SNCR脱硝技术在某水泥厂脱硝工程应用

通过对某水泥厂水泥生产线进行SNCR脱硝测试,考察不同的喷射位置、覆盖范围、NSR以及温度等因素对SNCR技术脱硝效率的影响。测试结果表明:SNCR脱硝技术在水泥生产线上可以获得超过88%的脱硝效率,NO x排放浓度可以低于200 mg/m3。     

Determination of time- and size-dependent fine particle emission with varied oil heating in an experimental kitchen

Particulate matter(PM) from cooking has caused seriously indoor air pollutant and aroused risk to human health.It is urged to get deep knowledge of their spatial-temporal distribution of source emission characteristics,especially ultrafine particles(UFP 100 nm) and accumulation mode particles(AMP 100-555 nm).Four commercial cooking oils are auto dipped water to simulate cooking fume under heating to 255℃ to investigate PM emission and decay features between 0.03 and 10 μm size dimension by electrical low pressure impactor(ELPI) without ventilation.Rapeseed and sunflower produced high PM_(2.5) around5.1 mg/m~3,in comparison with those of soybean and corn(5.87 and 4.55 mg/m~3,respectively)at peak emission time between 340 and 450 sec since heating oil,but with the same level of particle numbers 6-9 × 10~5/cm~3.Mean values of PM_(1.0)/PM_(2.5) and PM_(2.5)/PM_(10) at peak emission time are around 0.51-0.55 and 0.23-0.29.After 15 min naturally deposition,decay rates of PM_(1.0),PM_(2.5) and PM_(10) are 13.3%-29.8%,20.1%-33.9%and 41.2%-54.7%,which manifest that PM_(1.0) is quite hard to decay than larger particles,PM_(2.5) and PM_(1.0).The majority of the particle emission locates at 43 nm with the largest decay rate at 75%,and shifts to a larger size between137 and 555 nm after 15 min decay.The decay rates of the particles are sensitive to the oil type.     

土壤污染研究现状与趋势

简要介绍了土壤污染研究领域的主要内容 ,归纳了土壤污染研究中一些主要方法。结合土壤污染发展特点 ,对今后土壤污染研究的重点方向作了一般性探讨。     

Development of a PCR strategy for thraustochytrid identification based on 18S rDNA sequence

The identification and characterization of the thraustochytrids, an emerging economically and biotechnologically important group of marine heterotrophic protists, is usually based on morphological characters. In this research we used molecular markers to identify thraustochytrids. We designed three sets of primers based on the 18S rDNA sequence alignment of known strains and employed a PCR (polymerase chain reaction) strategy to identify unknown thraustochytrid isolates. DNA from 26 thraustochytrids (three isolated from primary cell cultures of the tunicate Botryllus schlosseri and 23 from a coral holding aquarium) were amplified by these primers, revealing 21 isolates with three bands each, which were assigned to two groups according to PCR fragment sizes. Taxonomic characterizations were deduced by comparing with GenBank data. Four isolates were further studied by sequencing their 18S rDNA. Sequence alignments and phylogenetic analysis revealed that isolates from the coral aquarium (7-5 and 8-7) were highly similar to each other and 95.0-97.0% similar to Thraustochytrium multirudimentale and Schizochytrium minutum. Isolates from the tunicate primary cell cultures (BS1 and BS2) were also closely related to each other and 84.3-86.0% similar to labyrinthulid quahog parasite and Thraustochytrium pachydermum. AFLP (amplified fragment-length polymorphism) analysis revealed 2.5-3.6% differences within the genomic DNA of each group, showing that each isolate is different, although isolates within each group may belong to the same species, in spite of differences found in the general morphology.     

