A new approach to estimation of methane emission rates from landfills

Methane emission monitoring has become increasingly essential for diffusive area sources, especially for landfills, which contribute to a significant fraction of the total anthropogenic methane emission globally. Statutorily, methane emission rate from landfills in Germany shall be examined on a semiannual basis; however, an appropriate approach has yet to be developed and adopted for general use. In this study, a new method is proposed based on experimental results, which utilizes a TDLAS (Tunable Diode Laser Absorption Spectroscopy) instrument – GasFinder2.0® system and a dispersion model LASAT (Lagrangian Simulation of Aerosol Transport) as the measurement device and calculation model, respectively. Between April 2010 and December 2011, a research project was conducted at a pilot scale landfill in the south of Germany. Drawing on the extensive research into this pilot project, an effective strategy of measurement setup was determined. Methane concentration was measured with GasFinder2.0® system in the upstream and downstream sections of the project site, while wind and turbulence data were measured simultaneously by an ultrasonic anemometer. The average methane emission rate from the source can be calculated by using the results as input data in the dispersion model. With this method, site-specific measurement approaches can be designed for not only landfills, but also different diffusive area sources with less workload and lower cost compared to conventional FID (Flame Ionization Detector) method.     

Bioavailability and metabolism of hexavalent chromium compounds †

Intratracheal instillation of ⁵¹CrCl₃ in anaesthetized rabbits resulted in partial absorption. In blood, the absorbed material was entirely confined to the plasma compartment. Only trace amounts were deposited in liver and kidney. By contrast, after similar application of Na, ⁵¹CrO₄ the bulk of blood radioactivity was present in red blood cells (RBC). Substantial deposition occurred in liver and kidneys. It is concluded that Cr(VI) may enter the body unreduced via the lung and is partially deposited in cells over a prolonged period of time.

Since chromium was accumulated in liver after administration of Cr(VI) we investigated the intracellular disposition of Cr(VI) in the isolated perfused liver. No significant sex differences in chromium distribution were observed. At the end of the experiments (1 h), 60% of the applied dose (312μg Cr/liver) was located in the cytosol, whilst 14% was in the mitochondria, 9% in the microsomal pellet and 2% was associated with the nuclei. Gel chromatography of the cytosolic compartment showed that the overwhelming part of chromium was eluted in fractions with an apparent molecular weight of 6,000 dalton. These fractions exhibited absorption maxima at 410nm and 548nm. It is concluded, that cytosolic reduction might be the main intracellular redox pathway for chromates. This view was confirmed by monitoring the reaction of Cr(VI) with GSH in vitro. GSH reduced Cr(VI) without further cofactors under formation of GSH‐chromium complexes, which possibly represent major intermediates in the metabolism of Cr(VI).     

Divergent neighbors: corporatism and climate policy networks in Finland and Sweden

ABSTRACT

Previous research has suggested that corporatist polities tend to enact more ambitious environmental policies than others. Here it is argued that the macro concept of corporatism can be dissected into three components: inclusiveness, consensualism and strength of tripartite organisations. These components of corporatism can be measured at the meso-level of policy networks. It is proposed that inclusiveness and consensualism are related to ambitious climate policy but exclusive tripartite coalitions can be detrimental for the ambitiousness of climate policy. This argument is backed by evidence from policy network surveys in two similar corporatist countries where climate change policies diverge: Sweden, where policies are ambitious, and Finland, where they are less so. It is found that in Sweden the climate change policy network is more consensual and slightly more inclusive, while in Finland tripartite organisations play a strong role.     

The challenge of validating vulnerability estimates: the option of media content analysis for identifying drought-related crises

For an integrated assessment of the vulnerability of societies to drought it is necessary to set the benchmark at a level where the impacts of droughts lead to a state of affairs that departs from normal conditions, i.e. a crisis event. This article aims to improve the understanding of drought-related crisis events on the basis of a twofold media content analysis. This approach enables us to test when increased vulnerability in fact leads to a crisis situation and offers an improved understanding of the intensity and the extent of crisis events. To this end, we first outline our perspective on crisis and give an overview on existing approaches to identify crisis events. We then outline our two-step approach of media content analysis aimed at developing a crisis data set for the case study regions Andhra Pradesh (India), Southern Portugal and the Volga region (Russia). Using the Factiva news database and information by regional newspapers, a crisis data set is generated enabling us to define the occurrence and extent of drought-related crisis events in the case study regions. Moreover, based on attributes of drought impacts reported by news sources, we categorize the extensiveness of a specific drought. As a key result, our findings suggest that Southern Portugal, the case study region which is expected to be less susceptible to drought events than the other case study regions, faced the most extended crisis events.     

Effect of commercial mineral-based additives on composting and compost quality

The effectiveness of two commercial additives meant to improve the composting process was studied in a laboratory-scale experiment. Improver A (sulphates and oxides of iron, magnesium, manganese, and zinc mixed with clay) and B (mixture of calcium hydroxide, peroxide, and oxide) were added to source-separated biowaste:peat mixture (1:1, v/v) in proportions recommended by the producers. The composting process (T, emissions of CO₂, NH₃, and CH₄) and the quality of the compost (pH, conductivity, C/N ratio, water-soluble NH₄–N and NO₃–N, water- and NaOH-soluble low-weight carboxylic acids, nutrients, heavy metals and phytotoxicity to Lepidium sarivum) were monitored during one year. Compared with the control, the addition of improver B increased pH by two units, led to an earlier elimination of water-soluble ammonia, an increase in nitrates, a 10-fold increase in concentrations of acetic acid, and shortened phytotoxicity period by half; as negative aspect it led to volatilization of ammonia. The addition of improver A led to a longer thermophilic stage by one week and lower concentrations of low-weight carboxylic acids (both water- and NaOH-extractable) with formic and acetic of similar amounts, however, most of the aspects claimed by the improver’s producer were not confirmed in this trial.