乙醇废水的超临界水氧化反应路径及动力学研究

研究了超临界水氧化法 (SCWO)处理乙醇废水过程的反应路径和动力学 .乙醇SCWO反应的最终产物为CO2 ,CO是此过程的中间产物 .以幂指数方程描述乙醇SCWO反应动力学 ,得到对于乙醇的反应级数为 1,对氧气的反应级数为 0 .求出活化能和指前因子分别为 3 5 1× 10 5J·mol-1和 7 74× 10 2 1s-1.方程计算值和实验值吻合较好 ,误差基本在 10 %以内     

炼油厂污水处理负荷的削减措施

总结和分析了某厂削减污水处理负荷的主要措施及效益，预测该厂在达到16000kt/a以上加工规模时的污水处理负荷。     

马铃薯淀粉废水的碱式聚合氧化铝处理

本文介绍了用碱式聚合氯化铝处理高浓度有机淀粉废水的效果。用实验室配制的CODw浓度为10000－15000mg/L的淀粉废水以不同用量的碱式聚合氯化铝为絮凝剂处理后，CODw去除率达到28％－47％，再经吸附柱吸附后，CODw去除率可达到65％。     

Hydrogen storage and distribution systems

Hydrogen storage and transportation or distribution is closely linked together. Hydrogen can be distributed continuously in pipelines or batch wise by ships, trucks, railway or airplanes. All batch transportation requires a storage system but also pipelines can be used as pressure storage system. Hydrogen exhibits the highest heating value per weight of all chemical fuels. Furthermore, hydrogen is regenerative and environment friendly. There are two reasons why hydrogen is not the major fuel of toady’s energy consumption: First of all, hydrogen is just an energy carrier. And, although it is the most abundant element in the universe, it has to be produced, since on earth it only occurs in the form of water. This implies that we have to pay for this energy, which results in a difficult economic task, because since the industrialization we are used to consuming energy for free. The second difficulty with hydrogen as an energy carrier is the low critical temperature of 33 K, i.e. hydrogen is a gas at room temperature. For mobile and in many cases also for stationary applications the volumetric and gravimetric density of hydrogen in a storage system is crucial. Hydrogen can be stored by six different methods and phenomena: high pressure gas cylinders (up to 800 bar), liquid hydrogen in cryogenic tanks (at 21 K), adsorbed hydrogen on materials with a large specific surface area (at T < 100 K), absorbed on interstitial sites in a host metal (at ambient pressure and temperature), chemically bond in covalent and ionic compounds (at ambient pressure), oxidation of reactive metals e.g. Li, Na, Mg, Al, Zn with water. These metals easily react with water to the corresponding hydroxide and liberate the hydrogen from the water. Finally, the metal hydroxides can be thermally reduced to the metals in a solar furnace.     

电活性铝凝剂EAF对炼油废水的絮凝作用

采用电化学方法制取电活性铝凝剂ＥＡＦ．对照测定了３种传统的含铝絮凝剂和ＥＡＦ对模拟和实际含油废水的絮凝净化作用．结果表明，６０℃温度下，ｐＨ＝６～７，ＥＡＦ的用量为１０～３０ｍｇ／Ｌ时，油与ＣＯＤｃｒ去除率分别在９０％和８０％以上．简单讨论了ＥＡＦ的絮凝作用机理．     

光催化降解有机磷农药废水的可行性

在ＴｉＯ２粉末的存在下，研究光催化降解有机磷农药废水的可行性。结果表明，ＣＯＤｃｒ６５０ｍｇ／Ｌ，有机磷１９．８ｍｇ／Ｌ的有机磷农药废水在３７５Ｗ中压汞灯照射４ｈ，ＣＯＤ去除率为９０％，有机磷将完全转化为无机磷。同时还研究了光催化剂ＴｉＯ２的用量，反应液初始ｐＨ值，空气流量，外加Ｆｅ３＋浓度等多种因素对光降解的影响；并利用太阳聚光做了室外实验     

电助光催化处理高COD农药废水的研究

采用自制的电助光催化装置处理高浓度COD农药废水,处理后的出水水质符合《污水综合排放标准》(GB8978-1996)三级标准。     

兴文石林地质地貌景观的脆弱化趋势研究

兴文石林是喀斯特岩溶地质风景名胜区兴文石海的中心景区,喀斯特岩溶山地的生态环境具有一定脆弱特性,随着旅游业的不断发展,景区加大了开发力度,可能导致景区脆弱性的加剧,为了保证在旅游开发中能对景区重要的地质资源进行更好地保护,采用生态脆弱区评级指标及权重值评分法对兴文石林的10个主景点进行了研究,分析得出,兴文石林存在轻生态脆弱性、中生态脆弱性和强生态脆弱性三种梯度趋向,其中,脆弱性最强区域面积达到2平方公里的面积,这些区域分布在景区的边缘地带,因此,要实现旅游资源的可持续利用,必须对强生态脆弱性区域实行禁游和实行退耕还林等措施,以防止脆弱区域的扩大和脆弱性加剧.     

钢筋混凝土框架电算结果的人工调整

根据钢筋混凝土多层框架的设计经验和设计规范，对如何调整电算结果中的梁，柱截面尺寸，配筋率，裂缝宽度和梁，柱配筋等问题进行探讨，并提出相应的建议。     

Alteration in Rhizosphere Soil Properties of Afforested <Emphasis Type="Italic">Rhamnus lycioides</Emphasis> Seedlings in Short-Term Response to Mycorrhizal Inoculation with <Emphasis Type="Italic">Glomus intraradices</Emphasis> and Organic Amendment

The reestablisment of autochthonous plant species is an essential strategy for recovering degraded areas under semiarid conditions. A field experiment was carried out to assess the short-term effect of two reafforestation methods involving mycorrhizal inoculation and compost addition on soil quality parameters and Rhamnus lycioides seedling growth. The nutrient content (NPK) and enzymatic activities (dehydrogenase, urease, protease-BAA, acid phosphatase and β-glucosidase) increased and bulk density decreased in the rhizosphere soil with the organic amendment. Biomass C of rhizosphere soil increased by at least 240% with respect to the control soil after mycorrhizal inoculation and the combination of compost addition + mycorrhizal inoculation. Both mycorrhizal inoculation and composted organic residue addition increased R. lycioides seedling growth in the same proportion. In the short term, we conclude that the application of both reafforestation methods not only enhances the establishment of R. lycioides seedlings, but also improves soil quality.