Discharge permit market and farm management nexus: an approach for eutrophication control in small basins with low-income farmers

The economic concerns of low-income farmers are barriers to nutrient abatement policies for eutrophication control in surface waters. This study brings up a perspective that focuses on integrating multiple-pollutant discharge permit markets with farm management practices. This aims to identify a more economically motivated waste load allocation (WLA) for non-point sources (NPS). For this purpose, we chose the small basin of Zrebar Lake in western Iran and used the soil and water assessment tool (SWAT) for modeling. The export coefficients (ECs), effectiveness of best management practices (BMPs), and crop yields were calculated by using this software. These variables show that low-income farmers can hardly afford to invest in BMPs in a typical WLA. Conversely, a discharge permit market presents a more cost-effective solution. This method saves 64% in total abatement costs and motivates farmers by offering economic benefits. A market analysis revealed that nitrogen permits mostly cover the trades with the optimal price ranging from $6 to $30 per kilogram. However, phosphorous permits are limited for trading, and their price exceeds $60 per kilogram. This approach also emphasizes the establishment of a regional institution for market monitoring, dynamic pricing, fair fund reallocation, giving information to participants, and ensuring their income. By these sets of strategies, a WLA on the brink of failure can turn into a cost-effective and sustainable policy for eutrophication control in small basins.     

Assessment of water quality of Manchar Lake in Sindh (Pakistan)

Manchar Lake is the largest natural freshwater lake in Pakistan. The Lake has received less fresh water in past few years. In addition, drainage water is being discharged in the Lake through Main Nara Valley Drain (MNVD) since many years. Consequently, concern has grown regarding the water quality of the Lake. The aim of this study was to assess the water quality of Manchar Lake and MNVD and the objectives were to determine physiochemical properties and the concentrations of common cations and anions as well as seven trace metals i.e. Cu, Ni, Zn, Co, Fe, Pb and Cd. The concentration of the trace metals were determined by simultaneous preconcentration and solvent extraction using flame atomic absorption spectrometer. Results of physicochemical parameters of Manchar Lake water samples showed mean pH 8.4 (±0.2), conductivity 2,310.3 (±581.3) μS cm⁻¹ and hardness (as CaCO₃) 213.1 (±62.3) mg l⁻¹. Mean concentrations of cations and anions were Na 521.5 (±49.7), Cl⁻ 413.6 (±225.7), Ca 70.7 (±12.9), Mg 56.2 (±28.9), K 17.6 (±6.5), 0.34 (±0.2) and 0.02 (±0.01) mg l⁻¹. Mean concentrations of trace metals were Zn 15.7 (±1), Fe 12 (±3.5), Pb 9 (±2.7), Cu 8.9 (±7.7), Ni 4.3 (±3.4), Co 4 (±3.4) and Cd 1.1 (±1) μg l⁻¹. MNVD water samples showed mean pH 8.9 (±0.8), conductivity 1,735.7 (±567.8) μS cm⁻¹ and hardness (as CaCO₃) 184.8 (±32.4) mg l⁻¹. In MNWD, the mean concentrations of cations and anions were Na 482.7 (±11.7), Cl⁻ 395.7 (±271.5), Ca 79.1 (±23.5), Mg 54.2 (±28.1), K 26.2 (±21.3), NO⁻³ 0.5 (±0.3) and 0.1 (±0.1) mg l⁻¹. Mean concentrations of trace metals observed in MNWD water were Fe 14.9(±3.5), Cd 8.3 (±9.4), Pb 6.9 (±2.4), Cu 6.6 (±3.1), Zn 6.2 (±1.8), Co 4.5 (±2.7), and Ni 3.5 (±2.9) μg l⁻¹. The pH of both Manchar Lake and MNVD waters and concentration of Pb in Manchar Lake and concentration of Cd in MNVD water were higher than the World Health Organisation’s guideline values for the drinking water quality. The water quality of Manchar Lake was found degraded.     

Analysis of cost–benefit in life-cycle of plastic solid waste: combining waste flow analysis and life cycle cost as a decision support tool to the selection of optimum scenario

Millions of tons of plastic are consumed annually in the world due to its significant characteristics such as durability, flexibility, and low weight. High consumption has made plastic one of the most important municipal solid waste compounds, the quantity of which has increased in recent decades. Plastic solid wastes are known as a threat to the environment, and its efficient management in various aspects such as cost–benefit requires decision-making tools. This study was assessing the cost–benefit of plastic solid waste management by development of an economic model, and definition of different scenarios to change plastic solid waste management status. The results showed that 8971 tons of plastic solid waste were generated annually in the studied city. The plastic solid wastes were finally transferred to either recycling or landfilling site through 5 identified routes. 83 percent of the total recycled plastic solid waste was due to post-separation routes, and only 7.7 percent of the total plastic solid waste was recycled from the source separation route. The economic comparison of scenarios showed that with the aggregation of post-separation routes, the net revenue of plastic solid waste management increases by 334,000 euro per year while increasing the public participation and the ratio of source separation route raises net revenue by 875,000 euro per year, which was the best economic condition among the scenarios. Using life cycle cost method and it’s respected developed economic model truly satisfied the conditions of both, the current plastic solid waste management and the alternative scenarios, and hence can be adopted as a tool for decision-making.

