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561.
City hazardous gas monitoring network 总被引:2,自引:0,他引:2
In our today's societies, many dangerous chemicals are produced and transported. Due to the vast use of chemicals, more chemical accidents are taking place with huge losses. In this study a city hazardous gas monitoring network was designed to detect the dispersion of toxic and combustible gases in the primary stages. The network could cover hazardous chemical facilities, important hazardous chemical routes, warehouses and special locations which may be the targets of terrorist attacks. The network is consisted of several local networks and a central control panel complex. Each local network has a local control panel in the center and many detectors and sounders around it at distances less than 3000 m that communicate with the local control panels wirelessly. In each location there are two types of gas detectors, toxic and combustible, and a sounder which are equipped with a wireless, radio frequency modem allowing the units to communicate readings and other information on a real-time basis with a remotely located local control panel. High sensitive Photo Ionization Detectors, PIDs, are used to provide fast and low-level on-site screening for chemicals contamination. Combustible gas detectors are the second choice to sense the combustible gas and verify the readings of PIDs in this regard. The central panel consists of several connected control panels work uniquely helping a computer set and the appropriate software and communicate with local control panels via telephone lines. All of the network components are shown on the monitor of central panel with special symbols by geographical information system program. The system is fully addressable so that the high level detection of a detector produces a blinking color double-circle around its symbol in GIS plan. In case of high level gas detection, a team of experts who are fully equipped with different portable detectors depart to the site to test the field to identify the chemicals. All readings of detectors are saved in a data bank and then analyzed to find any chemicals spills and leakages. The network was simulated by a special program so that the components of local networks and the central panel are shown in separate windows. By clicking on one detector on environmental window the formerly designed responses will be activated in central panel window. 相似文献
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We draw on the economic, corporate governance, and family business literatures to explain why the effects of family on family firms makes this governance form theoretically distinct from those of public and private non‐family firms. Our thesis is that parental altruism, when combined with private ownership and owner‐management, influences the ability of the firm's owner‐manager to exercise self‐control, which, in turn, can expose some family firms to conflicts rooted in the agency threats of moral hazard, hold‐up, and adverse selection. We then discuss why some other family firms are able to minimize these dark side threats and thereby attain altruism's brighter side. Finally, we discuss how altruism's influence changes over time as ownership becomes dispersed among family members and across generations. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
565.
Rai S. Kookana Raymond L. Correll Rosalind B. Miller 《Water, Air, & Soil Pollution: Focus》2005,5(1-2):45-65
Pesticide users, natural resource managers, regulators, government agencies and many others are concerned about the off-site
impact of pesticides on the environment. Systematic methods of the assessment of potential risk of pesticides to environmental
components can serve as valuable tools in decision making and policy formulation. Simple risk indicators have been developed
which cover a range of scenarios such as toxicity to organisms, health of farm workers, consumer health, and residues in harvested
produce. The authors have developed a software package named Pesticide Impact Rating Index (PIRI) that outputs an improved
pesticide risk indicator for water quality. PIRI is a standalone, user-friendly, platform-independent program. It can be used
to (i) rank pesticides in terms of their relative pollution potential to groundwater or surface water, and (ii) to compare
different land uses in a catchment or at a regional scale in terms of their relative impact on water quality. It is based
on pesticides use; the pathway through which the pesticides are released to the water resources (drift, runoff, erosion, leaching)
and the value of the water resources threatened. Each component is quantified using pesticide characteristics (including toxicity
to organisms at different trophic levels, i.e. fish, daphnia, algae, etc.), environmental and site conditions (e.g. organic
carbon content of soil, water input, slope of land, soil loss, recharge rate, depth of water table, etc.). This paper describes
two case studies of the application of PIRI in Australia. The comparison of the risk assessment by PIRI on these revealed
that PIRI correctly estimated the pollution potential of pesticides in greater than 80% of cases. A GIS version of PIRI is
described in a companion paper in this volume.
An erratum to this article is available at . 相似文献
566.
Davey L. Jones John F. Farrar Kevin K. Newsham 《Water, Air, & Soil Pollution: Focus》2005,4(6):169-175
Amino acids constitute one of the largest inputs of organic nitrogen (N) to most polar soils and have been hypothesized to be important in regulating vegetational succession and productivity in Arctic ecosystems. Our understanding of amino acid cycling in these soils, however, is poor. The aim of this study was to investigate the size and rate of turnover of the amino acid pool in a range of Arctic and Antarctic soils. Our results indicate that in polar soils with either high or low ornithogenic inputs the amino acid pool is small in comparison to the inorganic N pool (NO? 3 and NH+ 4). The free amino acid pool constituted only a small proportion of the total dissolved organic nitrogen (DON) pool in these soils. Here we show that these low concentrations may be due to rapid use by the soil microbial community in both Arctic and Antarctic soils. The turnover of the amino acid pool in soil was extremely rapid, with a half-life ranging from 2 to 24 h, indicating that this N pool can be turned over many hundred times each summer when polar soils are frequently unfrozen. The implications of amino acids in N cycling and plant and microbial nutrition are discussed. 相似文献
567.