农药在土壤中迁移的研究方法

农药对地下水的污染已日益为人们密切关注，本文详细介绍了用土壤柱和土壤薄层层析法研究农药在土壤迁移行为用于预测或评价农药对地下水污染程度的研究方法。     

The transportation,time-dependent distribution of heavy metals in paddy crops

Sixteen experimenmtal plots (5 m x 6 m = 30 m2) were designed with four different levels of heavy metals (HMs) concentration in soil. The concentrations of heavy metals in soils, and paddy plant during the different periods of growth were investigated. A relationship between the total HM content in plants and the HM level in soil was found for a wide range of concentrations. The exchangeable fraction of HMs extracted with 1 M MgCl2 solution according to Tessier's method increased correlation with the dosage of supplemented HMs, then decreased as time went on. The time-related variation of exchangeable HMs in soil demonstrated that the amount of effective HMs taken up by paddy differed at various growth phases. The amount of HMs accumulated in different parts of paddy followed the order of root > stem > grain, leaf. The transportation potential of the HMs in paddy in present study followed the order of Zn, Cr > Cd, Cu > Pb. The HM content in root, stem and leaf of paddy plant (dry weight) was low at time of seedling. The concentration in the root increased sharply at time of tillering, decreased thereafter. The concentrations in stem and leaf reached the highest at time of tillering, then decreased, while rose slightly at following time.     

Stressful work characteristics,health indicators and work behavior: the case of machine operators

This article shows the results of research on psychosocial risks for a group of machine and plant operators (n?=?1014) from the construction, chemical, energy, mining, metal and food industries in Poland. The Psychosocial Risk Scale designed in Nofer Institute of Occupational Medicine (NIOM) by Moscicka-Teske and Potocka was used to indicate the occurrence of general and specific occupational stressors and the level of their stressfulness. The results revealed that the studied machine and plant operators experience job context stress – related to working environment features concerning work organization – more frequently than job content stressors – related to the type of tasks they perform. Moreover, a correlation analysis between work features and the health and occupational functioning of the respondents revealed significant but weak relationships between the variables (from ?0.08 to ?0.23). Comparative analysis revealed the differences between the studied sectors. Such a comparison makes it possible to set goals for each sector and to attempt to improve the distinctive areas.     

居民为改善北京市大气环境质量的支付意愿研究

用意愿调查价值评估法分析了北京市居民为改善大气环境质量的支付意愿 ,评估大气质量改善的价值 ,并对这一方法在我国的应用进行探讨。结果显示 ,研究范围内的居民为 5年内降低目前大气污染物质浓度的 5 0 %而支付费用的平均支付意愿是 143元 /户·年 (1999年元 ) ,该区域内居民总的支付意愿是 3 .36亿元 /年 (1999年元 ) ,被调查者的家庭收入、教育水平、家庭人口数和年龄等社会经济变量对支付意愿有显著影响。最后 ,对意愿调查价值评估法在我国应用时存在的问题进行了初步探讨     

Macroporous Ni foam-supported Co3O4 nanobrush and nanomace hybrid arrays for high-efficiency CO oxidation

Herein, we reported the synthesis of well-defined Co_3O_4 nanoarrays(NAs) supported on a monolithic three-dimensional macroporous nickel(Ni) foam substrate for use in highefficiency CO oxidation. The monolithic Co_3O_4 NAs catalysts were obtained through a generic hydrothermal synthesis route with subsequent calcination. By controlling the reaction time,solvent polarity and deposition agent, these Co_3O_4 NAs catalysts exhibited various novel morphologies(single or hybrid arrays), whose physicochemical properties were further characterized by using several analytical techniques. Based on the catalytic and characterization analyses, it was found that the Co_3O_4 NAs-6 catalyst with nanobrush and nanomace arrays displayed enhanced catalytic activity for CO oxidation, achieving an efficient 100% CO oxidation conversion at a gas hourly space velocity(GHSV) 10,000 hr~(-1) and 150°C with longterm stability. Compared with the other Co_3O_4 NAs catalysts, it had the highest abundance of surface-adsorbed oxygen species, excellent low-temperature reducibility and was rich in surface-active sites(Co~(3+)/Co~(2+)= 1.26).     

单甲脒水中溶解度及正辛醇／水分配系数的测定

有毒有机化合物在水中的溶解度(WS)及正辛醇/水分配系数(K_(ow)),是描述其在环境中行为的两个重要物理化学参数。本文用溶解度平衡曲线法和振荡法,测得单甲脒在水中的溶解度为21.8±1.3mg/1(25℃),其在正辛醇/水中的分配系数lgK_(ow)为2.92±0.06。