Decolouring mechanism of Zhejiang diatomite. Application to printing and dyeing wastewater

We report the adsorption isotherm of methylene blue on the surface of Zhejiang and Jilin diatomite. The relationship between the adsorption isotherm and diatomite pore structure is discussed. The degree of decolouring was found to be strongly related to pH and isoelectrical value. Furnace ash residue and diatomite were found to be very effectively treating printing and dyeing wastewater.     

Size fractionation of organic matter and heavy metals in raw and treated leachate

This study characterized the organic matter and heavy metals in the leachate from two typical municipal solid waste (MSW) sanitary landfills in China, the recently established (3-year-old) Liulitun landfill and the mature (11-year-old) Beishenshu landfill, using a size fractionation procedure. The organic matter of all raw and treated leachate samples primarily existed in a truly-dissolved fraction with an apparent molecular weight (AMW) of <1 kDa, and its percentage decreased with an increase in overall AMW. The leachate from the newer landfill had a higher percentage of truly-dissolved organic matter. After anaerobic treatment, this leachate had a similar size fraction of organic matter to that seen for the raw leachate of the mature landfill. Biochemical processes had different removal efficiencies for various types of AMW organic matter, and the concentration of moderate AMW organic matter appeared to increase throughout these processes. Most of the heavy metals existed in a colloidal fraction (AMW >1 kDa and particle size <0.45 μm). The behaviors of different species of heavy metals had large variations. The size fractions of heavy metal species were significantly affected by treatment processes and landfill age, except for Zn. The concentration ratio of heavy metals to organic matter was maximal in the colloidal fraction and showed an inverse change to that seen for organic matter concentration changes caused by biochemical processes. Consequently, the pollution levels of heavy metals were substantially increased by treatment processes, although their concentrations decreased.     

Comparison among filter-based,impactor-based and continuous techniques for measuring atmospheric fine sulfate and nitrate

Filter-based methods for sampling aerosols are subject to great uncertainty if the gas–particle interactions on filter substrates are not properly handled. Sampling artifacts depend on both meteorological conditions and the chemical mix of the atmosphere. Despite numerous of studies on the subject, very few have evaluated filter-based methods in the Asian environments. This paper reports the results of a comparison of the performances of two filter-based samplers, including a Thermo Anderson Chemical Speciation Monitor (RAAS) and a honeycomb denuder filter-pack system, a Micro Orifice Uniform Deposit Impactor (MOUDI) and a real-time ambient ion monitor (AIM, URG9000B) in measuring atmospheric concentrations of PM_2.5 sulfate and nitrate. Field studies were conducted at an urban site in Jinan, Shandong province, during the winter of 2007 and at a rural site near Beijing in the summer of 2008. The AIM was first compared with the honeycomb denuder filter-pack system which was considered to have minimal sampling artifacts. After some modifications made to it, the AIM showed good performance for both sulfate and nitrate measurement at the two sites and was then used to evaluate other instruments. For the un-denuded RAAS, the extent of sampling artifacts for nitrate on quartz filters was negligible, while that on Teflon filters was also minimal at high nitrate concentrations (>10 μgm^?3); however, loss through evaporation was significant (～75%) at low nitrate concentrations under hot summer conditions. The MOUDI using aluminum substrates suffered a significant loss of nitrate (50–70%) under summer conditions due to evaporation. Considering that the aluminum substrates are still being widely used to obtain size-resolved aerosol compositions because of their low cost and accurate mass weighed, caution should be taken about the potential significant under determination of semi-volatile components such as ammonium nitrate.     

