Behavior of endocrine-disrupting chemicals in leachate from MSW landfill sites in Japan

Endocrine-disrupting chemicals (EDCs) in landfill leachates and the effluent from leachate treatment facilities have been analyzed by many researchers. However, seasonal and yearly variations and the influence of landfill age are still not clear. In this study, leachate was sampled on four occasions each, at different seasons, from two MSW landfills which receive different waste material. Then, the quantities of alkylphenols (APs), bisphenol A (BPA), phthalic acid esters (PAEs) and organotin compounds (OTs) in leachate were determined. By sampling leachate from landfill cells of different age, the long-term behavior of EDCs was studied. Furthermore, leachate was also sampled at different points in the process of a leachate treatment system, and then the behavior of EDCs in the facility was studied. The concentrations of APs were as low as in surface waters, and OTs were not detected (detection limit was 0.01 microg/l), while BPA and DEHP, which were the most abundant of the four substances measured as PAEs, were found in all the leachates that were measured. Concentrations of BPA and DEHP were almost constant regardless of season, except for a couple of low concentrations observed for BPA. The varying composition of landfilled waste did not influence BPA and DEHP in leachate. Concentration of BPA in raw leachate tends to decrease as the years go by, but the concentration of DEHP was observed to remain at a constant level. BPA was considerably degraded by aeration for leachates from the two landfills, except when the leachate temperature was low. Aeration, coagulation/sedimentation, and biological treatment could not remove DEHP.     

Recent trends in recycling activities and waste management in Japan

Japan's basic approach to municipal solid waste (MSW) is (1) waste reduction, (2) promotion of recycling, (3) volume reduction by intermediate treatment, and (4) environmentally sound final disposal. A brief history of legislative trends in waste management is given as background for current waste management and recycling activities. The material recovery rate for MSW collected by local municipalities was only 5.6% in 1996. More than half of MSW, on a volume basis, consists of containers and packages, while great amounts of landfill space are also taken up by bulky wastes such as electric appliances. Therefore, in order to promote recycling and decrease landfill waste, Japan is targeting containers, packages, and electric appliances. A law promoting separate collection and recycling of containers and packages (Packaging Waste Recycling Law) and a law requiring the recycling of specific home electric appliances into new products (Home Electric Appliance Recycling Law) were introduced in June 1995 and June 1998, respectively. These laws are in line with the OECD policy Extended Producer Responsibility (EPR). Received: September 16, 1998 / Accepted: March 10, 1999     

Resolving public conflict in site selection process-a risk communication approach

In Japan, conflicts regarding the siting of waste disposal facilities occur frequently. In particular, siting of incinerators and landfills has become increasingly difficult because the public is highly concerned about the dioxin issues. Inefficient siting of waste disposal facilities causes several social problems, such as the shortage of waste treatment and disposal facilities, the rising of waste management costs and an increase in the consumption of resources. While dealing with a similar situation, the Chemical Society of Japan adopted a risk communication technique successfully. Hence, the pragmatic use of a risk communication technique is proposed to avoid conflicts and for a smooth information exchange to seek cooperation in waste management. In order to achieve this, a study was conducted to resolve conflicts between residents and the municipality for the selection of site for a solid waste treatment and disposal facility. This study aims to discuss the subject of risk communication for the waste disposal system in Japan. This study is performed through personal interviews and a questionnaire covering opposing parties in the town. As a result of the survey, a risk communication approach for a waste treatment and disposal system is presented in the paper addressing issues such as building of social trust, pragmatic use of the communication process, installation of credible information sources, and environmental education and awareness.     

Research on leachate recirculation from different types of landfills

Landfills can produce a great amount of leachate containing highly concentrated organic matter. This is especially true for the initial leachate from landfilled municipal solid wastes (MSW) that generally has concentrations of COD(Cr) and BOD(5) up to 80,000 and 50,000mg/L, respectively. The leachate could be disposed by means of recirculating technique, which decomposes the organics through the action of proliferating microorganisms and thereby purifies the leachate, and simultaneously accelerates organic decomposition through water saturation control. Data from experimental results indicated that leachate recirculating could reduce the organic concentration considerably, with a maximum reduction rate of COD(Cr) over 95%; and, using a semi-aerobic process, NH(3)-N concentration of treated leachate could be under 10mg/L. In addition, the organic concentration in MSW decreased greatly.     

Pesticide residues in soils, sediments, and vegetables in the Red River Delta, northern Vietnam

This study assessed pesticide residues in soils, sediments, and vegetables in the Xuan Khe and Hop Ly communes located along the Chau Giang River in the Red River Delta, northern Vietnam. Samples were collected from agricultural areas within and outside of embankments built to prevent flooding. In Xuan Khe, the soils outside of the embankment were more clayey with higher organic matter contents compared with the inside, due to selective deposition during river flooding. Many of the soils contained significant amounts of pesticides including dichlorodiphenyltrichloroethane (DDT), dicofol, isoprothiolane, and metalaxyl although their levels were below the maximum allowable concentration set by the Vietnamese government. The spectrum of DDT derivatives found suggested that the source of DDTs was not contaminated dicofol. Soils in Hop Ly resembled soils in Xuan Khe but were relatively sandy; one field showed appreciable contents of DDT derivatives. The ratios of (p,p ^′-dichlorodiphenyldichloroethylene + p,p ^′-dichlorodiphenyldichloroethane)/∑DDT in the surface and subsurface soils in Hop Ly were 0.34 and 0.57, suggesting that the DDTs originated from recent application. Pesticide residues in soils were not likely to translocate into vegetable crops, except for metalaxyl. High concentrations of cypermethrins in kohlrabi leaves could be ascribed to foliar deposition.     

