was more pronounced in lower ionic strength solutions.     

Toxicity and metal speciation characterisation of waste water from an abandoned gold mine in tropical northern Australia

The decommissioned Mount Todd gold mine, located in the wet-dry tropics of northern Australia, consists of a large waste water inventory and an acid rock drainage problem, which has the potential to impact upon freshwater ecosystems of the Edith River catchment. The toxicity of retention pond 1 (RP1) water was determined using six local freshwater species (duckweed, alga, cladoceran, snail, hydra and a fish). RP1 water was very toxic to all species, with the percentage dilution of RP1 water inhibiting 10% of organism response (IC(10)), or lethal to 5% of individuals (LC(5)), ranging from 0.007 to 0.088%. The percentage dilution of RP1 water inhibiting 50% of organism response (IC(50)), or lethal to 50% of individuals (LC(50)), ranged from 0.051% to 0.58%. Based on chemical analyses and geochemical speciation modelling of the test waters, Cu, Zn and Al were the most likely toxic components at acidic dilutions (i.e. 1%), while Cu and Zn were the most likely toxic components at 0.1% RP1 water, where pH was 6.5. Species sensitivity distributions (SSDs) were used to predict dilutions of RP1 water that would protect or unacceptably affect the downstream aquatic ecosystems. A dilution ratio of 1 part RP1 water to 20000 parts Edith River water (0.005% RP1 water) was calculated to be required for the protection of at least 95% of species. This information can be used in conjunction with field chemical and biological data to better predict the ecological risks of RP1 waste water downstream of the Mount Todd mine.