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201.
A. O. Oyeyiola C. M. Davidson K. O. Olayinka T. O. Oluseyi B. I. Alo 《Environmental monitoring and assessment》2013,185(3):2167-2177
Surface sediments collected from the Lagos Lagoon, Nigeria, and three adjoining rivers were analysed for their physicochemical properties and pseudo-total concentration of the potentially toxic metals (PTM) Cd, Cr, Cu, Pb and Zn. The concentration of the PTM varied seasonally and spatially. Odo-Iyaalaro was observed to be the most polluted river, with highest concentrations of 42.1 mg kg?1, 102 mg kg?1, 185 mg kg?1, 154 mg kg?1 and 1040 mg kg?1 of Cd, Cr, Cu, Pb and Zn, respectively, while Ibeshe River was the least contaminated, apart from a site affected by Cu from the textile industry. Some of the sediments were found to be above the consensus-based probable effect concentrations and Dutch sediment guideline for metals. Overall metal concentrations were similar to those reported for other tropical lagoon and estuarine systems affected by anthropogenic inputs as a result of rapid urbanisation. Due to the large number of samples, principal component analysis was used to examine relationships within the data set. Generally, sediments collected during the dry season were observed to have higher concentration of PTM than those collected during the rainy season. This means that PTM could accumulate over a prolonged period and then be released relatively rapidly, on an annual basis, into tropical lagoon systems. 相似文献
202.
Mehmet Ates James Daniels Zikri Arslan Ibrahim O. Farah 《Environmental monitoring and assessment》2013,185(4):3339-3348
Aquatic stability and impact of titanium dioxide nanoparticles (TiO2 NPs, 10–30 nm) were investigated using Artemia salina. Acute exposure was conducted on nauplii (larvae) and adults in seawater in a concentration range from 10 to 100 mg/L TiO2 NPs for 24 and 96 h. Rapid aggregation occurred in all suspensions of TiO2 NPs to form micrometer size particles. Yet, both nauplii and adults accumulated the aggregates significantly. Average TiO2 content in nauplii ranged from 0.47 to 3.19 and from 1.29 to 4.43 mg/g in 24 and 96 h, respectively. Accumulation in adults was higher ranging from 2.30 to 4.19 and from 4.38 to 6.20 mg/g in 24 and 96 h, respectively. Phase contrast microscopy images revealed that Artemia were unable to excrete the particles. Thus, the TiO2 aggregates filled inside the guts. No significant mortality or toxicity occurred within 24 h at any dose. Lipid peroxidation levels characterized with malondialdehyde concentrations were not statistically different from those of the controls (p?>?0.05). These results suggested that suspensions of the TiO2 NPs were nontoxic to Artemia, most likely due to the formation of benign TiO2 aggregates in water. In contrast, both mortality and lipid peroxidation increased in extended exposure to 96 h. Highest mortality occurred in 100 mg/L TiO2 NP suspensions; 18 % for nauplii and 14 % for adults (LC50?>?100 mg/L). These effects were attributed to the particle loading inside the guts leading to oxidative stress as a result of impaired food uptake for a long period of time. 相似文献
203.
Rubenstein LZ Vivrette R Harker JO Stevens JA Kramer BJ 《Journal of Safety Research》2011,42(6):493-499
Background
Falls are a common, serious, and often unrecognized problem facing older adults. The objective of this study was to provide an initial clinical and statistical validation for a public health strategy of fall risk self-assessment by older adults using a Fall Risk Questionnaire (FRQ).Methods
Adults age 65 + (n = 40) were recruited at a Los Angeles Veterans Affairs (VA) medical facility and at a local assisted living facility. Participants completed the FRQ self-assessment and results were compared to a “gold standard” of a clinical evaluation of risks using the American/British Geriatrics Society guidelines to assess independent predictors of falls: history of previous falls, fear of falling, gait/balance, muscle weakness, incontinence, sensation and proprioception, depression, vision, and medications. For the comparison, we used an iterative statistical approach, weighing items based on relative risk.Results
There was strong agreement between the FRQ and clinical evaluation (kappa = .875, p < .0001). Individual item kappa values ranged from .305-.832. After dropping one FRQ item (vision risk) because of inadequate agreement with the clinical evaluation (kappa = .139, p = .321), the final FRQ had good concurrent validity.Conclusions
The FRQ goes beyond existing screening tools in that it is based on both evidence and clinical acceptability and has been initially validated with clinical examination data. A larger validation with longitudinal follow-up should determine the actual strength of the FRQ in predicting future falls. 相似文献204.
