Global climate change: an opportunity for coastal dunes??

The predictions for coastal change under the scenario of global sea-level rise offer impending disaster for the variety of coastal morphologies, their associated habitats, and the accompanying infrastructure. However, the predictions tend to ignore the role of sediment budget in the maintenance of coastal morphology and the dynamics of sediment transfers in the beach-dune sand-sharing system. Accepting that shoreline displacement may be an outcome of sea-level rise and a negative sediment budget, conditions are presented that could lead to a positive or equilibrium sediment budget in the coastal foredune and the retention of the foredune system even as it is being displaced. Accommodation space is a key requirement for the continued functioning of the foredune morphologies during periods of sea-level rise.     

Hydrolytic biodegradation of chlorothalonil in the soil and in cabbage crops

Broccoli and Chinese cabbage crops were treated at planting by pouring an emulsion of the fungicide chlorothalonil around the stem of the plant. During culture, chlorothalonil was biodegraded in soil into l,3‐dicarbamoyl‐2,4,5,6‐tetrachlorobenzene (compound 1), l,3‐dicyano‐4‐hydroxy‐2,5,6‐trichlorobenzene (compound 2), and l‐carbamoyl‐3‐cyano‐4‐hydroxy‐2,5,6‐trichlorobenzene (compound 3). Compounds 1 and 2 were the major metabolites in soil. In the harvested broccoli (in the flower) and Chinese cabbages (the leaves), the concentrations of chlorothalonil and of compounds 1 and 2 were lower respectively than 0.1, 0.1 and 0.5mg/kg fresh weight.     

Sediment budget as a driver for sediment management at plumb beach,New York,USA: vectors of change and impacts

Persistent erosion at Plumb Beach, New York, USA, has been countered by a series of isolated actions to stabilize the shoreline. Sediment placed at the erosion site has quickly been removed and re-deposited in downdrift locations to the detriment of the existing habitats. In a renewed effort to better understand the dimensions of change at Plumb Beach, detailed spatial analysis of shoreline displacement, dune-beach profile evolution, and sediment budget has been undertaken through intensive surveying and comparisons of Digital Elevation Models. Products derived from these surveys establish that the sector of maximum erosion has shifted downdrift and that the scale of the changes is twice the volume exchange as previously estimated. Improved knowledge of the dimensions and spatial distributions of the changes is used to create a focused approach that is functioning within the scale of the local sediment budget and reducing its impacts.     

Feasibility versus sustainability in urban water management

Decision making in urban water management is exemplified by the case of Austria: Although researchers define a comprehensible concept of sustainability, practitioners emphasize feasibility and accept limitations in sustainability. Could the specification of particular methods, chosen from some decision support methodology, remedy this situation? While an integrative assessment of sustainability should not be based on prescribed or standardized criteria, or even a certain assessment method, it should force the decision makers to make their chosen premise more visible. To this end a change of the decision making process is proposed, which will allow the decision makers to adapt the decision making process to the circumstances of a specific project in a way that is accepted by the stakeholders.     

Biologische Effekte von Hexachlorbenzol (HCB) in aquatischen Modell?kosystemen

Ohne Zusammenfassung The online version of the original article can be found at     

Dose estimation and radon action level problems due to nanosize radon progeny aerosols in underground manganese ore mine

One of the essential parameters influencing of the dose conversion factor is the ratio of unattached short-lived radon progeny. This may differ from the value identified for indoor conditions when considering special workplaces such as mines. Inevitably, application of the dose conversion factors used in surface workplaces considerably reduces the reliability of dose estimation in the case of mines.This paper surveyed the concentration of radon and its short-lived radon progeny and identified the unattached fraction of short-lived radon progeny. As well equilibrium factor during the month of August was calculated simultaneously at two extraction faces in a manganese ore mine.During working hours the average radon concentrations were 220 Bq m⁻³ and 530 Bq m⁻³ at Faces 1 and 2; the average short-lived progeny concentration was 90 Bq m⁻³ and 190 Bq m⁻³, the average equilibrium factors were 0.46 and 0.36, and the average unattached fractions were 0.21 and 0.17, respectively. The calculated dose conversion factor was between 9 and 27 mSv WLM⁻¹, but higher values could also be possible.     

