Performance Characteristics of Instrumental Methods for Monitoring Sulfur Dioxide

The performance characteristics of commercially available sulfur dioxide monitors were determined. Con-ductimetric, colorimetric, and coulometric analyzers were investigated. During this phase of the study, characteristics that were more closely related to field operation were studied. These included comparability of data among the instruments over a period of time, weekly calibration drift, maintenance requirements (including operating cost), unattended operation performance, and the effect of rotameter changes on calibration. The methodology and apparatus used to determine each operational parameter are described. The results of this study should be useful in the selection of instruments for monitoring sulfur dioxide.     

Real-World Emissions from a Modern Production Vehicle Driven in Los Angeles

The emissions of hydrocarbons, nitric oxide, and carbon monoxide from one modern vehicle were measured using on-board instrumentation during about 350 miles of driving in Los Angeles, California. Emissions during on-road driving were compared to those obtained on dynamometers using the urban dynamometer driving schedule (UDDS). Although this study only used one driver and vehicle, tested over a relatively short distance, the analysis technique may be useful for a larger evaluation of off-cycle emissions.

The test vehicle had low warmed-up running emissions over the UDDS and for most of the on-road testing where the air-to-fuel ratio was maintained at the stoichiometric point. However, occasional heavily-loaded conditions during the on-road testing led to richerthan-stoiehiometric operation.

During these brief enrichment events, which lasted up to 29 seconds, CO emissions were increased by a factor of 2500 and HC by a factor of 40 over closed-loop stoichiometric operation. Nitrogen oxide emissions were similar during low-load stoichiometric operation and high-load enriched operation. The relatively constant gram-per-second emission rate of CO and HC observed during enriched operation suggests that such information can be combined with determinations of the frequency of enrichment for a large number of vehicles with similar calibrations to estimate the impact of the additional emissions from enrichment on emissions inventories.     

From Global to Local: Providing Actionable Flood Forecast Information in a Cloud‐Based Computing Environment

Global and continental scale flood forecast provide coarse resolution flood forecast, but from the perspective of emergency management, flood warnings should be detailed and specific to local conditions. The desired refinement can be provided by the use of downscaling global scale models and through the use of distributed hydrologic models to produce a high‐resolution flood forecast. Three major challenges associated with transforming global flood forecasting to a local scale are addressed in this work. The first is using open‐source software tools to provide access to multiple data sources and lowering the barriers for users in management agencies at local level. This can be done through the Tethys Platform that enables web water resources modeling applications. The second is finding a practical solution for the computational requirements associated with running complex models and performing multiple simulations. This is done using Tethys Cluster that manages distributed and cloud computing resources as a companion to the Tethys Platform for web app development. The third challenge is discovering ways to downscale the forecasts from the global extent to the local context. Three modeling strategies have been tested to address this, including downscaling of coarse resolution global runoff models to high‐resolution stream networks and routing with Routing Application for Parallel computatIon of Discharge (RAPID), the use of hierarchical Gridded Surface and Subsurface Hydrologic Analysis (GSSHA) distributed models, and pre‐computed distributed GSSHA models.     

Risk communication and sustainability science: lessons from the field

Sustainability science aims to help societies across the globe address the increased environmental and health crises and risks that range from poverty to climate change to health pandemics. With the increased magnitude and frequency of these large-scale risks to different societies, scientists and institutions have increasingly recognized the need for improved communication and collaboration among researchers, governments, businesses, and communities. This article argues that risk communication has fundamentally important contributions to make to sustainability science’s mission to create use-inspired, “actionable science” that can lead to solutions. Risk communication research can advance the mission of sustainability science to engage a wide range of stakeholders. This kind of engagement is especially important in the context of addressing sustainability problems that are characterized by high levels of uncertainty and complexity. We introduce three core tenets of risk communication research that are fundamental to advancing sustainability science. Risk communication specifically offers an increased understanding of how system feedbacks, human perceptions, and levels of uncertainty influence the study and design of solutions within social ecological systems.     