South Australian organizations assess their OHSMS through audits as evidence of risk control and to help make workplaces healthy and safe. Auditing is an evaluative process regarded as an important step in the cycle of continuous improvement in OHS. Auditing began with financial audits conducted for reasons of corporate governance: for accountability, to inform management decisions and to provide market confidence. Society expects audits to be a tool of regulation, governance and accountability, but celebrated failures of audits to warn of impending financial collapse in organizations in recent years appears to have led to an increased fervour for auditing, rather than a decline. Social audits, including auditing of OHSMS, are intended to determine that an organization is meeting its corporate social responsibilities; but what is audited is often contested and requires subjective analysis. Financial and social audits are subject to failure: unintentional errors, deliberate fraud, financial interests causing undue influence, and undue influence from personal relationships between the auditor and client. We identify five further categories of failure: lack of worker participation; paperwork for the sake of the audit; goal displacement of audit scoring; confusion of audit criteria; and lack of auditor independence and skill. There has been a shift in focus: the current demand and preparation for auditing distracts organizations from the primary goal of making the workplace healthy and safe. We argue that auditing OHSMS has become a ritual rather than a means of improving workplace health and safety and should at least be treated with caution. 相似文献
205.
The officer of the deck (OOD) of a US Navy ship is in charge of the safe and proper operation of the ship, and accountable to the commanding officer for every event that occurs during his or her OOD watch. This paper discusses the development of a prototype behavioral marker system to evaluate, and provide feedback on, the nontechnical (cognitive, social, and personal resource) skills of OODs.An initial set of 17 categories of nontechnical skills were identified from a literature review. A focus group with four qualified OODs used the skills identified from the literature review to develop an initial taxonomy of five categories, each with two or three corresponding behavioral elements. This taxonomy was then used to classify 149 statements concerned with the nontechnical skills of OODs collected from 16 critical incident interviews. After three iterations of adaptations to the taxonomy, two independent raters were able to reach acceptable levels of reliability in using the taxonomy to classify the statements. Although further development work is required, it is suggested that the prototype behavioral marker system has implications for improving safety and performance on military and civilian ships. 相似文献
206.
Agunbiade FO Olu-Owolabi BI Adebowale KO 《Environmental monitoring and assessment》2012,184(1):89-102
The accumulation patterns of ten metals in tissues of plant, Eichornia crassipes, and fishes, Hydrocynus forskahlii and Oreochromis mossambicus, were modeled with simple fuzzy classification (SFC) to assess toxic effects of anthropogenic activities on the coastal biota.
The plant sample was separated into root, stem, and leaves and the fishes into bones, internal tissues, and muscles. They
were analyzed for As, Cd, Cr, Cu, Ni, Pb, V, Fe, Mn, and Zn after wet oxidation of their dried samples. The results were converted
into membership functions of five accumulation classes and aggregated with SFC. The classification results showed that there
was no metal accumulation in the plant parts while the fishes were classified into low accumulation category. The internal
tissues of the fishes had higher metal accumulation than the other parts. Generally, Fe and Mn had highest concentrations
in the biota but are natural to the area and may not constitute significant risk. Cr had the highest transfer and accumulation
from the coastal water into the aquatic lives and may be indicative of risk prone system being a toxic metal. Metal contaminations
in the zone had not significantly accumulated in the biota making them less prone to risk associated with metal accumulation. 相似文献
207.
