高铁酸钾与O3对有机磷农药的去除效力对比及应用前景

本文介绍了臭氧/高铁酸钾技术降解有机磷农药的基本化学机理以及在国内外的研究现状,从五个方面对比了臭氧和高铁酸钾去除有机磷农药的的优劣性,分析了今后有机磷农药降解的研究方向。     

基于OGP数据的点火概率在保护层分析中的研究与应用

保护层分析(LOPA)是一种数量级层面上的半定量风险评估方法,它通常以定性风险评估为基础,以相对定量风险分析更短的时间及更少的资源为特点而得到广泛应用.在利用LOPA进行风险分析时,需要确定各类场景修正因子,其中点火概率由于影响因素多、现有确定方法较为粗糙,导致较高的不确定性,使得LOPA分析结果的一致性难以保证.根据OGP提供的经验数据,对不同泄漏速率下的点火概率进行数据的完善与补充,得出简化后的点火概率计算模型,在确保点火概率相对准确的同时简化点火概率的计算方法,为LOPA中点火概率的取值提供了依据.同时采用显著性检验的分析方法研究了不同泄漏特征对于点火概率的影响,为LOPA分析中保护层的选取与设计提供了建议.     

Nest site selection in the open-nesting honeybee Apis florea

We studied nest site selection by swarms of the red dwarf honeybee, Apis florea. By video recording and decoding all dances of four swarms, we were able to determine the direction and distances indicated by 1,239 dances performed by the bees. The bees also performed a total of 715 nondirectional dances; dances that were so brief that no directional information could be extracted. Even though dances converged over time to a smaller number of areas, in none of the swarms did dances converge to one site. As a result, even prior to lift off, bees performed dances indicating nest sites in several different directions. Two of four swarms traveled directly in what seemed to be the general direction indicated by the majority of dances in the half hour prior to swarm lift off. The other two traveled along circuitous routes in the general direction indicated by the dances. We suggest that nest site selection in A. florea has similar elements to nest site selection in the better-studied Apis mellifera. However, the observation that many more locations are indicated by dances prior to lift off also shows that there are fundamental differences between the two species.     

中国域际关键自然资本竞争效应的测算与分析

以生产生态足迹核算法为基础,引入关键自然资本概念,计算全国32个地区1949至2007年的3类自然资源的本区域生态足迹,即生产性土地、水资本及能源足迹,核算时将水产品、淡水及水电统一在水足迹项下,并对生产性土地和能源足迹的核算口径作相应调整。在此基础上,继而测算关键自然资本竞争效应,从全局及个案2个角度分析区域发展战略对区域关键自然资本竞争效应的影响。这里关键自然资本竞争效应是对区域自然资本禀赋开采活动的抽象,描述战略期内某区域自然资本开采量调整幅度较同期平均水平的相对情况。全局分析,即比较东、中、西部地区1949至1979年非倾向性区域战略、1980至1997年东部倾向性战略和1998至2007年中、西部倾向性战略期的关键自然资本竞争效应,结果显示：关键自然资本竞争效应的调整方向与区域战略倾斜方向相同,第一次调整为东部倾斜,对应着东部境内关键自然资本竞争效应的上升,第二次调整为中、西部倾斜政策,对应着中、西部境内关键自然资本的上升。南水北调工程作为个案分析,补充论述资源再配置工程对关键自然资本竞争效应的影响,通过比较南水北调东、中线相关区域关键自然资本变动情况发现：水源区自然资本生产力下降;不可持续开采方式的负外部性有从＂点＂向工程沿线扩展的可能。     

The formation of a new horseradish peroxidase binding rare earth

The charge distribution, the isolation, purification, and characterization of horseradish peroxidase (HRP) were investigated. A new HRP protein binding La (La-HRP) was found for the first time in vivo. The molecular weight of the La-HRP protein is about 43,833 Da. The activity index (Rz) of the La-HRP protein (Rz = 2.4) is lower than that of HRP (Rz = 3.1). The La-HRP protein is absorbed in the plasma membrane of the plant and animal, leading to the change in the function of the cell membrane. Therefore, the La-HRP protein is harmful to living organisms.     

