Dry deposition and soil-air gas exchange of polychlorinated biphenyls (PCBs) in an industrial area

Ambient air and dry deposition, and soil samples were collected at the Aliaga industrial site in Izmir, Turkey. Atmospheric total (particle + gas) ∑₄₁-PCB concentrations were higher in summer (3370 ± 1617 pg m⁻³, average + SD) than in winter (1164 ± 618 pg m⁻³), probably due to increased volatilization with temperature. Average particulate ∑₄₁-PCBs dry deposition fluxes were 349 ± 183 and 469 ± 328 ng m⁻² day⁻¹ in summer and winter, respectively. Overall average particulate deposition velocity was 5.5 ± 3.5 cm s⁻¹. The spatial distribution of ∑₄₁-PCB soil concentrations (n = 48) showed that the iron-steel plants, ship dismantling facilities, refinery and petrochemicals complex are the major sources in the area. Calculated air-soil exchange fluxes indicated that the contaminated soil is a secondary source to the atmosphere for lighter PCBs and as a sink for heavier ones. Comparable magnitude of gas exchange and dry particle deposition fluxes indicated that both mechanisms are equally important for PCB movement between air and soil in Aliaga.     

Detection of Y chromosome-specific DNA in the plasma and urine of pregnant women using nested polymerase chain reaction

The present study was undertaken to evaluate a nested polymerase chain reaction (PCR) for detection of Y chromosome-specific fetal DNA in maternal plasma and urine of pregnant women during different gestational stages. DNA isolated from plasma and urine samples of 80 pregnant women (between 7 and 40 weeks' gestation) underwent amplification for Y chromosome-specific 198 bp DNA by nested PCR. The postpartum analysis of fetal gender showed that 55 women carried male and 25 female fetuses. Among the 55 women bearing male fetuses, Y chromosome-specific signals were detected in 53 (96%) plasma and 21 (38%) urine samples. Moreover, out of 25 women bearing female fetuses, 3 (12%) and 1 (4%) women had Y chromosome-specific signal in plasma and urine, respectively. Analysis of results with respect to gestational age revealed that there was no significant difference in the detection of Y chromosome-specific DNA between different trimesters in maternal plasma of women bearing male fetuses. These results showed that fetus-specific DNA was detected with high sensitivity (96%) and specificity (88%) in the maternal plasma by nested PCR, and therefore the method could be useful as a non-invasive procedure for fetal sex determination and prenatal diagnosis. Copyright © 2001 John Wiley & Sons, Ltd.     

Maternal and cord blood levels of Aldrin and Dieldrin in Delhi population

Aldrin and dieldrin, structurally similar organochlorine pesticides belong to cyclodiene family and were widely used for agriculture and public health program in India. Although the manufacturing, use and import of aldrin and dieldrin have been banned in India since 2003, these pesticides are still persistent in environment and may be associated with adverse neurological and reproductive effects. The aim of this study is to assess the recent exposure level of aldrin and dieldrin and their placental transfer to fetus in normal healthy full-term pregnant women belonging to north Indian population undergoing normal delivery at Obstetrics and Gynecology department of UCMS and GTB hospital, Delhi. Quantitative analysis of aldrin and dieldrin residues in maternal and cord blood samples were carried out by gas chromatography system equipped with electron capture detector. The results of our study clearly revealed that maternal and cord blood levels of aldrin and dieldrin of pregnant women are age and dietary habit dependent. The aldrin level in maternal blood and dieldrin level in cord blood are higher in women in the age group 25–30 years than in women in age group of 19–24 years. Similarly, aldrin level in maternal blood is significantly higher in women with non-vegetarian dietary habit than in women with vegetarian dietary habit. No significant association is found for maternal and cord blood level. The results of the present study clearly demonstrate prenatal uptake of aldrin and dieldrin and provide recent information on the subsequent transplacental transfer.     

Appraisal of work hazards and safety in the industrial estate of Jeddah

An environmental study for the appraisal of work hazards and safety in Jeddah Industrial Estate (JIE), Saudi Arabia has been conducted. The study is based upon a representative (stratified random) sample of 44 enterprises, including 52 plants and employing 5830 workers. Nearly 2/3 of the workers have heat exposure, orginating from climatic heat and heat dissipated from industrial operations, while exposure to noise is slightly less, and is attributed to noisy operations and machinery and to lack of meticulous maintenance; both exposures are mild in most of the plants and moderate in some. Mild exposures to nonionizing radiations (UV and IR) and to deficient illumination occur in 25% and 19.2% of the plants studied. Respiratory exposure to chemical agents (organic and inorganic dusts, metal fumes, gases and vapours — including asphyxiants, irritants, liver and nervous system offenders and acid and alkali mists) occurs in 75% of the plants, particularly in the medium-size enterprises plants; however, is mainly mild with a few moderate and severe exposures. Skin absorption contributes to absorption of chemical agents in 29% of the plants, and direct skin contact to chemicals (particularly to lubricating oils) occurs in 81% of the plants. Meanwhile, only eight plants, out of the 32 plants where controls for physical hazards are required (51.2%), apply engineering controls, and even in a few of these plants the efficiency of the control measures has been rated ‘bad’. A few of them provide personal protective equipment, and even no maintenance to this equipment is provided. The level of safety is better in the large plants than in the small and medium-size plants; the safety score is the best in the recently established plants, while is the worst in the plastic industry, which is relatively old. The appraisal of fire protection is better than that of the safety, due to efficient supervision of the General Directorate of Civil Defense (GDCD). However, most of the safety problems are managerial and are preventable. First aid is present in all enterprises, as required by the Saudi Labor Laws; however, an in-plant medical service is present in 75% of the large enterprises, in 31.6% of the medium-size and in only 17.6% of the small enterprises. Also, satisfactory medical, accidents and absenteeism records exist in only 15.9% of the enterprises; safety supervision exists in 27.3, and safety education exists in 91% of them, while no environmental monitoring is carried out in any enterprise. Sanitation facilities exist in satisfactory numbers in most of the enterprises; however, their maintenance is poor in most of them, due to lack of hygienic supervision. All enterprises dispose of their liquid wastes into the JIE sewerage system without any treatment, while the solid wastes are collected by the city authorities in 56.8% of them; both wastes are anticipated to cause environmental pollution problems.     