Design of an institutional decision-making process: the case of urban water management

Urban water infrastructure expenditures cause a major financial burden to municipalities. In the opinion of many policy-makers, public funds may alleviate this burden and facilitate environmental policies. However, practice has shown that despite ambitious policies, funding often follows traditional cost-dominated thinking. In Austria, national policy-makers were interested in new guidelines for funding that increase the transparency of the planning, ensure the adequate treatment of ecological problems, and foster stakeholder involvement, but keep the process as simple as possible, and require minimal changes of the current guidelines. An interdisciplinary project team conducted such a study. Its outcome was tested in two pilot projects. Based on these experiences, policy-makers finally implemented the recommended guidelines for the funding of communal urban water infrastructure projects. A general observation about the policy-making process was a conservative attitude of policy-makers. They prefer simple constraints (precautionary principle) and flexible negotiations (delegation) to complex assessment and decision-aid methodologies.     

Finger and hand protection on circular table and panel saws

Several hundred accidents involving the use of circular saws and resulting in injury, to hands or fingers occur each year in Germany.In the presented project, new approaches for the prevention of hand injuries and for the contactless detection of fingers are being investigated for comprehensive protection on circular saws. The basic principles can be applied to other machines with manual loading and/or unloading. This paper describes several principles to distinct human skin and wood and a safety guard that prevents touching the rotating blade. In a first approach a reliable protective device with functional diversity has been developed using a passive infrared sensor in combination with a capacitive field sensor. Second the distinction between skin and wood or other material is done by dedicated kind of spectral analysis in the near infrared region. With a kind of light curtain the intrusion into the dangerous zone near the blade can be prevented.The safety guard protects the operator’s hand within 50 ms. The forces of the protective system peak at no more than 120 N. We are presenting a complete strategy for such different tasks as cutting wedges, stopped cutting and hidden cutting, which have a very high odds ratio.     

Occurrence of perfluorinated organic acids in the North and Baltic Seas. Part 2: distribution in sediments

Purpose  

The distribution of polar perfluorinated compounds (PFCs) in sea water of the North and Baltic Seas has been described in part 1 of this study. In part 2, their occurrence in sediments is described in order to further investigate their distribution routes and possible sinks.     

Stereochemistry of LinB-catalyzed biotransformation of δ-HBCD to 1R,2R,5S,6R,9R,10S-pentabromocyclododecanol

The haloalkane dehalogenase LinB from Sphingobium indicum B90A converts β-hexachlorocyclohexane (β-HCH), the most persistent HCH stereoisomer, to mono- and dihydroxylated metabolites. Recently, we reported that LinB also transforms α-, β- and γ-hexabromocyclododecanes (HBCDs), which are structurally related to HCHs. Here, we show that LinB catalyzes the hydroxylation of δ-HBCD to two pentabromocyclododecanols (PBCDOHs) and two tetrabromocyclododecadiols (TBCDDOHs). The stereochemistry of this enzymatic transformation was deduced from XRD crystal structure data of the substrate δ-HBCD and α₂-PBCDOH, one of the biotransformation products. Five stereocenters of δ-HBCD are unchanged but the one at C6 is converted to an alcohol with inversion from S- to R-configuration in a nucleophilic, S_N2-like substitution reaction. Only α₂-PBCDOH with the 1R,2R,5S,6R,9R,10S-configuration is obtained but not its enantiomer. With only two of the 64 PBCDOHs formed, these transformations indeed are regio- and stereoselective. A conformational analysis revealed that the triple-turn motive, which is predominant in δ-HBCD and in several other HBCD stereoisomers, is also found in the product. This shows that LinB preferentially converted reactive bromine atoms but not those in the conserved triple-turn motive. The widespread contamination with HCHs triggered the bacterial evolution of dehalogenases which acquired the ability to convert these pollutants and their metabolites. We here demonstrate that LinB of S. indicum also transforms HBCDs regio- and stereoselectively following a similar mechanism.