P. Hill C. Marshall H. Harmens D. L. Jones J. Farrar 《Water, Air, & Soil Pollution: Focus》2005,4(6):177-186
Soil respiration is a large C flux which is of primary importance in determining C sequestration. Here we ask how it is altered by atmospheric CO2 concentration and N additions. Swards of Lolium perenne L. were grown in a Eutric cambisol under controlled conditions with and without the addition of 200 kg NO? 3 ?N ha?1, at either 350 ppm or 700 ppm CO2, for 3 months. Soil respiration and net canopy photosynthesis were both increased by added N and elevated CO2, but soil respiration increased proportionately less than fixation by photosynthesis. Thus, both elevated CO2 and N appeared to increase potential C sequestration, although adding N at elevated CO2 reduced the C sequestered as a proportion of that fixed relative to elevated CO2 alone. Across all treatments below-ground respiratory C losses were predicted by root biomass, but not by soil solution C and N concentrations. Specific root-dependent respiration was increased by elevated CO2, such that below-ground respiration per unit biomass and per unit plant N was increased. 相似文献
568.
L. J. Sheppard A. Crossley I. D. Leith K. J. Hargreaves J. A. Carfrae N. van Dijk J. N. Cape D. Sleep D. Fowler J. A. Raven 《Water, Air, & Soil Pollution: Focus》2005,4(6):197-205
Critical N loads for ombrotrophic bogs, which often contain rare and N-sensitive plants (especially those in lower plant groups: lichens, mosses and liverworts), are based on very few experimental data from measured, low background N deposition areas. Additionally the relative effects of reduced versus oxidised N are largely unknown. This paper describes an automated field exposure system (30 km S. of Edinburgh, Scotland) for treating ombrotrophic bog vegetation with fine droplets of oxidised N (NaNO3) and reduced N (NH4Cl). Whim Moss exists in an area of low ambient N deposition (ca. 8 kg N ha?1 y?1), the sources and quantification of which are described. The wet N treatment system is run continuously, and is controlled/activated by wind speed and rainfall to provide a unique simulation of “real worl” treatment patterns (no rain=no treatment). Simulated precipitation is supplied at ionic concentrations below 4 mM in rainwater collected on site. Treatments provide a replicated dose response to 16, 32 and 64 kg N ha?1 y?1 adjusted for ambient deposition (8 kg N ha?1 y?1). The 16 and 64 kg N ha?1 y?1 are duplicated with a P+K supplement. Baseline soil chemistry and foliar nutrient status was established for all 44 plots for Calluna vulgaris, Sphagnum capillifolium, Hypnum jutlandicum and Cladonia portentosa. 相似文献
569.
R. Skinner P. Ineson W. K. Hicks H. E. Jones D. Sleep I. D. Leith L. J. Sheppard 《Water, Air, & Soil Pollution: Focus》2005,4(6):219-228
A field ammonia (NH3) release experiment and open top chambers containing moorland monoliths continuously fumigated with NH3 or sprayed with NH4Cl were used to assess the potential for using δ15N values in determining the area of influence around a point NH3 emission source. δ15N values are being increasingly used as environmental tracers and we tested the hypothesis that the δ15N signal from an NH3 emission source is observable in nearby vegetation. Using modified monitoring devices, atmospheric NH3 concentrations were found to decrease with distance from source, with δ15N values also reflecting this trend, producing a signal shift with changing concentration. Open top chamber studies of δ15N values of Calluna vulgaris (L.) Hull indicated a correlation with deposition treatments in current year shoots. Analysis of Calluna shoots from the NH3 release showed a similar trend of δ15N enrichment. Significant linear correlations between δ15N and percent N in plant material were found, both in the controlled conditions of the open top chambers and at the NH3 release site, illustrating the possible use of this technique in N deposition biomonitoring. 相似文献
570.
S. A. Power M. R. Ashmore A. C. Terry S. J. M. Caporn M. G. Pilkington D. B. Wilson C. G. Barker J. A. Carroll N. Cresswell E. R. Green G. W. HEIL 《Water, Air, & Soil Pollution: Focus》2005,4(6):259-267
The results from three long-term field manipulation studies of the impacts of increased nitrogen deposition (0–120 kg N ha?1 yr?1) on lowland and upland heathlands in the UK were compared, to test if common responses are observed. Consistent increases in Calluna foliar N content and decreases in litter C:N ratios were found across all sites, while increases in N leaching were not observed at any site over the range 0–80 kg ha?1 yr?1. However, the response of Calluna biomass did vary between sites, possibly reflecting site differences in nutrient status and management histories. Five versions of a simulation model of heathland responses to N were developed, each reflecting different assumptions about the fate and turnover of soil N. Model outputs supported the deduction from mass balance calculations at two of the field sites that N additions have resulted in an increase in immobilisation; the latter was needed to prevent the model overestimating measured N leaching. However, this version of the model significantly underestimated Calluna biomass. Model versions, which included uptake of organic N by Callunaand re-mobilisation of N from the soil organic store provided some improvement in the fit between modelled and field biomass data, but re-mobilisation also led to an overestimation of N leaching. Quantification of these processes and their response to increased N deposition are therefore critical to interpreting experimental data and predicting the long-term impacts of atmospheric deposition on heathlands and moorlands. 相似文献