Characterization, dissolution and solubility of synthetic svabite [Ca5(AsO4)3F] at 25�C45��C

Svabite is a secondary arsenate mineral, calcium fluoride arsenate [Ca₅(AsO₄)₃F], in the apatite group of phosphates. Its dissolution and subsequent release of aqueous species play an important role in the cycling of arsenic and fluoride in the environment, but the thermodynamic and kinetic properties of svabite dissolution have never been investigated. In the present study, svabite was prepared by precipitation and characterized by various techniques, and then dissolution of synthetic svabite was studied at 25, 35 and 45°C in a series of batch experiments. In addition, the aqueous concentrations from the batch dissolution were used to calculate the solubility product and free energy of formation of svabite. The results of the X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy analyses indicated that the synthetic, microcrystalline svabite with apatite structure used in the experiments has not changed after dissolution. For the dissolution of svabite [Ca₅(AsO₄)₃F] in ultrapure water, F⁻ ions were initially found to dissolve preferentially when compared with calcium and arsenate. Preferential dissolution of arsenate when compared with that of calcium was also observed. Dissolution of svabite in aqueous medium appeared to be always non-stoichiometric at the beginning, but when a dissolution equilibrium or steady state was reached at 25 and 35°C, the solid dissolved almost stoichiometrically. The release of calcium, arsenic and fluoride to solution increased with decreasing temperature. The mean K _sp value was calculated for Ca₅(AsO₄)₃F of 10^−39.21 (10^−39.18 ~ 10^−39.24) at 25°C; the free energy of formation ΔG _f ^o [Ca₅(AsO₄)₃F] was −5210.46 kJ/mol.     

Application of continuous time random walk theory to nonequilibrium transport in soil

Continuous time random walk (CTRW) formulations have been demonstrated to provide a general and effective approach that quantifies the behavior of solute transport in heterogeneous media in field, laboratory, and numerical experiments. In this paper we first apply the CTRW approach to describe the sorbing solute transport in soils under chemical (or) and physical nonequilibrium conditions by curve-fitting. Results show that the theoretical solutions are in a good agreement with the experimental measurements. In case that CTRW parameters cannot be determined directly or easily, an alternative method is then proposed for estimating such parameters independently of the breakthrough curve data to be simulated. We conduct numerical experiments with artificial data sets generated by the HYDRUS-1D model for a wide range of pore water velocities (υ) and retardation factors (R) to investigate the relationship between CTRW parameters for a sorbing solute and these two quantities (υ, R) that can be directly measured in independent experiments. A series of best-fitting regression equations are then developed from the artificial data sets, which can be easily used as an estimation or prediction model to assess the transport of sorbing solutes under steady flow conditions through soil. Several literature data sets of pesticides are used to validate these relationships. The results show reasonable performance in most cases, thus indicating that our method could provide an alternative way to effectively predict sorbing solute transport in soils. While the regression relationships presented are obtained under certain flow and sorption conditions, the methodology of our study is general and may be extended to predict solute transport in soils under different flow and sorption conditions.     

影响灾后恢复期的因素分析——基于水灾灾民的调查

恢复力作为减灾建设的重要环节,探讨其影响因素,有助于提升承灾体适应变化及异常的能力.以恢复期为恢复性的刻画指标,通过问卷调查了539例灾民的水灾恢复期的主观识觉,运用列联表分析灾民受灾经历、个体属性与恢复期长短的关系.结果表明:灾后精神恢复期为5个月,物质恢复期约7.4个月;灾时心理越镇静精神恢复期越短,灾害损失越严重物质恢复期越长,而灾后救援没有发挥出明显改变恢复期的作用;个体属性中的家庭结构、受教育水平、收入水平等与恢复期没有明显相关.因此,拓展灾民可获救援渠道及能力,开展保险,有助于提升恢复力.     

中孔硅胶负载过氧乙酸深度脱除柴油硫化物

采用滴定吸附法将过氧乙酸组装于中孔硅胶中,通过红外光谱分析和N2吸附法对组装体进行了表征,研究了常温常压下,该组装体氧化、吸附、脱除柴油硫化物的活性.结果表明,该组装体具有优良的脱硫性能.柴油中硫化物与过氧乙酸在硅胶孔中发生氧化反应,氧化产物被吸附在硅胶上,使柴油的含硫量从1697μg/g降到14μg/g,符合美国环境保护署标准.     

多因子影响下铜的水质基准及生态风险

为探究特定水环境中多因子影响下的铜水质基准及生态风险,采用物种权重敏感度分布法、水效应比法和生物配体模型推导保护太湖水生生物铜的水质基准.根据推导结果,推荐采用最大浓度基准值(CMC)1.43 μg/L和持续浓度基准值(CCC)1.33 μg/L.结合水效应比法和生物配体模型,采用联合概率法评估太湖铜的生态风险.结果表明,两种方法下丰水期5%水生生物受到铜慢性毒性影响的概率分别为23.43%和39.43%,而未考虑多因子影响的风险概率为85.01%,高估了太湖铜生态风险.可见,水环境多因子对水质基准和生态风险的影响不容忽视,我国目前使用的铜标准可能无法保护特定区域的水生生物.考虑多因子影响可提高基准值推导和风险评估的科学性,避免"过保护"和"欠保护"现象.