Economic valuation of Shadegan International Wetland,Iran: notes for conservation

Wetlands are among the most productive ecosystems on the earth. They produce various market and non-market goods and services, which have a significant role in human welfare. Despite the great opportunities from sustainable development, wetlands all over the world are under serious threat from a diverse range of non-sustainable activities. One of the major reasons for excessive depletion and the conversion of wetland resources is due to underestimating the non-market values of wetlands during development decisions. Shadegan International Wetland (SIW) in southern Iran is one of these wetland areas that is threatened by undervaluation and overexploitation from commercial activities. This study utilizes the contingent valuation method to estimate the economic benefits of SIW from the view point of peoples’ willingness to pay (WTP). The logit model was defined based on dichotomous choice to measure individuals’ WTP. The estimated mean WTP was US$ 1.74 per household as a onetime donation. This study concludes that the benefits of SIW to society could encourage managers to set priorities to ensure that the health of the ecosystem, its integrity, and its uniqueness would be conserved in a proper manner.     

Synthesis and biological activities of new azacrown ether Schiff bases and spectrophotometric studies of their complexation with [60]fullerene

A series of novel azacrown ether Schiff bases 1–3 have been synthesized in good yield and in a simple way. Their host–guest interaction with [60]fullerene has been studied in toluene by absorption spectroscopic method. All the complexes are found to be stable with 1:1 stoichiometry. Because of their potential applications in industry, agriculture and medicine, they were investigated for their mutagenic and antimutagenic activities using the spot test and the plate incorporation assay of Ames. Compounds 1, 2 and 3 were found to be nonmutagenic in the Ames test using strains TA 1535, TA100 and TA97a of Salmonella typhimurium. However, using strain TA102 revealed that, although both compounds 1 and 2 were nonmutagenic, compound 2 gave a positive response indicating that it acts as an oxidative mutagen. The structure-activity relationship may throw some light on the biological activity of such series of compounds.     

Foliar uptake of arsenic nanoparticles by spinach: an assessment of physiological and human health risk implications

Atmospheric contamination by heavy metal(loid)–enriched particulate matter (metal-PM) is highly topical these days because of its high persistence, toxic nature, and health risks. Globally, foliar uptake of metal(loid)s occurs for vegetables/crops grown in the vicinity of industrial or urban areas with a metal-PM-contaminated atmosphere. The current study evaluated the foliar uptake of arsenic (As), accumulation of As in different plant organs, its toxicity (in terms of ROS generation, chlorophyll degradation, and lipid peroxidation), and its defensive mechanism (antioxidant enzymes) in spinach (Spinacia oleracea) after foliar application of As in the form of nanoparticles (As-NPs). The As-NPs were prepared using a chemical method. Results indicate that spinach can absorb As via foliar pathways (0.50 to 0.73 mg/kg in leaves) and can translocate it towards root tissues (0.35 to 0.68 mg/kg). However, health risk assessment parameters showed that the As level in the edible parts of spinach was below the critical limit (hazard quotient <?1). Despite low tissue level, As-NP exposure caused phytotoxicity in terms of a decrease in plant dry biomass (up to 84%) and pigment contents (up to 38%). Furthermore, several-fold higher activities of antioxidant enzymes were observed under metal stress than control. However, no significant variation was observed in the level of hydrogen peroxide (H₂O₂), which can be its possible transformation to other forms of reactive oxygen species (ROS). It is proposed that As can be absorbed by spinach via foliar pathway and then disturbs the plant metabolism. Therefore, air quality needs to be considered and monitored continuously for the human health risk assessment and quality of vegetables cultivated on polluted soils (roadside and industrial vicinity).

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Residual effects of tobacco biochar along with different fixing agents on stabilization of trace elements in multi-metal contaminated soils

The residual effect of tobacco biochar(TB ≥ 500°C) mono and co-application with Cahydroxide(CH),Ca-bentonite(CB) and natural zeolite(NZ) on the bio-availability of trace elements TE(s) in alkaline soils has not been deeply studied yet.A pot study that had earlier been investigated TB mono and blended with CH,CB and NZ on the immobilization of Pb,Cu Cd,and Zn by Chinese cabbage.Maize crop in the rotation was selected as test plant to assess the residual impact of amendments on stabilization of Pb,Cu Cd,and Zn in mine polluted(M-P),smelter heavily and low polluted(S-HP and S-LP,respectively) soils.The obtained results showed that stabilization of Pb,Cd,Cu and Zn reached 63.84% with TB + CB,61.19% with TB + CH,83.31% with TB + CH and 35.27% with TB + CH for M-P soil,36.46% with TB + NZ,38.46% with TB + NZ,19.40% with TB + CH and 62.43% with TB + CH for S-LP soil,52.94% TB + NZ,57.65% with TB + NZ,52.94% with TB + NZ,and 28.44% with TB + CH for S-LP soil.Conversely,TB + CH and TB alone had mobilized Pb and Zn up to19.29% and 34.96% in M-P soil.The mobility of Zn reached 8.38% with TB + CB and 66.03%with TB for S-HP and S-LP soils.The uptake and accumulation of Pb,Cd,Cu and Zn in shoot and root were reduced in three polluted soils.Overall,the combination of TB along with CH,CB and NZ has been proven to be effective in Pb,Cd,Cu and Zn polluted mine/smelter soils restoration.     

