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Karen Kennedy Darryl W. Hawker Steve Carter Jochen F. Mueller 《Environmental pollution (Barking, Essex : 1987)》2010,158(1):142-147
Performance reference compound (PRC) derived sampling rates were determined for polyurethane foam (PUF) passive air samplers in both sub-tropical and temperate locations across Australia. These estimates were on average a factor of 2.7 times higher in summer than winter. The known effects of wind speed and temperature on mass transfer coefficients could not account for this observation. Sampling rates are often derived using ambient temperatures, not the actual temperatures within deployment chambers. If deployment chamber temperatures are in fact higher than ambient temperatures, estimated sampler-air partition coefficients would be greater than actual partition coefficients resulting in an overestimation of PRC derived sampling rates. Sampling rates determined under measured ambient temperatures and estimated deployment chamber temperatures in summer ranged from 7.1 to 10 m3 day−1 and 2.2-6.8 m3 day−1 respectively. These results suggest that potential differences between ambient and deployment chamber temperatures should be considered when deriving PRC-based sampling rates. 相似文献
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Toms LM Guerra P Eljarrat E Barceló D Harden FA Hobson P Sjodin A Ryan E Mueller JF 《Chemosphere》2012,89(4):398-403
Brominated flame retardants, including hexabromocyclododecane (HBCD) and polybrominated diphenyl ethers (PBDEs) are used to reduce the flammability of a multitude of electrical and electronic products, textiles and foams. The use of selected PBDEs has ceased, however, use of decaBDE and HBCD continues. While elevated concentrations of PBDEs in humans have been observed in Australia, no data is available on other BFRs such as HBCD. This study aimed to provide background HBCD concentrations from a representative sample of the Australian population and to assess temporal trends of HBCD and compare with PBDE concentrations over a 16 year period. Samples of human milk collected in Australia from 1993 to 2009, primarily from primiparae mothers were combined into 12 pools from 1993 (2 pools); 2001; 2002/2003 (4 pools); 2003/2004; 2006; 2007/2008 (2 pools); and 2009. Concentrations of ∑HBCD ranged from not quantified (nq) to 19 ng g(-1)lipid while α-HBCD and γ-HBCD ranged from nq to 10 ng g(-1)lipid and nq to 9.2 ng g(-1)lipid. β-HBCD was detected in only one sample at 3.6 ng g(-1)lipid while ∑(4)PBDE ranged from 2.5 to 15.8 ng g(-1)lipid. No temporal trend was apparent in HBCD concentrations in human milk collected in Australia from 1993 to 2009. In comparison, PBDE concentrations in human milk show a peak around 2002/03 (mean ∑(4)PBDEs=9.6 ng g(-1)lipid) and 2003/04 (12.4 ng g(-1)lipid) followed by a decrease in 2007/08 (2.7 ng g(-1)lipid) and 2009 (2.6 ng g(-1)lipid). In human blood serum samples collected from the Australian population, PBDE concentrations did not vary greatly (p=0.441) from 2002/03 to 2008/09. Continued monitoring including both human milk and serum for HBCD and PBDEs is required to observe trends in human body burden of HBCD and PBDEs body burden following changes to usage. 相似文献
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Kaserzon SL Kennedy K Hawker DW Holling N Escher BI Booij K Mueller JF 《Chemosphere》2011,84(4):497-503
N-Nitrosamines such as N-nitrosodimethylamine (NDMA) are organic compounds of environmental concern in groundwater, wastewater and potable water due to their potent carcinogenicity in laboratory animal studies and probable human carcinogenicity. While passive sampling techniques have become a widely used tool for providing time-averaged estimates of trace pollutant concentration, for chemicals such as NDMA that have relatively high water solubility, the selection of a suitable sorbent is difficult. This work is a proof of principle study that investigated for the first time the use of coconut charcoal as a passive sampler sorbent. Apparent charcoal/water sorption coefficients for NDMA were >551 mL g−1 at environmentally relevant aqueous concentrations of less than 1 μg L−1. Under the experimental conditions employed, a sampling rate of 0.45 L d−1 was determined and for an aqueous concentration of 1000 ng L−1, it is predicted that the sampler remains in the linear uptake stage for approximately 4 d, while equilibrium attainment would require about 26 d. The presence of humic acid, used as a surrogate for DOC, enhanced NDMA sorption on the coconut charcoal. 相似文献
308.
