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91.
Mohammad Goodarzi Erlinda V. Ortiz Leandro dos S. Coelho Pablo R. Duchowicz 《Atmospheric environment (Oxford, England : 1994)》2010,44(26):3179-3186
This work aims to predict the air to water partitioning for 96 organic pesticides by means of the Quantitative Structure–Property Relationships Theory. After performing structural feature selection with Genetics Algorithms and Replacement Method linear approaches, it is found that among the most important molecular features appears the Moriguchi octanol–water partition coefficient, and higher lipophilicities would lead to compounds having higher Henry’s law constants. We also compare the statistical performance achieved by four fully-connected Feed-Forward Multilayer Perceptrons Artificial Neural Networks. The statistical results found reveal that the best performing model uses the Levenberg–Marquardt with Bayesian regularization (BR) weighting function for achieving the most accurate predictions. 相似文献
92.
Hamed Gharibi Mohammad Hossein Sowlat Amir Hossein Mahvi Morteza Keshavarz Mohammad Hossein Safari Saeedeh Lotfi Mahnaz Bahram Abadi Azim Alijanzadeh 《Chemosphere》2013,90(4):1487-1494
The present study aimed to evaluate the performance of a bipolar electrolysis/electrocoagulation reactor designed to enhance the sludge dewaterability. The reactor was 15 L in volume, with two series of plates used in it; Ti/RuO2 plates for the electrolysis of the sludge, and also aluminum and iron plates for electrocoagulation process. The dewaterability of the sludge was determined in terms of its capillary suction time (CST) and specific resistance to filtration (SRF), while the degree of sludge disintegration was determined based on the value of degree of sludge disintegration (DDSCOD). The maximum reduction in CST and SRF was observed at a detention time of 20 min and a voltage of 30 V. However, increasing of both detention time and voltage significantly increased the values of CST and SRF even to an extent that they both exceeded those of the untreated sludge. The optimal degree of sludge disintegration achieved by the present study was 2.5%, which was also achieved at a detention time of 20 min and a voltage of 30 V. As reported previously, increased DDSCOD values led to increasing CST and SRF values, due primarily to the disruption of the sludge flocs. According to the results from the present study, it can be concluded that simultaneous application of electrocoagulation and electrolysis is effective in enhancing the sludge dewaterability, because electrocoagulation helps to achieve a higher degree of sludge disintegration while maintaining the desired sludge dewaterability. 相似文献
93.
Surface sediments of the lagoons of Lomé, Togo, were analyzed for mercury, methylmercury, and trace elements. Concentrations
were greater than typical for natural lagoon sediments, and with greater variability within the Eastern lagoon compared to
the Western one. The Eastern lagoon is larger and has been dredged in the past, while the Western lagoon, which also receives
major waste inputs, has not been dredged and shows less tidal flushing. Accordingly, one naturally believes that the Eastern
lagoon is cleaner and probably safe to use due to its natural resources, including fishes to eat. Unexpectedly, we describe
here that mercury methylation was greater in the Eastern lagoon, indicating increased bioavailability of mercury, as probably
facilitated by past dredging that decreased solid-phase retention of inorganic mercury. Urbanization has historically been
more developed in the southern part of the lagoons, which is still reflected in contamination levels of sediment despite dredging,
probably because sources of contamination are still more important there today. Such urban contamination emphasizes the need
to regulate waste discharges and possible airborne contamination in growing cities of developing countries, and implements
environmental and public health monitoring, especially in relation to misbelieves systematically associated with the cleansing
effect of dredging activity. 相似文献
94.
Khani MH 《Environmental science and pollution research international》2011,18(5):790-799
Introduction
The application of response surface methodology is presented for optimizing the removal of U ions from aqueous solutions using Padina sp., a brown marine algal biomass. 相似文献95.
Vijgen J Abhilash PC Li YF Lal R Forter M Torres J Singh N Yunus M Tian C Schäffer A Weber R 《Environmental science and pollution research international》2011,18(2):152-162
Purpose
Hexachlorocyclohexane (HCH) isomers (??-, ??- and ??- (Lindane)) were recently included as new persistent organic pollutants (POPs) in the Stockholm Convention, and therefore, the legacy of HCH and Lindane production became a contemporary topic of global relevance. This article wants to briefly summarise the outcomes of the Stockholm Convention process and make an estimation of the amount of HCH waste generated and dumped in the former Lindane/HCH-producing countries.Results
In a preliminary assessment, the countries and the respective amount of HCH residues stored and deposited from Lindane production are estimated. Between 4 and 7 million tonnes of wastes of toxic, persistent and bioaccumulative residues (largely consisting of alpha- (approx. 80%) and beta-HCH) are estimated to have been produced and discarded around the globe during 60 years of Lindane production. For approximately 1.9 million tonnes, information is available regarding deposition. Countries are: Austria, Brazil, China, Czech Republic, France, Germany, Hungary, India, Italy, Japan, Macedonia, Nigeria, Poland, Romania, Slovakia, South Africa, Spain, Switzerland, Turkey, The Netherlands, UK, USA, and former USSR. The paper highlights the environmental relevance of deposited HCH wastes and the related POPs?? contaminated sites and provides suggestions for further steps to address the challenge of the legacy of HCH/Lindane production.Conclusion
It can be expected that most locations where HCH waste was discarded/stockpiled are not secured and that critical environmental impacts are resulting from leaching and volatilisation. As parties to the Stockholm Convention are legally required to take action to stop further POPs pollution, identification and evaluation of such sites are necessary. 相似文献96.
