Synthesis and anti-microbial activity of hydroxylammonium ionic liquids

Eight hydroxylammonium-based room temperature ionic liquids (ILs) have been synthesized by acid-base neutralization of ethanolamines with organic acids. The ILs were characterized by infrared and nuclear magnetic resonance spectroscopies and elemental analysis. Their anti-microbial activities were determined using the well-diffusion method. All eight ILs were toxic to Staphylococcus aureus, while 2-hydroxyethylammonium lactate and 2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium acetate showed high anti-microbial activity against a wide range of human pathogens.     

The use of marine sediments as a pavement base material

The management of marine sediments after dredging has become increasingly complex. In the context of sustainable development, traditional solutions such as immersion will be increasingly regulated. More than ever, with the shortage of aggregates from quarries, dredged material could constitute a new source of materials. In this study of the potential of using dredged marine sediments in road construction, the first objective is to determine the physical and mechanical characteristics of fine sediments dredged from a harbour in the north of France. The impacts of these materials on the environment are also explored. In the second stage, the characteristics of the fine sediment are enhanced for use as a road material. At this stage, the treatment used is compatible with industrial constraints. To decrease the water content of the fine sediments, natural decantation is employed; in addition, dredged sand is added to enhance the granular distribution and to reinforce the granular skeleton. Finally, the characteristics of the mix are enhanced by incorporating binders (cement and/or lime). The mechanical characteristics measured on the mixes are compatible with their use as a base course material. Moreover, the obtained results demonstrate the effectiveness of lime in the mixes. In terms of environmental impacts, on the basis of leaching tests and according to available thresholds developed for the use of municipal solid waste incineration (MSWI) bottom ash in road construction, the designed dredged mixes satisfy the prescribed thresholds.     

A simple and efficient multi-residue method based on QuEChERS for pesticides determination in palm oil by liquid chromatography time-of-flight mass spectrometry

In this study, a rapid, specific and sensitive multi-residue method based on acetonitrile extraction followed by dispersive solid-phase extraction (d-SPE) clean-up was implemented and validated for multi-class pesticide residues determination in palm oil for the first time. Liquid-liquid extraction followed by low-temperature precipitation procedure was evaluated in order to study the freezing-out clean-up efficiency to obtain high recovery yield and low co-extract fat residue in the final extract. For clean-up step, d-SPE was carried out using a combination of anhydrous magnesium sulphate (MgSO(4)), primary secondary amine, octadecyl (C(18)) and graphitized carbon black. Recovery study was performed at two concentration levels (10 and 100 ng g(-1)), yielding recovery rates between 74.52% and 97.1% with relative standard deviation values below 10% (n?=?6) except diuron. Detection and quantification limits were lower than 5 and 9 ng g(-1), respectively. In addition, soft matrix effects (≤±20%) were observed for most of the studied pesticides except malathion that indicated medium (20-50%) matrix effects. The proposed method was successfully applied to the analysis of suspected palm oil samples.     

Performance of oil palm kernel shell gasification using a medium-scale downdraft gasifier

This article focused on the performance of oil palm kernel shell (PKS) gasification using a medium-scale downdraft gasifier with a feedstock capacity of 500 kg at a temperature range of 399–700°C and at a feed rate of 177 kg/h. This article is important for evaluating the reliability of PKS gasification for commercial power generation activities from biomass. The process performance was evaluated based on the syngas calorific value (CV), syngas flow rate, and its cold gas efficiency (CGE). The syngas flow rates and CVs were measured using a gas flow meter and a gas analyzer in real time. The data obtained were then analyzed to evaluate the performance of the process. The results showed that the CGE of the process was moderately high (51%) at 681°C, with a high syngas CV (4.45–4.89 MJ/Nm³) which was ideal for gas engine applications. The PKS gasification performance increased when the reactor temperature increased. Projections were made for the CGE and the syngas CV for the PKS gasification with increased reactor temperatures and it was found that these values could be increased up to 80% and 5.2 MJ/Nm^3, respectively at a reactor temperature of 900°C. In addition, the estimated power that could be generated was about 600 kW_e at a maximum operation of 500 kg/h of feed rate. Based on the analysis, a medium-scale PKS gasification is observed to be a promising process for power generation from biomass due to the favorable performance of the process.     

