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201.
The composition of drilling muds is based on a mixture of clays and additives in a base fluid. There are three generic categories of base fluid - water, oil, and synthetic. Water-based fluids (WBFs) are relatively environmentally benign, but drilling performance is better with oil-based fluids (OBFs). The oil and gas industry developed synthetic-based fluids (SBFs), such as vegetable esters, olefins, ethers, and others, which provide drilling performance comparable to OBFs, but with lower environmental and occupational health effects. The primary objective of this paper is to present a methodology to guide decision-making in the selection and evaluation of three generic types of drilling fluids using a risk-based analytic hierarchy process (AHP). In this paper a comparison of drilling fluids is made considering various activities involved in the life cycle of drilling fluids.This paper evaluates OBFs, WBFs, and SBFs based on four major impacts—operations, resources, economics, and liabilities. Four major activities—drilling, discharging offshore, loading and transporting, and disposing onshore—cause the operational impacts. Each activity involves risks related to occupational injuries (safety), general public health, environmental impact, and energy use. A multicriteria analysis strategy was used for the selection and evaluation of drilling fluids using a risk-based AHP. A four-level hierarchical structure is developed to determine the final relative scores, and the SBFs are found to be the best option.  相似文献   
202.
The regulation of the emissions of 'traditional' primary air pollutants (fluorides, sulfur dioxide) has changed the pattern of exposure of ecological systems, with greatly reduced exposure close to sources, but with a smaller effect in some remote areas. Measurements show that recovery is occurring at some sites, in fresh water chemistry (reduced acidity) and in sensitive biota (sustainable fish populations). However, the pattern of change in exposure has not always been simply related to emission reductions. An understanding of responses to recent changes will improve our predictions of the response to future emission changes, both locally and globally. As exposure to 'traditional' pollutants is reduced, the potential for other pollutants to have effects becomes more evident. In the aqueous phase, we need to understand the role of soluble and suspended organics, but this also means explicit recognition of the possibility of phase exchange, and the role of photolytic reactions on plant, soil, and water surfaces. Do highly reactive free radicals in the atmosphere, formed by the action of sunlight on volatile organic compounds, have direct effects on plants? Organic compounds and heavy metals may be bioactive as gases and particles, but for many potentially toxic compounds, the experimental evidence for biotic response is very limited. To evaluate the potential effects of pollutants, we need to understand the pathways by which airborne pollutants enter and react within ecosystems. For vegetation, we have to consider bidirectional fluxes, and distinguish among uptake through stomata, through leaf surfaces, or through roots. There are several challenges for the future. (1) Can we devise experiments that permit exposure of vegetation to gases, particles, and/or aqueous pollutants at 'realistic' concentrations? (2) Can we include the potential interactions with photolytically derived free radicals, and the dynamics of exchange? (3) How do we allow for responses to pollutant mixtures, or the simultaneous exposure to pollutants in gas, particle, and aqueous phases? The recognition of the importance of the dynamic exchange of pollutants between phases will be the key to the development of effective experimental approaches to evaluating cause-effect relationships between pollutant mixtures and ecosystem responses.  相似文献   
203.
ABSTRACT: Rainfall simulator studies were conducted during 1982 and 1983 on agricultural and native rangeland soils of the same soil series in northern Utah. Results indicate that the same soil series mapped at different locations on agricultural land will have similar 10, 20, and 30 minute infiltration rates and similar interrill erosion rates. Seasonal differences in infiltration and erosion rates were significant. Comparisons between agricultural and native soils were complicated by three-way statistical interactions. Seasonal variations in both infiltration rates and erosion rates were greatest on agricultural soils. Of four soil series on native rangeland, only one showed significant seasonal variation in infiltration rates, while erosion rates were similar across all seasons for all soil series. Soil and cover factors important in predicting infiltration and erosion were identified.  相似文献   
204.
ABSTRACT: Least squares regression and ARIMA models were developed from suspended sediment data for the Ausable River, Southern Ontario, Canada. A poor correlation between discharge and suspended sediment concentration results from the dynamics of the physical system, including seasonality, antecedent conditions, and hysteresis. Regression model results were significantly improved by the division of the data set into seasons and the addition of simple. but physically meaningful variables. Misleading improvements obtained from the regression of sediment load and discharge are discussed. ARIMA models provided accurate forecasts of sediment concentration on a real-time basis, but the rigorous data requirements limit their use in modeling suspended sediment concentrations in Canadian rivers.  相似文献   
205.
The solution with the aid of the hybrid computer of the partial and total differential equations for an integrated surface water groundwater system is described. A versatile computing technique has been developed to make a rapid and accurate study of the groundwater response due to varying inputs (deep percolation) or outputs (evapotranspiration) from the groundwater system. Spatial variations in basic vegetation phenomena, such as pattern, and hydrological parameters, are represented by means of a grid network which also allows the input of variable boundary conditions. The model is applied to an area in Columbia, South America which is subject to high water-table conditions. Various reclamation schemes and management practices under conditions of irrigated agriculture are assessed.  相似文献   
206.