Mohammad Sharif Zami 《Environment, Development and Sustainability》2011,13(6):993-1006
Addressing urban housing crisis is an enormous challenge for most of the countries due to the increasing cost of the building
material. Therefore, affordable alternative building material can make a breakthrough to the urban housing crisis. In the
light of current success of stabilised earth construction in urban low-cost housing, it is important to find out the potential
drivers that can help to adopt this building material. This paper aims to identify and highlight these drivers from the method
of literature review and validates through a Delphi technique. 相似文献
97.
Starch nanocomposites have been prepared using mineral clay. Montmorillonite, kaolin and a surface-modified montmorillonite
by dimethyl (hydrogenated tallow alkyl) ammonium cation were used. Starch-g-PCL nanocomposites have been prepared with graft
polymerization through in situ ring-opening polymerization of ε-caprolactone in the presence of starch, Sn(Oct)2 (Tin(II) 2-ethyl hexanoate) as an initiator/catalyst and silicate layers. In fact, the related composites were prepared in
solution method, bulk polymerization and in situ polymerization methods with introducing the mineral clay. The effect of kind
of clay on d-spacing of silicate layers was investigated and the obtained nanocomposites were analyzed using X-ray diffraction.
The obtained compounds were characterized by Fourier transform infrared (FT-IR). Morphology of the prepared nanocomposites
was investigated using scanning electron microscopy and DSC enhanced the study of thermal behaviour of the prepared composite
compounds. 相似文献
98.
Fenton process, as a pretreatment method, was found to be effective in the primary treatment of mature/medium landfill leachate. However, the main problem of the process is the large amount of produced sludge that requires an accurate feasibility evaluation for operational applications. In this study, the response surface methodology was applied for the modeling and optimization of Fenton process in three target responses, (1) overall COD removal, (2) sludge to iron ratio (SIR) and (3) organics removal to sludge ratio (ORSR), where the latter two were new self-defined responses for prediction of sludge generation and applicability assessment of the process, respectively. The effective variables included the initial pH, [H2O2]/[Fe2+] ratio and Fe2+ dosage. According to the statistical analysis, all the proposed models were adequate (with adjusted R2 of 0.9116–0.9512) and had considerable predictive capability (with prediction R2 up to 0.9092 and appropriate adequate precision). It was found that all the variables had significant effects on the responses, specifically by their observed role in dominant oxidation mechanism. The optimum operational conditions obtained by overlay plot, were found to be initial pH of 5.7, [H2O2]/[Fe2+] ratio of 17.72 and [Fe2+] of 195 mM, which led to 69% COD removal, 2.4 (l sludge/consumed mole Fe2+) of SIR and 16.5 (gCOD removed/l produced sludge) for ORSR in verification test, in accordance with models-predicted values. Finally, it was observed that [H2O2]/[Fe2+] ratio and Fe2+ dosage had significant influence on COD removal, while Fe2+ dosage and [H2O2]/[Fe2+] ratio had remarkable effects on SIR and ORSR responses, respectively. 相似文献
99.
Hassan Abdel-Gawad Hamdy Taha 《Journal of environmental science and health. Part. B》2013,48(8):683-690
Sunflower plants were treated with 14C-chlorpyrifos under conditions simulating local agricultural practice. Residues present in the oil, methanol extract and cake of the treated sunflower seeds were 7.2, 2.8, and 12 ppm, respectively. When rats fed on sunflower cake containing bound residues for three days, the animals eliminated 46 % of the radioactivity in urine, 25 % in feces and 10 % in the expired air. A further bioavailable amount of 8 % was found in selected organs indicating that the bound residues were highly bioavailable. Chromatographic analysis of urine extract revealed the presence of the parent compound, its oxon, desethyl chlorpyrifos and desethyl chlorpyrifos oxon as free metabolites in addition to a conjugated metabolite. It was liberated by acid hydrolysis and identified as 3,5,6-trichloro-2-hydroxypyridine. Bound residues were found to have biological effects such as inhibition of rat plasma ChE, elevations of liver parameters (ALT, AST, and ALP), decrease in total protein and albumin content suggesting a hepatotoxic potential. A significant increase in the values of creatinine, urea, cholesterol, triglycerides and significant decrease in Catalase and Glutathion-S-Transfrase were observed in treated rats. 相似文献
100.
Nazan Karsavuran Mohammad Charehsaz Hayati Celik Bayram Murat Asma Cengiz Yakıncı 《毒物与环境化学》2013,95(10):1564-1570
Hydrogen cyanide (HCN) poisoning due to amygdalin (AMY) in apricot seeds is one of the public health issues in Turkey. The aim of this study was to investigate the AMY content of 13 different apricot seeds including bitter and sweet ones, and which are either sulfurized or roasted. The AMY content was determined by a high-performance liquid chromatography. Release of HCN was predicted and total amount of seeds which can cause poisoning was calculated. The mean AMY content of bitter seeds was 26 ± 14 mg g?1 and that of sweet seeds was 0.16 ± 0.09 mg g?1. The consumption of small amounts of bitter seeds may cause cyanide poisoning. 相似文献