An Experiment with Forced Oxygenation of the Deepwater of the Anoxic By Fjord,Western Sweden

In a 2.5-year-long environmental engineering experiment in the By Fjord, surface water was pumped into the deepwater where the frequency of deepwater renewals increased by a factor of 10. During the experiment, the deepwater became long-term oxic, and nitrate became the dominating dissolved inorganic nitrogen component. The amount of phosphate in the water column decreased by a factor of 5 due to the increase in flushing and reduction in the leakage of phosphate from the sediments when the sediment surface became oxidized. Oxygenation of the sediments did not increase the leakage of toxic metals and organic pollutants. The bacterial community was the first to show changes after the oxygenation, with aerobic bacteria also thriving in the deepwater. The earlier azoic deepwater bottom sediments were colonized by animals. No structural difference between the phytoplankton communities in the By Fjord and the adjacent Havsten Fjord, with oxygenated deepwater, could be detected during the experiment.

Electronic supplementary material

The online version of this article (doi:10.1007/s13280-014-0524-9) contains supplementary material, which is available to authorized users.     

Energy consumption and emission projection for the road transport sector in Malaysia: an application of the LEAP model

This study has attempted to estimate the energy consumption and emission of pollutants namely carbon dioxide (CO₂), carbon monoxide (CO), nitrogen oxides (NOx) and non-methane volatile organic compounds (NMVOC) from the road transport sector in Malaysia from the year 2012 till 2040. This was done using the long-range energy alternatives planning (LEAP) model. Estimates of energy consumption and emissions were evaluated and analysed under a business-as-usual scenario and three other alternative fuel policy scenarios of biodiesel vehicles (BIO), natural gas vehicles (NGV) and hybrid electric vehicles (HEV). The aim of this study has been to identify the potential alternative fuel policies that would be effective in reducing the future growth of road transport energy consumption and emission in Malaysia. Results indicate that the NGV scenario contributes towards the highest reduction in road transport energy consumption followed by BIO and HEV. The NGV scenario also achieves highest mitigation of emission of all the four pollutants. In the case of CO₂ emission, BIO scenario attains second highest mitigation, whereas in the event of CO, NOx and NMVOC emission, HEV scenario achieves second highest mitigation.     

Photocatalytic degradation of triclocarban in aqueous solution using a modified zeolite/TiO2 composite: kinetic,mechanism study and toxicity assessment

Environmental Science and Pollution Research - The current work aimed to investigate the degradation of the triclocarban (TCC) in aqueous solution using a modified zeolite/TiO2 composite (MZTC)...     

Marine dredged sediments as new materials resource for road construction

Large volumes of sediments are dredged each year in Europe in order to maintain harbour activities. With the new European Union directives, harbour managers are encouraged to find environmentally sound solutions for these materials. This paper investigates the potential uses of Dunkirk marine dredged sediment as a new material resource for road building. The mineralogical composition of sediments is evaluated using X-ray diffraction and microscopy analysis. Since sediments contain a high amount of water, a dewatering treatment has been used. Different suitable mixtures, checking specific geotechnical criteria as required in French standards, are identified. The mixtures are then optimized for an economical reuse. The mechanical tests conducted on these mixtures are compaction, bearing capacity, compression and tensile tests. The experimental results show the feasibility of the beneficial use of Dunkirk marine dredged sand and sediments as a new material for the construction of foundation and base layers for roads. Further research is now needed to prove the resistance of this new material to various environmental impacts (e.g., frost damage).     

Reviewing biomimicry design case studies as a solution to sustainable design

There have been many studies on bio-inspired research, where biomimicry capabilities facilitating sustainable designs are in dearth. For a sustainable design, it is necessary to consider water efficiency, zero waste, thermal environment, and energy supply. This paper investigates how biomimicry is adopted in the sustainable design of buildings. A thorough content analysis of eight case studies focused on the built environment and how biomimicry integrated with the design of a building was executed. The selection of cases study was based on the concept of biomimicry by taking inspiration from nature and applying them in the everyday built environment. Thus, the building designs are more ecologically sustainable than conventional ones, where biomimicry approaches and principles are adopted. The findings suggest that the design of a building can inspire society with new ecological morals, where understanding of biological morphogenesis can inspire design to resolve challenges and essentially help create a healthy environment. Biomimicry harnesses and replicates the principles found in nature to create a built environment that benefits people and other living creatures and safeguards biodiversity. Thus, adopting biomimicry in designing a building will help to develop a culture of active environmental design.

     

Electrochemical and optical sensors made of composites of metal–organic frameworks and carbon-based materials. A review

Environmental Chemistry Letters - Rapid and selective sensing of biological substances and pollutants is developing rapidly in medicine and environmental sciences. Sensing performance depends on...