Unleaded Gasoline Shortages and Fuel Switching

The use of leaded gasoline in automobiles equipped with catalytic converters causes deactivation of the converters and leads to significant increases in emissions of reactive hydrocarbons, a precursor of ozone. Such fuel switching may be a contributing factor to the increase in photochemical smog levels recently observed in the South Coast Air Basin (SOCAB).     

Human health effects of residual carbon nanotubes and traditional water treatment chemicals in drinking water

The volume of industrial and domestic wastewater is increasing significantly year by year with the change in the lifestyle based on mass consumption and mass disposal brought about by the dramatic development of economies and industries. Therefore, effective advanced wastewater treatment is required because wastewater contains a variety of constituents such as particles, organic materials, and emulsion depending on the resource. However, residual chemicals that remain during the treatment of wastewaters form a variety of known and unknown by-products through reactions between the chemicals and some pollutants. Chronic exposure to these by-products or residual chemicals through the ingestion of drinking water, inhalation and dermal contact during regular indoor activities (e.g., showering, bathing, cooking) may pose cancer and non-cancer risks to human health. For example, residual aluminium salts in treated water may cause Alzheimer's disease (AD). As for carbon nanotubes (CNTs), despite their potential impacts on human health and the environment having been receiving more and more attention in the recent past, existing information on the toxicity of CNTs in drinking water is limited with many open questions. Furthermore, though general topics on the human health impacts of traditional water treatment chemicals have been studied, no comparative analysis has been done. Therefore, a qualitative comparison of the human health effects of both residual CNTs and traditional water treatment chemicals is given in this paper. In addition, it is also important to cover and compare the human health effects of CNTs to those of traditional water treatment chemicals together in one review because they are both used for water treatment and purification.     

Development of a new aerosol monitoring system and its application in Fukushima nuclear accident related aerosol radioactivity measurement at the CTBT radionuclide station in Sidney of Canada

A high volume aerosol sampler ("Grey Owl") has been designed and developed at the Radiation Protection Bureau, Health Canada. Its design guidance is based on the need for a low operational cost and reliable sampler to provide daily aerosol monitoring samples that can be used as reference samples for radiological studies. It has been developed to provide a constant air flow rate at low pressure drops (∼3 kPa for a day sampling) with variations of less than ±1% of the full scale flow rate. Its energy consumption is only about 1.5 kW for a filter sampling over 22,000 standard cubic meter of air. It has been demonstrated in this Fukushima nuclear accident related aerosol radioactivity monitoring study at Sidney station, B.C. that the sampler is robust and reliable. The results provided by the new monitoring system have been used to support decision-making in Canada during an emergency response.     

Building capacity with demand-driven partnerships: a case study of Partners for Water and Sanitation

Multi-stakeholder partnerships emerged from the 2002 Johannesburg World Summit on Sustainable Development (WSSD) as a new vehicle for progressing toward the Millennium Development Goals (MDGs) by aligning the interests of businesses, governments and civil society to leverage the impact of their interventions. The water and sanitation sector boasts the largest number of such partnerships, including the demand-driven capacity-building partnership Partners for Water and Sanitation (PAWS), a product of the WSSD and a premier UK partnership for sustainable development. Through its partnership network, PAWS has access to the entire UK water industry, which they assign to capacity-building projects in Africa on a demand-driven basis. Though the supply of partners is generally strong, the demand for their assistance is variable. This paper examines the efficacy of demand-driven capacity building partnerships at achieving the water and sanitation MDGs, presenting a case study of the PAWS partnership and using it as a framework for discussion of the supply–demand dynamics that influence the scope, scale and ultimate impact of such partnerships.     