Impact of phosphorus load reduction on water quality in a stratified reservoir-eutrophication modeling study

Monitoring data collected from the Mingder Reservoir in Taiwan indicate that the water quality is between mesotrophic and eutrophic. Chlorophyll a concentration is higher in the summer and anoxic conditions occur in the bottom. The data also reveal that a pronounced vertical thermal gradient in summer and vertical mixing the end of fall. A vertical two-dimensional, laterally averaged hydrodynamic and water quality model (CE-QUAL-W2) was adopted to simulate the water surface elevation, water temperature, and water quality conditions in the water column. The modeling effort was supported with monitoring data collected in the field for a 2-year period in the reservoir. The hydrodynamic model reproduced the time series water surface elevation. Spatial and temporal distributions of temperature in the water column of the reservoir were also well reproduced by the hydrodynamic model. Model-calculated concentrations of key water quality constituents such as nutrients, dissolved oxygen, and algal biomass matched the measured values closely in the reservoir. The calibrated model was then applied to simulate water quality response to various nutrient reduction scenarios. Results of the model scenario runs reveal that a 20% and 80% reduction of the phosphorus loads will improve the water quality from eutrophic to mesotrophic and oligotrophic conditions, respectively. The modeling effort has yielded valuable information that can be used by decision makers for the evaluation of different management strategies of reducing watershed nutrient loads.     

EDTA及其回收溶液治理重金属污染土壤的研究

试验结果表明,EDTA能够有效地萃取土壤重金属,由于其价格较贵和不易被降解等特点,限制了它的广泛运用.在运用MINTEQA2模型对萃取液中重金属离子形态分析的基础上,选用Na2S沉淀法将重金属从EDTA萃取液中有效分离.同时将回收的EDTA连续进行萃取土壤重金属,由于回收EDTA浓度下降的原因,其效果比新鲜EDTA的要稍微差一点,但从经济和效率上来说,仍旧可以用来治理重金属污染的土壤.     

Mathematical equivalence of geometric mean fitness with probabilistic optimization under environmental uncertainty

Natural selection can be considered as optimising fitness. Because ‘mean’ fitness is maximized with respect to the genotypes of carriers, traditional theory can be viewed as a statistical theory of natural selection. Probabilistic optimisation is a way to incorporate such uncertainty into optimality analyses of natural selection, where environmental uncertainty is expressed as a probability distribution. Its canonical form is a weighted average of fitness with respect to a given probabilistic distribution. This concept should be applicable to three different levels of uncertainty: (1) behavioural variations of an individual, (2) individual variations within a generation, and (3) temporal change over generations (geometric mean fitness). The former two levels are straightforward with many empirical evidences, but the last category, the geometric mean fitness, has not well understood. Here we studied the geometric mean fitness by taking its logarithm, where the log growth rates become the fitness value. By further transforming the log growth rates, the fitness of log growth rates becomes its linear function. Therefore, a simple average of these distributions becomes the fitness measure across generations and consideration of variance discount or the entire probability distributions becomes unnecessary. We discuss some characteristic features of probabilistic optimization in general. Our view is considered a probabilistic view of natural selection, in contrast with the traditional statistical view of natural selection.     

Effect of natural and synthetic organic-Fe(III) complexes in an estuarine mixing model on iron uptake and growth of a coastal marine diatom, Chaetoceros sociale

Cell growth of a coastal marine diatom, Chaetoceros sociale, in the presence of different premixed organic-Fe(III) complexes [EDTA-Fe(III) (100:1 and 2:1), citric-Fe(III) (100:1) and fulvic-Fe(III) (0.1, 0.2 and 1 ppm C)] and solid amorphous hydrous ferric oxide [am-Fe(III) or Fe(III) hydroxide] were experimentally measured in culture experiments at 10 °C under 3000 lux fluorescent light. Fulvic-Fe(III) (0.1 and 0.2 ppm C) and citric-Fe(III) (100:1) induced maximal cell yields of C. sociale. The order of cell yields was: fulvic-Fe(III) (0.1 and 0.2 ppm C) ≥ citric-Fe(III) (100:1) > EDTA-Fe(III) (2:1) ≫ solid am-Fe(III) > EDTA-Fe(III) (100:1) ≫ fulvic-Fe(III) (1 ppm C). The short-term iron uptake rates by C. sociale in fulvic-Fe(III) (0.1 and 0.2 ppm C) and citric-Fe(III) (100:1) media were about five to six times faster than those in EDTA-Fe(III) (100:1) and solid am-Fe(III) media. The dissociative precipitation rates of premixed organic-Fe(III) complexes in seawater at 10 °C were determined by simple filtration (0.025 μm) involving γ-activity measurements of ⁵⁹Fe. The order of estimated initial Fe(III) dissociative precipitation rates of these organic-Fe(III) complexes in seawater were nearly consistent with those of cell yields in the culture experiments and short-term iron uptake rates by C. sociale [except for fulvic-Fe(III) (1 ppm C) medium]. In fulvic-Fe(III) (0.1 and 0.2 ppm C), citric-Fe(III) (100:1) and EDTA-Fe(III) (2:1) media, the concentrations of dissolved organic-Fe(III) complexes in initial culture experiments are prone to supersaturate under the culture conditions. The supersaturated dissolved organic-Fe(III) complex in seawater supplies biologically available inorganic Fe(III) species in culture media through its dissociation at high pH and high levels of seawater cations. Therefore, the natural dissolved organic-Fe(III) complexes supplied by riverine input may play an important role in supplying bioavailable iron in estuarine mixing system and coastal waters. Received: 6 September 1998 / Accepted: 8 April 1999