The technique of diffusion gradient in thin films (DGT) for assessing bioavailable metals has not been tested under field
conditions. We assessed the relationships of DGT- and cation exchange resin-membrane-measured concentrations of Cd, Cu, Pb,
and Zn with plant uptake of the metals under greenhouse and field conditions. In the greenhouse, the effective concentrations
of Cu, Pb, and Zn by DGT correlated significantly with uptake by sorghum (Sorghum bicolor), but cation exchange resin-membrane-measured concentrations of Cd, Pb, and Zn did not correlate with sorghum uptake. In
the field, the DGT-measured concentrations of Cd, Pb, and Zn were not linearly related to uptake Cd, Pb, and Zn by lettuce
(Lactuca sativa) except for Cu uptake (r = 0.87, p < 0.05). Similarly, it was only the resin-membrane-extractable Pb that correlated with Pb uptake by lettuce (r = 0.77; p < 0.05). However, fitting non-linear regression models improved the plant metal uptake predictions by DGT-measured bioavailable
Cd, Cu, Pb, and Zn under field conditions. In conclusion, the DGT technique was fairly predictive of bioavailability in the
greenhouse, but not in the field. 相似文献
208.
Langston WJ O'Hara S Pope ND Davey M Shortridge E Imamura M Harino H Kim A Vane CH 《Environmental monitoring and assessment》2012,184(1):289-311
Biomonitoring of contaminants (metals, organotins, polyaromatic hydrocarbons (PAHs), PCBs) was undertaken in Milford Haven
Waterway (MHW) and a reference site in the Tywi Estuary (St Ishmael/Ferryside) during 2007–2008. Bioindicator species encompassed
various uptake routes—Fucus vesiculosus (dissolved contaminants); Littorina littorea (grazer); Mytilus edulis and Cerastoderma edule (suspension feeders); and Hediste (=Nereis) diversicolor (sediments). Differences in feeding and habitat preference have subtle implications for bioaccumulation trends though, with
few exceptions, contaminant burdens in MHW were higher than the Tywi reference site, reflecting inputs. Elevated metal concentrations
were observed at some MHW sites, whilst As and Se (molluscs and seaweed) were consistently at the higher end of the UK range.
However, for most metals, distributions in MH biota were not exceptional. Several metal-species combinations indicated increases
in bioavailability upstream, which may reflect the influence of geogenic/land-based sources—perhaps enhanced by lower salinity.
TBT levels in MH mussels were below OSPAR toxicity thresholds and in the Tywi were close to zero. Phenyltins were not accumulated
appreciably in M. edulis, whereas some H. diversicolor populations appear subjected to localized (historical) sources. PAHs in H. diversicolor were distributed evenly across most of MHW, although acenaphthene, fluoranthene, pyrene, benzo(a)anthracene and chrysene were highest at one site near the mouth; naphthalenes in H. diversicolor were enriched in the mid-upper Haven (a pattern seen in M. edulis for most PAHs). Whilst PAH (and PCB) concentrations in MH mussels were mostly above reference and OSPAR backgrounds, they
are unlikely to exceed ecotoxicological thresholds. Bivalve Condition indices (CI) were highest at the Tywi reference site
and at the seaward end of MH, decreasing upstream—giving rise to several significant (negative) relationships between CI and
body burdens. Despite the possible influence of salinity gradient as a complicating factor, multivariate analysis indicated
that a combination of contaminants could influence the pattern in condition (and the biomarkers metallothionein and TOSC).
Integrating bioaccumulation data with biological and biochemical endpoints is seen as a useful way to discriminate environmental
quality of moderately contaminated areas such as MHW and to prioritise cause and effect investigations. 相似文献
209.
Evangelia Strogyloudi Michael O. Angelidis Anastassios Christides Evangelos Papathanassiou 《Environmental monitoring and assessment》2012,184(12):7189-7205
Spatial and temporal variability of Cd, Cu, Cr, Ni, Zn, Fe and Mn and metallothionein (MT) concentrations were determined in mussels Mytilus galloprovincialis from Elefsis bay (Saronikos gulf, Greece). Higher concentrations of both metal concentrations and MTs were recorded in mussels inhabiting industrial locations (steelworks and shipyard), indicating a markedly higher metal bioavailability. However at these sites, located at the eastern part of the bay, mussel metal concentrations were not always correlated with both seawater metal concentrations and MTs possibly due to different time scales of integration of the metal sources into mussels and/or the participation of other metal regulatory mechanisms except MT induction. The pattern of the temporal variation of mussel metal concentrations and the MT levels was similar among stations with higher values during the winter–spring season and lower during the summer–autumn period. The inverse relationship of flesh condition index with mussel metal concentrations was attributed to the influence of mussel annual reproductive cycle. 相似文献
210.