Multi-scale analysis of oxygen demand trends in an urbanizing Oregon watershed, USA

Human alteration of the landscape has an extensive influence on the biogeochemical processes that drive oxygen cycling in streams. We estimated trends from the mid-1990s to 2003, using the seasonal Mann-Kendall's test, for percent saturation dissolved oxygen (DO), chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN), and ammonia-nitrogen (NH(3)-N) for 12 sites in the Rock Creek watershed, northwest Oregon, USA. In order to understand the influence of landscape change, scale, and stormwater runoff management on dissolved oxygen trends, we calculated land cover change through aerial photo interpretation at full-basin, local (near sample point) basin, and 100m stream buffer scales, for the years 1994 and 2000. Significant (p < or = 0.05) trends occurred in DO (increasing at five sites), COD (decreasing at seven sites), TKN (decreasing at five sites, increasing at one site), and NH(3)-N (decreasing at one site, increasing at one site). Significant land cover change occurred in agricultural land cover (-8% for the entire basin area) and residential land cover (+10% for the entire basin area) (p < or = 0.05). Correlation results indicated that: (1) forest cover negatively influenced COD at the full basin scale and positively influences NH(3)-N at local scales, (2) residential land cover influenced oxygen demand variables at local scales, (3) agricultural land cover did not influence oxygen demand, (4) local topography negatively influenced TKN and NH(3)-N, and (5) stormwater runoff management infrastructure correlated positively with COD at the local scale. This study indicates that landscape factors influencing DO conditions for the study streams act at multiple scales, suggesting that better knowledge of scale-process interactions can guide watershed managers' decision making in order to maintain improving water quality conditions.     

Models for the field-based toxicity of copper and zinc salts to wheat in 11 Australian soils and comparison to laboratory-based models

Laboratory-based relationships that model the phytotoxicity of metals using soil properties have been developed. This paper presents the first field-based phytotoxicity relationships. Wheat (Triticum aestivum L.) was grown at 11 Australian field sites at which soil was spiked with copper (Cu) and zinc (Zn) salts. Toxicity was measured as inhibition of plant growth at 8 weeks and grain yield at harvest. The added Cu and Zn EC10 values for both endpoints ranged from approximately 3 to 4760 mg/kg. There were no relationships between field-based 8-week biomass and grain yield toxicity values for either metal. Cu toxicity was best modelled using pH and organic carbon content while Zn toxicity was best modelled using pH and the cation exchange capacity. The best relationships estimated toxicity within a factor of two of measured values. Laboratory-based phytotoxicity relationships could not accurately predict field-based phytotoxicity responses.     

Dispersion modeling to compare alternative technologies for odor remediation at swine facilities

The effectiveness of 18 alternative technologies for reducing odor dispersion at and beyond the boundary of swine facilities was assessed in conjunction with an initiative sponsored through agreements between the Attorney General of North Carolina and Smithfield Foods, Premium Standard Farms, and Frontline Farmers. The trajectory and spatial distribution of odor emitted at each facility were modeled at 200 and 400 m downwind from each site under two meteorological conditions (daytime and nighttime) using a Eulerian-Lagrangian model. To predict the dispersion of odor downwind, the geographical area containing the odorant sources at each facility was partitioned into 10-m2 grids on the basis of satellite photographs and architectural drawings. Relative odorant concentrations were assigned to each grid point on the basis of intensity measurements made by the trained odor panel at each facility using a 9-point rating scale. The results of the modeling indicated that odor did not extend significantly beyond 400 m downwind of any of the test sites during the daytime when the layer of air above the earth's surface is usually turbulent. However, modeling indicated that odor from all full-scale farms extended beyond 400 m onto neighboring property in the evenings when deep surface cooling through long-wave radiation to space produces a stable (nocturnal) boundary layer. The results also indicated that swine housing, independent of waste management type, plays a significant role in odor downwind, as do odor sources of moderate to moderately high intensity that emanate from a large surface area such as a lagoon. Human odor assessments were utilized for modeling rather than instrument measurements of volatile organic compounds (VOCs), hydrogen sulfide, ammonia, or particulates less than 10 microm in diameter (PM10) because these physical measurements obtained simultaneously with human panel ratings were not found to accurately predict human odor intensity in the field.     