Qualitatively and quantitatively assessing the aggregation ability of sludge during aerobic granulation process combined XDLVO theory with physicochemical properties

Inexact mechanism of aerobic granulation still impedes optimization and application of aerobic granules. In this study, the extended Derjaguin, Landau, Verwey, and Overbeek(XDLVO) theory and physicochemical properties were combined to assess the aggregation ability of sludge during aerobic granulation process qualitatively and quantitatively. Results show that relative hydrophobicity of sludge and polysaccharide content of extracellular polymeric substances(EPS) increased, while electronegativity of sludge decreased during acclimation phase. After 20 days' acclimation, small granules began to form due to high aggregation ability of sludge. Since then, coexisted flocs and granules possessed distinct physicochemical properties during granulation and maturation phase. The relative hydrophobicity decreased while electronegativity increased for flocs, whereas that for granules presented reverse trend. Through analyzing the interaction energy using the XDLVO theory, small granules tended to self-grow rather than self-aggregate or attach of flocs due to poor aggregation ability between flocs and granules during the granulation phase. Besides, remaining flocs were unlikely to self-aggregate owing to poor aggregation ability, low hydrophobicity and high electronegativity.     

RETRACTED ARTICLE: Consequences of health risk assessment of wastewater irrigation in Pakistan

Statement of Retraction

We, the Editors and Publisher of Toxicological & Environmental Chemistry, have retracted the following article:

Maria Sabeen, Qaisar Mahmood, Abdol Ghaffar Ebadi, Zulfiqar Ahmad Bhatti, Faridullah, Muhammad Irshad, Allauddin Kakar, Muhammad Bilal, Hafiz Muhammad Arshad and Naeem Shahid, ‘Consequences of health risk assessment of wastewater irrigation in Pakistan Israel Affairs’, Toxicological & Environmental Chemistry, 2019, DOI: 10.1080/02772248.2019.1619335

The article is retracted due to the oversights that were made during peer review process that resulted in the article being published online in error. Further review from independent reviewers was sought. This confirmed that the central findings and methodology of the study in question are unreliable and therefore unsuitable for publication.

We have been informed in our decision-making by our policy on publishing ethics and integrity and the COPE guidelines on retractions.

The retracted article will remain online to maintain the scholarly record, but it will be digitally watermarked on each page as “Retracted”.     

Routinization of job context and job content as related to employees' quality of working life: A study of Canadian nurses

The literature on routinization of work is both ambiguous and equivocal when its impact on quality of working life is considered. The classical management literature suggests that routinization of work has a positive influence on individual performance and by implication on the quality of working life resulting from the overall prosperity generated. However, more recent literature on job characteristics and job design argues that routinization of work has a negative impact on individual performance as it suppresses creative expression on the job. This paper suggests that these mixed findings are due to an inadequate theoretical grasp of the concept of routinization and presents empirical evidence which attempts to clarify the ambiguity. Data were collected from 1148 nurses working in anglophone hospitals in the greater Montreal area in the form of a field survey questionnaire. The results indicated that nurses who worked routine shifts perceived higher levels of quality of working life compared to those on non-routine shifts. The results also indicated that nurses who experienced high routinization in job content perceived lower levels of quality of working life compared to those nurses who experienced low routinization in job content. Implications of these findings for future research are discussed.     

Shiftwork and department-type related to job stress,work attitudes and behavioral intentions: A study of nurses

The present study examined the relationship of shiftwork and department-type with employees' job stress, stressors, work attitudes and behavioral intention. Data were collected by means of a structured questionnaire from nurses (N = 1148) working in eight hospitals in a large, metropolitan city in eastern Canada. One-way ANOVA, MANOVA and two-way ANOVA were used to analyze data. Results generally support the prediction that nurses working on fixed shifts were better off than nurses working on rotating shifts in terms of the dependent variables of the present study. The prediction that nurses working in non-intensive care departments were better off than nurses working in intensive care departments received mixed support at best. A few interaction effects of shiftwork × department-type on dependent variables were also noted. The impact of socio-demographic variables — age, marital status, cultural background (English- versus French-speaking) — on the above relationships were also analyzed. Results are discussed in light of the previous empirical evidence on shiftwork and department-type.     

STATUS AND PROSPECTS OF KAREZ IRRIGATION1

ABSTRACT: The karez is a traditional irrigation water source, consisting of hand-dug horizontal wells, that is still used in parts of South Asia, the Middle East, and North Africa. This paper describes the construction, management, and current problems of karez irrigation systems based on investigations conducted in Baluchistan Province, Pakistan. While karezes have served irrigation needs well in the past, they are now threatened by high costs of labor for construction and maintenance, and by the encroachment of tubewells which lower the water tables on which the karez systems depend. Possible methods for improving karez performance and needs for research are discussed.     

VALUING IRRIGATION WATER IN PUNJAB PROVINCE,PAKISTAN: A LINEAR PROGRAMMING APPROACH1

ABSTRACT: Linear programming models of a representative farm in a district of Pakistan's Punjab Province are formulated for the purpose of estimating the value of irrigation water. The models provide for choices among several irrigation levels for each potential crop. Solutions of the model for several water supply situations provide the basis for approximating the total, average, and marginal values of irrigation water. Prices for important crops in Pakistan are controlled at levels below their levels elsewhere in the world, so models are specified for both financial (domestic price) and economic (world price) scenarios. The value of water to society (its economic value) is high relative to the costs of some generally available water-augmenting investments, while financial values, which measure water management and allocation incentives faced by farmers, are less than the corresponding economic values. At current water supply levels, incremental returns to added water estimated from the economic model would justify investments in water-saving or water-augmenting technologies, while such a decision would be barely attractive assuming financial prices. While present government commodity price policies may serve to protect low-income and non-farm members of the population, they also inhibit farmer investments to increase the productivity of scarce irrigation water.