海外耕地投资是中国企业走出去,参与国际投资合作,获取耕地资源的重要手段。海外耕地投资能够通过国际合作和粮食进口,增加中国粮食供给,对国内粮食市场产生重大影响。基于柯布道格拉斯生产函数模型,对粮食播种面积、粮食成灾面积、农业机械总动力、农村用电量、粮食生产劳动力人数、有效灌溉面积、农业产品生产价格指数、农膜施用量、化肥施用折纯量、农药施用量等10个因素进行模型参数筛选,拟合中国粮食总产量关于粮食产量影响因子的函数关系,测算中国国内粮食生产总量;同时通过时间序列数据拟合出口粮、工业用粮、饲粮、种子粮以及粮食损耗的函数模型,测算中国国内粮食需求总量;在此基础上,通过情景分析法模拟不同情景下,中国在海外生产的粮食进入中国市场的比例,并以此作为影响中国粮食总产量的因子之一,构建关于中国粮食总供给的函数模型,分别测算不同情境中海外耕地投资生产的粮食对中国粮食供给安全的影响程度。研究结果表明,悲观情景和一般情境中,海外耕地投资生产的粮食对中国粮食安全的影响并不显著,乐观情境中中国海外耕地投资对中国粮食安全产生显著影响。进一步研究表明,当海外耕地投资粮食进口率超过75.3%时,海外耕地投资会对中国粮食供给安全产生显著影响。研究结论和建议:目前中国海外耕地投资对中国粮食安全的影响并不显著;中国的海外耕地投资能够直接或间接增加中国粮食供给,并且供给量显著提高,存在提高中国粮食供给率,保障国家粮食安全的巨大潜力,决策部门需要重视海外耕地投资,引导海外耕地投资良性发展。 相似文献
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AL Heffernan K English LML Toms AM Calafat L Valentin-Blasini P Hobson S Broomhall RS Ware P Jagals PD Sly JF Mueller 《Environmental science and pollution research international》2016,23(23):23436-23448
A range of pesticides are available in Australia for use in agricultural and domestic settings to control pests, including organophosphate and pyrethroid insecticides, herbicides, and insect repellents, such as N,N-diethyl-meta-toluamide (DEET). The aim of this study was to provide a cost-effective preliminary assessment of background exposure to a range of pesticides among a convenience sample of Australian residents. De-identified urine specimens stratified by age and sex were obtained from a community-based pathology laboratory and pooled (n = 24 pools of 100 specimens). Concentrations of urinary pesticide biomarkers were quantified using solid-phase extraction coupled with isotope dilution high-performance liquid chromatography–tandem mass spectrometry. Geometric mean biomarker concentrations ranged from <0.1 to 36.8 ng/mL for organophosphate insecticides, <0.1 to 5.5 ng/mL for pyrethroid insecticides, and <0.1 to 8.51 ng/mL for all other biomarkers with the exception of the DEET metabolite 3-diethylcarbamoyl benzoic acid (4.23 to 850 ng/mL). We observed no association between age and concentration for most biomarkers measured but noted a “U-shaped” trend for five organophosphate metabolites, with the highest concentrations observed in the youngest and oldest age strata, perhaps related to age-specific differences in behavior or physiology. The fact that concentrations of specific and non-specific metabolites of the organophosphate insecticide chlorpyrifos were higher than reported in USA and Canada may relate to differences in registered applications among countries. Additional biomonitoring programs of the general population and focusing on vulnerable populations would improve the exposure assessment and the monitoring of temporal exposure trends as usage patterns of pesticide products in Australia change over time. 相似文献
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应对气候变化的林业行动及其对就业的影响 总被引:1,自引:0,他引:1
当前,气候变化、可持续发展和就业问题备受世人瞩目。本文首先概述了气候变化、森林、林业与就业的相关关系;阐述了中国应对气候变化的主要林业行动框架,归纳出林业碳增汇、碳贮存和碳替代是林业应对气候变化的三种主要方式;并介绍了中国积极实施天然林保护工程、退耕还林等林业重点工程,大力发展碳汇林业和能源林业的具体实践;进而定性分析了中国林业重点行动对就业的正负面影响,并以广西碳汇试点项目为例加以佐证,最后阐明了中国林业发展及就业的潜力。研究结果表明,林业通过碳增汇、碳贮存和碳替代三种主要途径和系列行动,为减缓和适应全球气候变化做出了积极的贡献;应对气候变化的造林绿化等一系列林业行动对就业产生了积极的影响;此外,我国未来林业用地开发利用潜力、物种资源利用潜力和林业产业开发潜力巨大,由此创造的就业潜力也十分可观。因此,在当前全球气候变暖和经济衰退的双重压力下,加大林业领域投资,大力增加森林碳汇,并促进林业绿色就业具有重要的战略意义。 相似文献