Environmental Assessment Framework for Policy Applications: Life Cycle Assessment,External Costs and Multi-criteria Analysis

The paper presents a framework for the analysis of external costs of environmental burdens, namely an impact pathway analysis, often coupled with the inventory stage of life cycle assessment (LCA). The ground rule is: quantify as much as possible in terms of burdens (pollutant emissions, etc.), impacts, and their monetary equivalent, then use multi-criteria analysis (MCA) for any remaining impacts that are considered to be too uncertain or defy quantification through to monetization. Although MCA could be used directly on estimates of burdens or impacts, monetary valuation provides a mechanism for consistent weighting of impacts categories based on assessment of public preference. Further advantages of extending LCA through detailed impact assessment combined with monetary valuation are that it greatly simplifies MCA by combining a large number of different environmental impact categories, thereby avoiding an unmanageably large number of criteria, and also facilitates cost benefit analysis (CBA). The risks are noted of inappropriate use of the tools or interpretation/use of the results, and recommendations are made for improved practice. These points are illustrated with examples. The key messages are: (1) that policies should be targeted correctly to give a clear signal which source of a burden should be reduced by how much; (2) that analysts should take into account the needs of policy makers and the link between the analysis and possible policy applications; and (3) that current LCA practice gives limited guidance in both areas, largely through a lack of consideration of the relative and absolute importance of different types of impact. However, this is precisely the strength of external costs analysis, particularly when used with MCA.     

Sub-cooled and flashing liquid jets and droplet dispersion I. Overview and model implementation/validation

Many accidents involve two-phase releases of hazardous chemicals into the atmosphere. This paper describes the results of a third phase of a Joint Industry Project (JIP) on liquid jets and two-phase droplet dispersion. The aim of the project is to increase the understanding of the behaviour of sub-cooled non-flashing and superheated flashing liquid jets, and to improve the prediction of initial droplet size, droplet dispersion and rainout.Phase III of the JIP first included scaled experiments for materials with a range of volatilities (water, cyclohexane, butane, propane and gasoline). These experiments were carried out by Cardiff University including measurements of flow rate and initial droplet size across the full relevant range of superheats. See the companion paper II for further details of these experiments and the derivation of new refined correlations for droplet size distribution and Sauter Mean Diameter. Furthermore large-scale butane experiments were carried out by INERIS (France) to ensure that for more realistic scenarios the derived droplet size correlations are accurate.Model validation and model improvements were carried out by DNV Software, including validation of release rate and initial droplet size against the above scaled and large-scale experiments. New correlations for droplet size distribution and Sauter Mean Diameter (SMD) were implemented into the Phast discharge model. These were compared against a range of other droplet size and rainout correlations published in the literature, in conjunction with validation against an extensive set of experiments. It was shown that the new droplet size correlation agrees better against experimental data than the existing Phast correlation. To further improve the rainout prediction, the Phast dispersion model (UDM) was also extended to allow simultaneous modelling of a range of droplet sizes and distributed rainout (rather than rainout at one point).     

Vulnerability of land systems to fire: Interactions among humans,climate, the atmosphere,and ecosystems

Fires are critical elements in the Earth System, linking climate, humans, and vegetation. With 200–500 Mha burnt annually, fire disturbs a greater area over a wider variety of biomes than any other natural disturbance. Fire ignition, propagation, and impacts depend on the interactions among climate, vegetation structure, and land use on local to regional scales. Therefore, fires and their effects on terrestrial ecosystems are highly sensitive to global change. Fires can cause dramatic changes in the structure and functioning of ecosystems. They have significant impacts on the atmosphere and biogeochemical cycles. By contributing significantly to greenhouse gas (e.g., with the release of 1.7–4.1 Pg of carbon per year) and aerosol emissions, and modifying surface properties, they affect not only vegetation but also climate. Fires also modify the provision of a variety of ecosystem services such as carbon sequestration, soil fertility, grazing value, biodiversity, and tourism, and can hence trigger land use change. Fires must therefore be included in global and regional assessments of vulnerability to global change. Fundamental understanding of vulnerability of land systems to fire is required to advise management and policy. Assessing regional vulnerabilities resulting from biophysical and human consequences of changed fire regimes under global change scenarios requires an integrated approach. Here we present a generic conceptual framework for such integrated, multidisciplinary studies. The framework is structured around three interacting (partially nested) subsystems whose contribute to vulnerability. The first subsystem describes the controls on fire regimes (exposure). A first feedback subsystem links fire regimes to atmospheric and climate dynamics within the Earth System (sensitivity), while the second feedback subsystem links changes in fire regimes to changes in the provision of ecological services and to their consequences for human systems (adaptability). We then briefly illustrate how the framework can be applied to two regional cases with contrasting ecological and human context: boreal forests of northern America and African savannahs.