     

Hospital site selection using fuzzy AHP and its derivatives

Environmental managers are commonly faced with sophisticated decisions, such as choosing the location of a new facility subject to multiple conflicting criteria. This paper considers the specific problem of creating a well-distributed network of hospitals that delivers its services to the target population with minimal time, pollution and cost. We develop a Multi-Criteria Decision Analysis process that combines Geographical Information System (GIS) analysis with the Fuzzy Analytical Hierarchy Process (FAHP), and use this process to determine the optimum site for a new hospital in the Tehran urban area. The GIS was used to calculate and classify governing criteria, while FAHP was used to evaluate the decision factors and their impacts on alternative sites. Three methods were used to estimate the total weights and priorities of the candidate sites: fuzzy extent analysis, center-of-area defuzzification, and the α-cut method. The three methods yield identical priorities for the five alternatives considered. Fuzzy extent analysis provides less discriminating power, but is simpler to implement and compute than the other two methods. The α-cut method is more complicated, but integrates the uncertainty and overall attitude of the decision-maker. The usefulness of the new hospital site is evaluated by computing an accessibility index for each pixel in the GIS, defined as the ratio of population density to travel time. With the addition of a new hospital at the optimum site, this index improved over about 6.5 percent of the geographical area.     

Evaluation of the in-situ aerobic cometabolism of chlorinated ethenes by toluene-utilizing microorganisms using push-pull tests

A series of transport, biostimulation, and activity push-pull tests were performed under induced and natural gradient conditions in a trichloroethene (TCE) and cis-dichloroethene (c-DCE) contaminated aquifer. Transport tests demonstrated the feasibility of injecting and recovering complex solute mixtures from the aquifer. During the biostimulation tests, decreases in toluene concentration and the production of o-cresol as an intermediate oxidation product indicated the presence of toluene-utilizing microorganisms. Activity tests demonstrated that the stimulated microbial community had the ability to transform injected c-DCE and trans-dichloroethene (t-DCE) at similar zero-order rates. Injected isobutene was oxidized to isobutene oxide, which indicated that a toluene ortho-monooxygenase enzyme system was likely responsible for the observed c-DCE and t-DCE transformations. c-DCE zero-order transformation rates in drift push-pull tests were similar to those obtained from traditional push-pull tests (about 0.1 microM/h). Analysis of drift test data using first-order kinetic analysis resulted in similar conclusions as those obtained using zero-order kinetic analyses. When 1-butyne, an inhibitor of toluene ortho-monooxygenase, was added to injected test solutions, the oxidation of toluene, and the transformation of isobutene, c-DCE, and t-DCE were inhibited. The results illustrate how a series of push-pull tests can be used in combination to detect, quantify and confirm in-situ cometabolic microbial transformations.     

Indoor/Outdoor relationships, trends, and carbonaceous content of fine particulate matter in retirement homes of the Los Angeles Basin

Hourly indoor and outdoor fine particulate matter (PM2.5), organic and elemental carbon (OC and EC, respectively), particle number (PN), ozone (O3), carbon monoxide (CO), and nitrogen oxide (NOx) concentrations were measured at two different retirement communities in the Los Angeles, CA, area as part of the Cardiovascular Health and Air Pollution Study. Site A (group 1 [G1]) was operated from July 6 to August 20, 2005 (phase 1 [P1]) and from October 19 to December 10, 2005 (P2), whereas site B (group 2 [G2]) was operated from August 24 to October 15, 2005 (P1), and from January 4 to February 18, 2006 (P2). Overall, the magnitude of indoor and outdoor measurements was similar, probably because of the major influence of outdoor sources on indoor particle and gas levels. However, G2 showed a substantial increase in indoor OC, PN, and PM2.5 between 6:00 and 9:00 a.m., probably from cooking. The contributions of primary and secondary OC (SOA) to measured outdoor OC were estimated from collected OC and EC concentrations using EC as a tracer of primary combustion-generated OC (i.e., "EC tracer method"). The study average outdoor SOA accounted for 40% of outdoor particulate OC (40-45% in the summer and 32-40% in the winter). Air exchange rates (hr(-1)) and infiltration factors (Finf; dimensionless) at each site were also determined. Estimated Finf and measured particle concentrations were then used in a single compartment mass balance model to assess the contributions of indoor and/or outdoor sources to measured indoor OC, EC, PM2.5, and PN. The average percentage contributions of indoor SOA of outdoor origin to measured indoor OC were approximately 35% (during G1P1 and G1P2) and approximately 45% (for G2P1 and G2P2). On average, 36% (G2P1) to 44% (G1P1) of measured indoor OC was composed of outdoor-generated primary OC.     

Combined Non-Catalytic Reduction of NOx and SO2 by Ammonia Liquor during Staged Fluidized-Bed Combustion

Emissions of NOx and SO2 were monitored in the presence of ammonia liquor in a 0.09 m2 and 2 m high stainless-steel fluidized-bed combustor. Experiments were carried out at 2 m/s fluidizing velocity, 40% excess air, and 870 °C bed temperature. Ammonia liquor with 7% ammonia by weight was injected into the freeboard of the combustor 52 cm above the distributor through a water-cooled injector. A 65 : 34 primary/secondary air ratio was maintained throughout the investigation. Approximately 70% of NO and 20% of SO2 was reduced at an NH3/NO molar ratio of 2 : 1, respectively. However, a higher reduction in SO2 emissions (62%) was achieved at a very high NH3/NO molar ratio of 7 : 1. These experiments showed that ammonia addition did have a significant effect in SO2 reduction if injected in an excess amount. The injection of ammonia liquor combined with staged combustion was found to be very effective in reducing NOx emissions. A reduction of about 50% was achieved at an NH3/NO molar ratio of 0.6 : 1 which is also coupled with a very low level of ammonia in the flue.     

Separation and determination of trace levels of aromatic amines by HPLC

Aromatic amines were analysed by normal phase and reverse phase high performance liquid chromatography employing silica gel and octadecyl silane (ODS) columns, respectively. A number of mobile phases were used. The results obtained on silica gel column were compared with those achieved on reverse phase column. Excellent results were obtained on ODS and shoulder peaks were eliminated when a mixture of methyl alcohol and sodium perchlorate was used as mobile phase.