Global disposal strategies for waste cathode ray tubes

The collection and management of waste electrical and electronic appliances around the world, and the possible negative environmental consequences have been an issue of current debate. Cathode ray tubes (CRTs) used as display screen for computer monitors and televisions contains large quantities of lead, estimated at between 0.5 and 4 kg, depending on the size of the CRT and has been identified as the most polluting of all electronic waste components. Having failed the tests used in the toxicity characterization of solid wastes, CRTs have been declared ‘hazardous’ and subsequently banned from landfills and incinerators in most developed countries. Presently, large quantities of CRTs are generated globally with only few developed countries having effective take back and sound management program. Meanwhile, large quantities of CRT-containing devices are being moved across frontiers into developing countries in the name of ‘reuse’ and ‘bridging the digital divide’. With near absence of recycling infrastructure for electronic wastes in most developing countries, waste CRTs are disposed of with MSW at open dumps and unsanitary landfills. This paper reviews the current practices in the management of CRTs around the world, with emphasis on the role of regulations, availability of recycling infrastructure, recycling/reuse routes, and export into developing countries. Inappropriate disposal of waste CRTs creates the opportunity for large-scale environmental contamination with heavy metals, especially lead. Appropriate disposal routes are required globally in the management of CRTs in order to mitigate environmental contamination and human exposure to toxins.     

Survey of willingness of residents to participate in electronic waste recycling in Nigeria – A case study of mobile phone recycling

Presently, large quantities of waste mobile phones are being generated in Nigeria with a significant proportion in storage. This paper investigated the behavior of consumers in Nigeria towards this waste stream and their willingness to participate in waste mobile phones recycling. This study also assessed the willingness of consumer's to pay for a more ‘environment friendlier’ phone – the so-called ‘green phone’. We performed a principal component analysis with varimax rotation in order to condense some of our questions into a smaller set of factors. We developed a model to estimate and explain the willingness to pay (WTP) a premium for ‘green’ cell phones. The model showed that the significant predictors of willingness to pay extra for green electronics include awareness and concern about the deteriorating environment, age, and the general attitude towards the environment. About 65% of the respondents are either ‘willing’ or ‘very willing’ to drop-off no-longer-in-use electronics at a nearby recycling facility. Majority of the respondents are also very willing to pay a premium for a green phone. Considering the increasing waste generation by this sector, it has become expedient that a recycling program be introduced for these potentially harmful waste materials.     

Manganese content of Tradescancia species exposed to automotive combustion of methylcyclopentadienyl manganese tricarbonyl in urban and rural landscapes

The purpose of this study is to assess the effect of manganese (Mn) from methylcyclopentadienyl manganese tricarbonyl (MMT) on grass (Tradescancia) species beside the major urban and rural highways in the greater Toronto area. Grass clippings were collected at distances up to 40 m from the roadside of a wooded, weakly exposed site (E+) and two unwooded, highly exposed sites (E++ and E+++) to Mn contamination. Statistical tests, including analysis of variance and correlation coefficients, were used to compare the Mn deposition on grass species with respect to distance and traffic density. A higher deposition of Mn was expected at the highly exposed sites when compared with the weakly exposed site, but a significantly higher concentration of Mn was observed at weakly exposed rural E+ site (Mn = 54.07 microg/g; dry wt) than the highly exposed urban E++ (Mn = 38.17 microg/g; dry wt) and E+++ (Mn = 35.63 microg/g; dry wt) sites. A significant correlation coefficient was found for Mn and traffic density (r2 = 0.311, p = 0.0074) at the weakly exposed site than at the highly exposed (r2 = 0.1589, p = 0.1052) urban sites. These data demonstrate that despite the continuous use of MMT in Canadian gasoline, the levels do not appear to exceed the worldwide tolerable levels (17-334 g/g; dry wt) in grass species inhabiting ecosystems next to major highways in urban regions.     

Pollution studies on Nigerian rivers: The onset of lead pollution of surface waters in Ibadan

Lead levels in the waters and sediments of the lake of the International Institute of Tropical Agriculture, Agodi Lake, Oba Lake, at three stations on Ogunpa stream, and at three stations on Ona River were measured from October 1977 to June 1978, using the combined APDC-MIBK-flame atomic absorption spectrophotometry technique. The lead levels recorded ranged from 0.2 to 46 μg/L for the aqueous phases; however, the levels in the sediments were much higher, ranging from about 18 to 85 mg/kg (dry weight). Although there is nothing alarming about these levels, the levels of lead in water bodies located in areas with high traffic density were consistently higher than levels for comparable waters in low traffic density areas. Similarly, lead levels were significantly higher in the fresh sediments of water bodies in areas with high traffic density, clearly indicating the onset of lead pollution for those high traffic density areas.     

Mechanical performance and Taguchi optimization of kenaf fiber/cement-paperboard composite for interior application

Demand for particleboards keeps increasing and as such more trees are fell for its production, engendering deforestation. For the purpose of reducing falling of trees, this study, focused on recycling of waste paper in the development of paperboard as alternative to particleboards used for furniture and interior household applications. Kenaf fiber (KF) was blended at varying proportions of 0, 1, 2, 3, 4, and 5 wt.% with 20 wt.% constant cement and 20 wt.% constant coconut shell powder while the remaining was paper pulp. Board specimen developed were cured for 14, 28, and 90 days and mechanical properties were examined. Results obtained showed that fiber dosage improved bond strength and screw holding strengths as compared with the control mix. Similarly, modulus of rupture was enhanced with KF loading as compared with control mix while 1 to 3 wt.% KF spawned enhancement of modulus of elasticity. However, 4 and 5 wt.% KF led to a reduction in the modulus. Infusion of the fiber enhanced tensile strength from 1 to 3 wt.% content. 14-day and 28-day curing periods were observed to improve properties while the 90-day curing period is detrimental to all properties. Optimization via signal-to-noise ratio revealed an optimum mix of 2 wt.% obtained for fiber and an optimum curing duration of 28 days.