Digital innovation through partnership between nature conservation organisations and academia: A qualitative impact assessment

Nature conservation organisations increasingly turn to new digital technologies to help deliver conservation objectives. This has led to collaborative forms of working with academia to spearhead digital innovation. Through in-depth interviews with three UK research-council-funded case studies, we show that by working with academics conservation organisations can receive positive and negative impacts, some of which cut across their operations. Positive impacts include new ways of engaging with audiences, improved data workflows, financial benefits, capacity building and the necessary digital infrastructure to help them influence policy. Negative impacts include the time and resources required to learn new skills and sustain new technologies, managing different organisational objectives and shifts in working practices as a result of the new technologies. Most importantly, collaboration with academics was shown to bring the opportunity of a profound change in perspectives on technologies with benefits to the partner organisations and individuals therein.     

Persistence and Changes in Bioavailability of Dieldrin, DDE, and Heptachlor Epoxide in Earthworms Over 45 Years

The finding of dieldrin (88 ng/g), DDE (52 ng/g), and heptachlor epoxide (19 ng/g) in earthworms from experimental plots after a single moderate application (9 kg/ha) 45 years earlier attests to the remarkable persistence of these compounds in soil and their continued uptake by soil organisms. Half-lives (with 95 % confidence intervals) in earthworms, estimated from exponential decay equations, were as follows: dieldrin 4.9 (4.3–5.7) years, DDE 5.3 (4.7–6.1) years, and heptachlor epoxide 4.3 (3.8–4.9) years. These half-lives were not significantly different from those estimated after 20 years. Concentration factors (dry weight earthworm tissue/dry weight soil) were initially high and decreased mainly during the first 11 years after application. By the end of the study, average concentration factors were 1.5 (dieldrin), 4.0 (DDE), and 1.8 (heptachlor epoxide), respectively.     

Sustainable Development and Wildlife Conservation in Tanzanian Maasailand

Many current wildlife conservation efforts in Africa focus on providing local communities with economic incentives to utilize wildlife as a form of land use in order to achieve the twin goals of ecological preservation as well as sustainable human economic development. Tanzanian Maasailand is home to some of the greatest concentrations of large mammals remaining outside National Parks and reserves, as well as a uniquely traditional human culture in the form of the Maasai themselves. Both are increasingly threatened by a variety of factors; poaching and habitat loss for wildlife, and the increasing marginalization of their pastoralist economy with regards to the Maasai. The fundamental cause of declining wildlife populations and biodiversity loss is that the Maasai have little economic or social interest in wildlife due to centralized management and financial benefits which are directed primarily to the Tanzanian state. Maasai pastoralism is highly compatible with wildlife, and the potential for the local communities to sustainably manage and benefit from this resource is promising. However, implementation of effective community-based natural resource management in the area faces political, cultural, and economic obstacles which will be critical in determining the outcomes of both conservation and community development efforts in Maasailand.     

Inputs of heavy metals due to agrochemical use in tobacco fields in Brazil’s Southern Region

Only a few studies have assessed the joint incorporation of heavy metals into agricultural systems based on the range of agrochemicals used on a specific agricultural crop. This study was conducted to assess the heavy metals input through application of the main agrochemicals used in Brazilian tobacco fields. A total of 56 samples of different batches of 5 fertilizers, 3 substrates, 8 insecticides, 3 fungicides, 2 herbicides, and 1 growth regulator commonly used in the cultivation of tobacco in Brazil’s Southern Region were collected from 3 warehouses located in the States of Rio Grande do Sul, Santa Catarina, and Paraná. The total As, Cd, Co, Cr, Cu, Hg, Fe, Mn, Ni, Pb, and Zn content of the samples was then determined and compared with the regulations of different countries and information found in the available literature. The fertilizers were identified as the primary source of heavy metals among the agrochemicals used. Application of pesticides directly to the shoots of tobacco plants contributed very little to the supply of heavy metals. The agrochemicals used in Brazilian tobacco fields provide lower inputs of the main heavy metals that are nonessential for plants than those registered in the international literature for the majority of crop fields in different regions of the world.