Atmospheric emission of polychlorinated biphenyls from multiple industrial thermal processes

In this study, field measurements were conducted to estimate and characterize the atmospheric emission levels and profiles of polychlorinated biphenyls (PCBs) from multiple industrial thermal processes. The emission levels and profiles of PCBs from five types of thermal processes at twenty-three plants were studied and compared with eight processes reported in our previous studies. Correlation analysis was preformed to identify a marker congener for emission of ΣPCB. A significant correlation was observed between congener CB-118 and ΣPCB (R² = 0.65 and p < 0.01), which suggests that CB-118 is a good marker congener for emission of ΣPCB. The profiles of PCBs emitted from the thirteen thermal processes were compared, and this information could be used for studying source–receptor relationships and identifying the specific sources of PCBs. To prioritize the sources for control, the concentrations of PCBs from thirteen industrial thermal sources were compared. The PCB concentrations from secondary zinc smelting and thermal wire reclamation were about one to three order magnitude higher than those of other sources, which suggests that these two sources be given priority in PCB source control. Finally, the atmospheric emission factors of PCBs from the thirteen industrial sources were summarized, and these data will be useful for developing an integrated emission inventory of PCBs.     

An inexact-stochastic with recourse model for developing regional economic-ecological sustainability under uncertainty

Effective planning of resources management is important for facilitating socio-economic development and eco-environmental sustainability. Such a planning effort is complicated with a variety of uncertain, dynamic and nonlinear factors as well as their interactions. In this study, an inexact-stochastic quadratic programming with recourse (ISQP-R) method is developed for reflecting dynamics of system uncertainties based on a complete set of scenarios as well as tackling nonlinearities in the objective function to reflect the effects of marginal utility on system benefits and costs. Moreover, since penalties are exercised with recourse against any infeasibility, the ISQP-R can support the analysis of various policy scenarios that are associated with different levels of economic consequences when the promised targets are violated. The developed method is applied to a case study of planning resources management and developing regional ecological sustainability. The results have been generated and are helpful for decision makers in not only identifying desired resources-allocation strategies but also gaining insight into the tradeoff between economic objective and eco-environment violation risk.     

高水分蔬菜和花卉废物序批式进料联合堆肥的中试

以滇池流域典型蔬菜废物(西芹、白菜)和花卉废物(石竹)为原料,进行了序批式联合堆肥的试验研究.以西芹和石竹作为初始物料,控制初始混合物料的含水率在60%～70%,每隔4d添加一次白菜;采用温度反馈通气量控制的好氧静态堆肥技术,在堆体温度40℃左右时停止通风.试验分析了堆肥过程中堆体温度、通风速率、水分、pH值、有机质、灰分、体积、NH₄⁺-N,NO₃^--N等指标随时间的变化特征.结果表明:采用序批式进料、温度反馈通气量控制的静态好氧堆肥技术进行蔬菜和花卉废物联合堆肥可以有效控制堆肥过程,实现有机物料的快速稳定和去除水分,解决了滇池流域蔬菜废物量远大于花卉废物量时堆肥难以有效进行的技术难题.     

Seasonal dynamics of labile soil nitrogen from four plantations at the western edge of the Sichuan Basin北大核心CSCD

The objective of this study was to investigate the soil nitrogen components of four native artificial plantations at the western edge of the Sichuan Basin. Soil samples from two layers (0-20 cm and 20-40 cm) were collected from 4 plantations (Cryptomeria fortunei, Michelia wilsonii, Phoebe zhennan, and Quercus acutissima) during March, June, September, and December 2015 at the western edge of Sichuan Basin, to perform a comparative analysis on seasonal dynamics. Soil ammonium, nitrate, microbial biomass nitrogen, and environmental factors were synchronously monitored. The results showed that soil inorganic nitrogen was mainly the result of nitrate. The components of labile soil nitrogen showed significant seasonal dynamics. Soil ammonium during the growing season (June and September) was higher than that during the non-growing season (March and December), but soil nitrate, microbial biomass nitrogen, and inorganic nitrogen showed the opposite pattern. Labile nitrogen components in the 0-20 cm layer were generally higher than those in the 20-40 cm layer. Labile soil nitrogen was significantly affected by forest type, which was dependent on season and soil layer. In general, there were significant correlations between the soil nitrogen pools and labile soil nitrogen and the environmental factors, including soil temperature, water content, and monthly rainfall. In conclusion, the variation of labile soil nitrogen was influenced more by season than forest type or soil layer. Compared to the biological effects of tree species, the environmental factors had a stronger effect on labile soil nitrogen. © 2018 Science Press. All rights reserved.