OBJECTIVES: Older drivers are overinvolved in intersection crashes compared with younger drivers, but the reasons are not clearly understood. The purpose of the present study was to identify the factors that lead to older drivers' intersection crashes. METHOD: Study participants were composed of two groups of older drivers -- ages 70-79 (n = 78) and 80 and older (n = 76) -- and a comparison group of drivers ages 35-54 (n = 73); all were at fault in intersection crashes involving nonfatal injuries. Police crash reports, telephone interviews with at-fault drivers, and photographs of intersections were used to determine the kinds of driver actions and errors that led to the intersection crashes. RESULTS: Drivers 80 and older had fewer rear-end crashes than drivers ages 35-54 and 70-79, and both groups of older drivers had fewer ran-off-road crashes than drivers ages 35-54. Crashes where drivers failed to yield the right-of-way increased with age and occurred mostly at stop sign-controlled intersections, generally when drivers were turning left. The reasons for failure-to-yield crashes tended to vary by age. Compared with drivers ages 35-54 and 80 and older, drivers ages 70-79 made more evaluation errors -- seeing another vehicle but misjudging whether there was adequate time to proceed. In contrast, drivers 80 and older predominantly failed to see or detect the other vehicle. Drivers ages 35-54 also tended to make search errors, but theirs were due more often to distraction. CONCLUSIONS: Factors leading to intersection crashes vary with age, even between two age groups of older drivers. Because the number of older drivers is projected to increase, it is important to identify ways to reduce the frequency and severity of their intersection crashes. Roundabouts and protected left turn lanes at signalized intersections may help to reduce failure-to-yield crashes at intersections, especially among older drivers. Crash avoidance systems may help to reduce crashes for drivers of all ages, but most systems have not been thoroughly investigated using real-world crash data.  相似文献   
207.
There is substantial uncertainty regarding baseline greenhouse gas (GHG) emissions forecasts—i.e., how GHG emissions will grow over time in the absence of policy intervention. Thus baseline uncertainty should be a key consideration in setting GHG emissions targets as a mitigation strategy to respond to global climate change. At a minimum, the emissions target must be less than the baseline level to induce changing behavior and new investment. Despite this fundamental policy criterion, baseline considerations have played only a minor role in target setting under international climate policy. Baseline uncertainty applies to both absolute and intensity based emissions targets. It is demonstrated that one advantage of intensity targets is reduced uncertainty in the projected baseline, however there will always be some residual uncertainty in model projections. To illustrate the importance of considering baseline uncertainty in GHG target setting, the Bush Climate Change Initiative is analyzed against its projected baseline as a case study of a modest intensity target. Based on comparison with historical data, the range of projections by major energy-economic models, past discrepancies in the accuracy of model projections and the added complexity of sector-specific drivers for non-CO2 GHGs, it is shown that the Bush Initiative cannot be guaranteed or even expected to deliver actual reductions against an uncertain baseline. This finding emphasizes the importance of setting a target that accounts for baseline uncertainty to achieve genuine mitigation of GHG emissions.
Neil StrachanEmail:
  相似文献   
208.
This study investigated a person–climate fit model in order to explain the effect of organizational politics on work attitudes. A unique index of compatibility was developed based on the congruence between preferences for political influence processes and those processes perceived to be prevalent in the employment context. A survey of 138 non academic employees of a large public university, representing a variety of jobs, demonstrated that political influence compatibility was clearly related to a wide range of work attitudes (e.g. satisfaction with co-workers, trust in management, evaluation of self). Directions for future research investigating PIC and potential applications of political influence compatibility in human resource management are discussed. © 1997 John Wiley & Sons, Ltd.  相似文献   
209.
Antarctic lakes with simple plankton ecosystems are believed to be sensitive biological indicators of climate change. Models of the physical environment, in particular the ice layer, support understanding of how the ecosystems respond to meteorological variables. This paper describes how data from a previously reported automatic measuring probe and meteorological data from Davis station were used to develop a detailed thermodynamic model of the ice layer on Crooked Lake, one of the largest and deepest freshwater lakes in Antarctica. The general model structure is similar to a previously reported model of sea ice but with modifications specific to the Antarctic freshwater lake case informed by the data. The model inputs are atmospheric variables as well as water temperature, ice albedo and the radiation extinction coefficient for the ice. Heat and radiation fluxes at the ice–air and ice–water boundaries are calculated using equations chosen for their suitability for the Antarctic. In the case of shortwave radiation, equations were fitted to data from the automatic probe. Using the heat fluxes to establish boundary conditions, and incorporating the known thermodynamic properties of ice, the temperature profile within the ice and the resulting growth and melt of the ice can be calculated. The model uses a largely mechanistic approach, with most equations taken from established thermodynamic theories or empirical studies and only one adjustable parameter related to the sensible heat flux from the water, which is not easily calculated from the available data. It was found to accurately reproduce ice temperature and ice thickness data for the year 2003, with r2 = 0.89, n = 2005. Finally, the model was simplified to run with air temperature as the only input variable and was shown to perform well—this suggests that freshwater lake ice is affected more by air temperature than any other variable, and is therefore a useful indicator of climate change in its own right.  相似文献   
210.
The RE-AIM framework, created by Russell Glasgow and colleagues, addresses five major factors involved with sustained population-level effectiveness of public health interventions—Reach, Efficacy and/or Effectiveness, Adoption, Implementation and Maintenance. In this article, I illustrate how the framework might be applied to environmental communication interventions, and discuss how the framework needs to be adapted to important aspects of this context. Following that, I address several potential criticisms of RE-AIM or its usefulness for environmental communication scholars. Finally, I discuss how research practices of environmental communication scholars could be changed in light of the insights given by the RE-AIM framework. Much work remains to be done in order to see exactly how RE-AIM, or other frameworks focused on large-scale intervention effectiveness, can be made most useful to environmental communication scholars. However, RE-AIM already provides a valuable way to start thinking about how to best improve large-scale effectiveness of communication interventions.  相似文献   
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