The systemic heart of Octopus vulgaris: effects of exogenous arachidonic acid and capability for arachidonate metabolism

The actions of exogenous arachidonic acid on the performance of the isolated and perfused systemic heart of Octopus vulgaris (collected in the Bay of Naples in 1992), and the potential of this heart for eicosanoid synthesis are described. Arachidonic acid induces positive chronotropic and inotropic effects. The positive inotropic effect is apparent only at the lowest concentration used (10^–7 M) and in the paced heart preparations, in which a negative relationship between stroke volume and heart rate has been demonstrated. Using 10^–5 M arachidonate, which induces the greatest chronotropic effect, a reduction of inotropism is evident which is due to the above negative relationship between stroke volume and heart rate. These effects are scarcely affected by the cyclooxygenase and lipoxygenase inhibitors, indomethacin (IM) and nordihydroguaiaretic acid (NDGA), respectively. On the coronary system of this heart arachidonic acid displays a potent vasoconstrictory action (ca. 100 percent increase of coronary resistance). This effect is potentiated by IM and reduced by NDGA. ¹⁴C-arachidonate is metabolized by the octopus ventricle homogenate into the lipoxygenase products (assayed as hydroxy acids) more actively than into cyclooxygenase products (prostanoids: PGE₂, PGD₂, PGF₂ and 6-keto-PGF₁). On the other hand, the Ca-ionophore A23187 enhances the production of cyclooxygenase metabolites much more than of lipoxygenase metabolites.     

Solute Transport in Open-Channel Networks in Unsteady Flow Regime

In this paper we propose a robust algorithm to evaluate solute transport in open-channel networks with transient storage under an unsteady flow regime. In the proposed approach, through the integration of junction equations into the model and solving them explicitly, the analysis of solute transport problems in open-channel networks is simplified significantly. Furthermore, when coupled with a transient hydrodynamic open-channel network model for flow simulation, the proposed model can be utilized in the solution of solute transport problems under unsteady flow regimes. In the proposed model, the governing equations are written in a conservative form and are solved using a fractional-step algorithm, which is based on a relaxation and central difference scheme. The proposed algorithm is robust and accurate even for advection dominant cases. A pure advection with discontinuities, a field application and solute transport in an open-channel network in an unsteady flow regime are included, to demonstrate the performance of the proposed algorithm.     

Concentrations and gas/particle partitioning of PCBs in Chicago

Thirty seven air samples were collected in Chicago, IL from June to October 1995 and analyzed for gas and particle concentrations of polychlorinated biphenyls (PCBs). Lower molecular weight (MW) PCBs dominated the samples and on average 95% of the Sigma50PCB concentration (gas+particulate) was in the vapor phase. Sigma50PCB concentrations were classified based on prevailing winds (lake and land). The Sigma50PCB concentration varied between 0.42 and 5.21 ng/m3 (1.80+/-1.70 ng/m3) for lake and 0.53 and 8.31 ng/m3 (2.41+/-2.15 ng/m3) for land wind directions. Back trajectory analyses suggested that SW of Chicago can be an important local or regional source sector for PCBs. Partitioning between gas and particulate phases was modeled using the Junge-Pankow model. The measured particle phase concentrations for low MW PCBs were lower than those predicted by the model while the opposite was observed for high MW PCBs. Plots of gas/particle partition coefficient (log Kp) vs. subcooled liquid vapor pressure (log pL(0)) had reasonable correlations for individual samples but the slope varied among the samples. Samples that originated from over the lake had higher slopes than samples that originated from over the land.     

Polymer Supported Calix[4]Arene Derivatives for the Extraction of Metals and Dichromate Anions

Three newly synthesized polymer supported calix[4]arene ionophores (7–9) were synthesized, and their ion binding properties toward selected alkali (Li⁺, Na⁺, K⁺, Cs⁺) and transition metal (Hg²⁺, Ni²⁺, Cu²⁺, Co²⁺, Cd²⁺, and Pb²⁺) cations were investigated. It has been observed that these ionophores are not selective toward a particular metal cation but show better ion binding property as compared to monomeric calixarene derivatives (2 and 6). Ionophore 6 and its supported polymer were also employed in dichromate anion extraction experiments. The polymeric ionophore (9) was found an effective extractant for dichromate anion even at pH 7.