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11.
Environmental Science and Pollution Research - Male fertility and semen quality have declined over recent decades. Among other causes, exposure to environmental and occupational pollution has been...  相似文献   
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In recent years, an increasing number of regulations and methodologies have begun to utilize total organic carbon (TOC) analysis for monitoring microbial contamination and/or disinfectant byproduct (DBP) precursors. This paper highlights some analytical differences and similarities between the two widely used TOC oxidation techniques: UV persulfate and high temperature combustion (HTC). Previous papers have come to different and sometimes contradictory conclusions on this subject. However, these studies either compared instruments with significantly different flow paths or TOC systems from different eras. Unlike previous studies, this paper compares two modern TOC analyzers with nearly identical flow paths for sample recovery, detection limits, and analysis of real world samples. On average, both persulfate and HTC oxidation yielded good recoveries for 10 hard to oxidize compounds and potable water samples from 5 different locations across the USA. In general, persulfate yielded more precise results because of its lower background response relative to sample response while HTC gave slightly higher results (roughly 2% to 3%) for surface water samples.  相似文献   
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Over recent decades urban and regional development agendas in the United Kingdom have become dominated by the discourses of sustainable development, holistic regeneration and community capacity-building. It is in this context that brownfield development has emerged as a core feature in strategies to regenerate urban areas. Bringing brownfields back into use tends to be, a priori, presented as a 'good thing' that will have broader economic, environmental and social benefits. This paper assesses the role that brownfield development plays in urban and regional policy agendas in the UK. It begins by identifying the rationales for, and concerns associated with, the brownfield development process in the UK, before discussing the trajectories of policy under the New Labour government since 1997. It argues that at present too much is expected from brownfield-led regeneration programmes and that wider benefits will only accrue if these programmes are embedded within a wider and more comprehensive set of development projects and policy agendas.  相似文献   
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Sections of brood from colonies of the Cape honeybee ( Apis mellifera capensis), the African honeybee ( A. m. scutellata), and hybrid bees of the two races were exchanged between colonies to study the effect of different brood-origin/nurse-bee combinations on development of caste characters. When Cape larvae were raised by African workers the amount of food provided almost doubled in comparison with Cape larvae reared by their own workers. In contrast, African larvae raised by Cape workers were provided with only half the amount they received from their own workers. After the bees emerged, we found a large degree of plasticity in characters related to caste differentiation, which corresponded closely to the amount of food provided. Super-fed Cape bees had enlarged spermathecae, were heavier than normal workers and developed more rapidly, and had reduced pollen combs, all typical for a more queen-like condition. Ovariole numbers did not appear to be enhanced by additional feeding. Cape bees that behave as social parasites in African bee colonies were most queen-like in the characters studied, albeit within the range that was found for Cape bees from normal colonies, suggesting within-colony selection for characters that enhance reproduction.Communicated by R. Page  相似文献   
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In the Cape honey bee Apis mellifera capensis, workers lay female eggs without mating by thelytokous parthenogenesis. As a result, workers are as related to worker-laid eggs as they are to queen-laid eggs and therefore worker policing is expected to be lower, or even absent. This was tested by transferring worker- and queen-laid eggs into three queenright A. m. capensis discriminator colonies and monitoring their removal. Our results show that worker policing is variable in A. m. capensis and that in one colony worker-laid eggs were not removed. This is the first report of a non-policing queenright honey bee colony. DNA microsatellite and morphometric analysis suggests that the racial composition of the three discriminator colonies was different. The variation in policing rates could be explained by differences in degrees of hybridisation between A. m. capensis and A. m. scutellata, although a larger survey is needed to confirm this.  相似文献   
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Electrical resistance heating (ERH) is proving to be an effective technology to rapidly heat the subsurface and, in doing so, removing volatile organic compounds. Practitioners of this technology have observed that other processes (biodegradation, abiotic degradation, hydrolysis, and possibly others) occur to break down the chemicals of concern, and remediation is not solely accomplished through vaporization. Few sites treated using ERH have been monitored during and after treatment to identify and evaluate the processes occurring and assess the contribution of these other biological and chemical processes in the remediation effort so that they may be incorporated in the remediation design. At Fort Lewis, Washington, a landfill has been undergoing ERH treatment in three phases, where chlorinated volatile organic compounds represent the primary chemicals of concern in soil and groundwater. Other chemicals of concern include petroleum products, oils, and lubricants. The Fort Lewis remediation projects provided an opportunity to observe the reactions occurring in the subsurface during ERH and fine‐tune the study with each phase of operation. This study is still under way. However, the data gathered to date, which focuses on biodegradation, provides insights into the processes that have been observed. For the Fort Lewis site, biotic and abiotic degradation processes have been observed throughout the range of operating temperatures. At the lower temperature ranges (up to 70°C), biological processes appear to predominate. Above 70°C, abiotic processes become much more active. The goal of this work is to eventually optimize the use of these intrinsic processes in ERH remediation to reduce energy requirements and costs. © 2007 Wiley Periodicals, Inc.  相似文献   
18.
This paper analyzes potential impacts of climate change on biomass carbon (C) density and water-use (actual evapotranspiration, AET) of savannah woodlands in Sudan. Climate change scenarios were developed from five General Circulation Models (GCMs; CGCM2, CSIRO2, ECHam4, HadCM3 and PCM) under two IPCC (Intergovernmental Panel on Climate Change) emission scenarios (A1FI and B1). Baseline (1961-90) climate and climate change scenarios for 2080s for eight map sheet grids (1° latitude x 1.5° longitude) were constructed. Compared to baseline values, mean annual precipitation (MAP) showed both increases (+112 to +221 mm) and decreases (?13 to ?188 mm) but mean annual temperature (MAT) only showed increases (+1.2 to +8.3 °C). Baseline biomass C densities showed an exponential relationship with MAP (y?=?6.798 e 0.0054x, R2?=?0.70). Depending on climate change MAP, biomass C densities increased (+14 to +241 g C m?2) or decreased (?1 to ?148 g?C m?2). However, because of uncertainty in biomass C density estimates, the changes were only significant (P <0.05) for some of the climate change scenarios and for grids with MAP >260 mm. Under A1FI emission scenarios, only HadCM3 did not have a significant effect while under B1 emission scenarios, only CGCM2 and ECHam4 had a significant effect on biomass C density. AET also showed both increases (+100 to +145 mm for vertisols and +82 to +197 mm for arenosols) and decreases (?12 to ?178 mm for vertisols and ?12 to ?132 mm for arenosols). The largest relative changes in AET (up to 31 %) were associated with grids receiving the lowest rainfall. Thus, even if MAP increases across the study region, the increase will have little impact on biomass levels in the driest areas of the region, emphasizing the need for improved management and use of savannah woodlands.  相似文献   
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Objective: Derive lower leg injury risk functions using survival analysis and determine injury reference values (IRV) applicable to human mid-size male and small-size female anthropometries by conducting a meta-analysis of experimental data from different studies under axial impact loading to the foot–ankle–leg complex.

