Rotary Kiln Incineration IV. An Indepth Study— Kiln Exit,Transition and Afterburner Sampling During Liquid CCl4 Processing

Detailed temperature and stable species concentration data are presented from the kiln exit, transition section and afterburner of a full-scale incinerator facility firing natural gas/carbon tetrachloride/air. The data are collected as part of a cooperative program involving university, industry and government participation. The overall goal of the program is to develop an understanding and predictive capability for rotary kiln and afterburner performance as influenced by basic design and operational parameters. The data demonstrate that nonuniformities in stable species and temperature exist, under certain operating conditions, at the kiln exit in the vertical direction only. Measurements from the transition section indicate that non-uniformities may exist within this region under certain operating conditions. Flow perturbations from within the kiln can persist into the afterburner, although the degree of nonuniformity is substantially reduced compared to either the kiln or transition sections. High destruction and removal efficiencies were achieved under all operating conditions of these tests through a combination of kiln and secondary combustion processing.     

Biodegradation of carbofuran in soils within Nzoia River Basin,Kenya

Carbofuran (2,3-dihydro-2,2-dimethylbenzofuran-7-yl methylcarbamate) has been used within the Nzoia River Basin (NRB), especially in Bunyala Rice Irrigation Schemes, in Kenya for the control of pests. In this study, the capacity of native bacteria to degrade carbofuran in soils from NRB was investigated. A gram positive, rod-shaped bacteria capable of degrading carbofuran was isolated through liquid cultures with carbofuran as the only carbon and nitrogen source. The isolate degraded 98% of 100-μg mL^?1 carbofuran within 10 days with the formation of carbofuran phenol as the only detectable metabolite. The degradation of carbofuran was followed by measuring its residues in liquid cultures using high performance liquid chromatography (HPLC). Physical and morphological characteristics as well as molecular characterization confirmed the bacterial isolate to be a member of Bacillus species. The results indicate that this strain of Bacillus sp. could be considered as Bacillus cereus or Bacillus thuringiensis with a bootstrap value of 100% similar to the 16S rRNA gene sequences. The biodegradation capability of the native strains in this study indicates that they have great potential for application in bioremediation of carbofuran-contaminated soil sites.     

Ozone-driven photocatalyzed degradation and mineralization of pesticide,Triclopyr by Au/TiO2

Triclopyr is a widely used pesticide which is non-biodegradable and enters aquatic systems. The ozone facilitated photocatalyzed degradation and mineralization of Triclopyr using Au-loaded titania as heterogeneous catalyst is reported. The oxidative degradation activity of the hazardous pesticide was investigated at pH 7.8 under varied reaction conditions, including in presence and absence of ozone, titania alone, in presence and absence of light and with different loadings of Au on support. Photocatalysis with 2% Au/TiO₂ in the presence of ozone yielded 100% degradation of Triclopyr in 2 h. The extent of degradation of pesticide and its mineralization were confirmed by GC-MS. For 10 mg/L of Triclopyr, 0.1 g/L of catalyst was found to be the optimum for mineralization. Results show that photocatalyzed ozonation with Au/TiO₂ as catalyst is a very effective for its removal. No leaching of Au was observed in triplicate runs. Catalyst was fully recoverable and reusable with no loss of activity.     

Metabolic fate of dichloromethyl‐0,0‐diphenyl phosphonate (I) and dichloromethyl‐0,0‐di‐(p‐nitrophenyl) phosphonate (II) in/on rice plants∗

Abstract

Metabolic fate of two dichloromethyl diaryl phosphonates (³²P labelled) in/on rice plants was investigated. The test compounds were found to be less persistent on the surface of rice leaves with half lives 7.4 and 6.7 days respectively. Main degradation product from both the phosphonates were dichloromethyl phosphonic acid with trace of dichloromethyl‐O‐aryl phosphonate as a transitory intermediate product.     

Persistence and biodegradation of carbaryl in soils

Abstract

The persistence of the methylcarbamate pesticide carbaryl was studied in four soils under flooded conditions. A substantial portion of the pesticide was recovered from all soils even after 15 days of its application, with the recovery ranging from 37% in an alluvial soil to 73% in an acid sulfate soil. The degradation of carbaryl was more rapid under flooded conditions than under nonflooded conditions. A bacterium, Pseudomonas cepacia, isolated from a flooded soil amended with a related methylcarbamate pesticide carbofuran, degraded carbaryl in a mineral medium supplemented with yeast extract.     