     

Transition to Lead-Free Products in the US Electronics Industry: A Model of Environmental,Technical, and Economic Preferences

The European Union’s Restriction on the Use of Certain Hazardous Substances (Directive 2002/95/EC) targeted at electronic products took effect in 2006. In contrast, the USA has no comparable national policy on these products. To understand corporate responses to policy differences across jurisdictions, we conducted a structured-questionnaire survey of individuals in 109 companies that are representative of the US electronics industry. The results reveal that 70% of these companies have already adopted lead-free solder for electronics with 49% of the total preferring the SnAgCu formulation, despite uncertainties associated with environmental impacts of this alternative alloy. We use a modified life cycle impact assessment method based on endpoint modeling approach to derive weighting factors that represent the respondents’ value system for tradeoffs among environmental impacts. We use a modified fuzzy Technique for Order Preference by Similarity to Ideal Solution approach to evaluate technical criteria dominance in declared preferences. A statistical model of corporate behavior is also presented. The results provide the first systematic framework that accounts for environmental impact, technological challenge, and business strategy concurrently toward formulating a comprehensive national policy for materials selection in electronic products.     

Assessment of Use,Reuse, and End‐of‐Life Disposal and X‐Ray Fluorescence Analysis Screening of Waste Mobile Phones in Nigeria

Insights into consumer behavior, hazards of inappropriate disposal, and opportunities to reclaim valuable resources     

Ethnobotanical Study of Fuelwood and Timber Wood Consumption and Replenishment in Ogbomoso, Oyo State, Nigeria

A survey of both urban and rural communities in five Local Government Areas (LGA) of Oyo State in Nigeria showed that 76% of households depend on fuelwood for cooking. The total annual wood consumption for fuelling by bread bakers, food sellers and in domestic cooking was 5984 metric tons for the region. The sawmills in the study area also convert 79 889 metric tons of wood yearly into boards of different grades. Total wood consumption outstrips the quantity of wood extracted from the forests. The balance of over 60 000 metric tons of wood is sourced from neighbouring forest locations. The quantity of wood harvested for various purposes did not show a significant difference (p < 0.05) among the five LGAs. However, a significant difference at p > 0.05 existed in the quantity of wood actually consumed in the various LGAs. Moreover. the number of trees cut down outstrips the number of trees planted with a significant difference (p > 0.05) between the mean quantity of wood removed from the forests and the mean quantity replaced by reforestation. The practice in the study area was that of 'cut-eight-plant-one' which is at variance to the much publicized operation 'cut-one-plant-one'. The study concludes that residents of Ogbomoso in Nigeria have not shown positive disposition to tree planting. It therefore suggests scientific tree conservation strategies aimed at improved burning of fuel wood and maximized use of timber products as complementary efforts to enforced tree planting for conservation of our forests.     

Electronic waste (e-waste): material flows and management practices in Nigeria

The growth in electrical and electronic equipment (EEE) production and consumption has been exponential in the last two decades. This has been as a result of the rapid changes in equipment features and capabilities, decrease in prices, and the growth in internet use. This creates a large volume of waste stream of obsolete electrical and electronic devices (e-waste) in developed countries. There is high level of trans-boundary movement of these devices as secondhand electronic equipment into developing countries in an attempt to bridge the 'digital divide'. The past decade has witnessed a phenomenal advancement in information and communication technology (ICT) in Nigeria, most of which rely on imported secondhand devices. This paper attempts to review the material flow of secondhand/scrap electronic devices into Nigeria, the current management practices for e-waste and the environmental and health implications of such low-end management practices. Establishment of formal recycling facilities, introduction of legislation dealing specifically with e-waste and the confirmation of the functionality of secondhand EEE prior to importation are some of the options available to the government in dealing with this difficult issue.     

Effect of environmental conditions on perceived psychological restorativeness of coastal parks

We investigated the hypothesis that perception of psychological restorativeness during visits to coastal parks is modified by objective and perceived environmental conditions. Visitors (n = 1153) to California beaches completed a survey on perceived weather, environmental quality, and perceived restorativeness. We used generalized ordinal logistic models to estimate the association between environmental parameters and odds of perceiving higher levels of restorativeness. Visitors perceived greater restorativeness at beaches when ambient temperatures were at or below mean monthly temperatures and during low tides. The odds of perceiving the environment as more psychologically restorative were three times greater when visiting on days defined by government policy as having good air quality (OR = 3.25; CI: 1.69–6.28). Visitors’ perception of air (OR = 1.56; CI: 1.14–2.18) and water quality (OR = 1.78; CI: 1.28–2.49) also affected perceived restorativeness; with perceived healthy days more restorative. Warmer temperatures with less space due to sea level rise and poor environmental quality will restrict restorative experiences in recreational facilities designed for urban populations.