Methods: Specimen-specific dynamic peak force, age, total body mass, and injury data were obtained from tests conducted by applying the external load to the dorsal surface of the foot of postmortem human subject (PMHS) foot–ankle–leg preparations. Calcaneus and/or tibia injuries, alone or in combination and with/without involvement of adjacent articular complexes, were included in the injury group. Injury and noninjury tests were included. Maximum axial loads recorded by a load cell attached to the proximal end of the preparation were used. Data were analyzed by treating force as the primary variable. Age was considered as the covariate. Data were censored based on the number of tests conducted on each specimen and whether it remained intact or sustained injury; that is, right, left, and interval censoring. The best fits from different distributions were based on the Akaike information criterion; mean and plus and minus 95% confidence intervals were obtained; and normalized confidence interval sizes (quality indices) were determined at 5, 10, 25, and 50% risk levels. The normalization was based on the mean curve. Using human-equivalent age as 45 years, data were normalized and risk curves were developed for the 50th and 5th percentile human size of the dummies.

Results: Out of the available 114 tests (76 fracture and 38 no injury) from 5 groups of experiments, survival analysis was carried out using 3 groups consisting of 62 tests (35 fracture and 27 no injury). Peak forces associated with 4 specific risk levels at 25, 45, and 65 years of age are given along with probability curves (mean and plus and minus 95% confidence intervals) for PMHS and normalized data applicable to male and female dummies. Quality indices increased (less tightness-of-fit) with decreasing age and risk level for all age groups and these data are given for all chosen risk levels.

Conclusions: These PMHS-based probability distributions at different ages using information from different groups of researchers constituting the largest body of data can be used as human tolerances to lower leg injury from axial loading. Decreasing quality indices (increasing index value) at lower probabilities suggest the need for additional tests. The anthropometry-specific mid-size male and small-size female mean human risk curves along with plus and minus 95% confidence intervals from survival analysis and associated IRV data can be used as a first step in studies aimed at advancing occupant safety in automotive and other environments.  相似文献   
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