Clinical effects and cholinesterase activity changes in workers exposed to phorate (Thimet)

Abstract

Phorate (Thimet), an aliphatic derivative of phospnorus is a hignly toxic insecticide. In order to implement the safety measures, the clinical manifestations and cholinesterase (ChE) activity were evaluated before and after 2 weeks of exposure to this insecticide in 40 male tormulators.

The 2 week's exposure reveal signs and symptoms of toxicity in 60% of the formulators. Gastrointestinal symptoms and lowering of heart rate (bradycardia) were more prominent as compared to the neurological symptoms. A significant depression in plasma ChE activity was observed at the end of 1st week (55%) and 2nd week (71%) as compared to the respective pre‐exposure values. A recovery up to 79% of the pre‐exposure activity of this enzyme was noticed 10 days after cessation of the above exposure.     

Minimizing drift and exposure from knapsack sprayers

Abstract

An improved drift shield for attaching to the lance of conventional knapsack sprayer to reduce wind induced drift and operator exposure was designed and tested. The drift shield consists of a conical wire frame covered with polythene and has an annular opening at the point of attachment to the lance which allows air to be drawn into the shield while spraying. Tests conducted with winds in the range of 1.25–5.75 m/s show that wind can increase the width of spray swath from an unshielded lance, up to 4.3 times the normal swath in no‐wind condition. Use of a conventional shield contained the swath width within 3.5 times and the improved shield restricted the swath width to 3.1 times the normal swath. Spray deposit from an unshielded lance, within the normal swath decreased to as low as 45%, due to wind effects. However, use of the conventional, and the improved shields enhanced the spray deposit to 54.2% and 68%, respectively. The improved drift shield improved the spray pattern displacement (SPD) significantly (P<0.05) compared with the conventional shield and the unshielded lance when the wind speed exceeded 1.25 m/s. The improved shield decreased the off target drift by as much as 63% compared with the unshielded spray. It also decreased the quantity of pesticide deposit on the operator's body by 41–84% and thereby reduced exposure and improved safety.     

The Effects of Precipitation on Aquatic and Terrestrial Ecosystems: A Proposed Precipitation Chemistry Network

Precipitation is one of the most important factors determining the nature and productivity of terrestrial and aquatic ecosystems. Detailed historical and contemporary records are available indicating the amount of water deposited at thousands of locations throughout the world. Comparatively, however, knowledge of the changing chemistry of precipitation has developed only recently and is still very fragmentary. Our present ignorance of the total impact of changes in precipitation quality on the productivity and stability of ecosystems is especially profound. This paper has a fourfold purpose: (1) to describe the myriad of trace chemical constituents transferred from the atmosphere into the biosphere of the earth; (2) to define the range of beneficial and injurious ecological effects of perturbations in atmospheric deposition; (3) to explain the concepts of sensitive areas, life stages, and life forms; and (4) to describe briefly plans for a National Deposition Network and associated research on the terrestrial and aquatic ecosystems of the United States.     

Sulfur Concentrations in Plant Foliage and Related Effects

Sulfur Is an essential element for plants and is normally taken up from soil In the sulfate form. S0₂ absorbed from the air also can supply S for plant nutrition. Plants are therefore dependent on an optimum S content, but deficiencies or excesses can result in deleterious effects. The Phytotoxicology Section has conducted numerous assessment surveys in rural, urban, or industrial locations in Ontario to determine the concentrations of S in plants and related effects. During the ten year period, 1968 to 1977, about 50,000 samples of vegetation and soil were collected and analyzed for S concentrations. The results of these analyses were examined with respect to natural background concentrations of S in foliage of 33 different species, and effects observed on plant life associated with excess concentrations of S. For example, in one situation 0.35% sulfur in foliage of trembling aspen trees was found to be the threshold level for injury to occur. Some of the industries surveyed for the degree and extent of S effects in their vicinity included pulp mills, power plants, iron concentrators, and gold, nickel, and copper smelters. In interpreting the results of S analyses in plant foliage for diagnostic purposes, consideration should be given also to the geographical location, the stage of growth of the plant, the relation of visible injuries to pollutant or biological causes, the S content of the soil, and S0₂ emission data for the area.