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431.
Qian YAO Hua ZHANG Jun WU Liming SHAO Pinjing HE 《Frontiers of Environmental Science & Engineering》2010,4(3):286-294
Batch biosorption experiments were conducted to remove Cr(III) from aqueous solutions using activated sludge from a sewage treatment plant. An investigation was conducted on the effects of the initial pH, contact time, temperature, and initial Cr(III) concentration in the biosorption process. The results revealed that the activated sludge exhibited the highest Cr(III) uptake capacity (120 mg·g−1) at 45°C, initial pH of 4, and initial Cr(III) concentration of 100 mg·L−1. The biosorption results obtained at various temperatures showed that the biosorption pattern accurately followed the Langmuir model. The calculated thermodynamic parameters, ΔGo (−0.8– −4.58 kJ·mol−1), ΔHo (15.6–44.4 kJ·mol−1), and ΔSo (0.06–0.15 kJ·mol−1·K−1) clearly indicated that the biosorption process was feasible, spontaneous, endothermic, and physical. The pseudo first-order and second-order kinetic models were adopted to describe the experimental data, which revealed that the Cr(III) biosorption process conformed to the second-order rate expression and the biosorption rate constants decreased with increasing Cr(III) concentration. The analysis of the values of biosorption activation energy (Ea = −7 kJ·mol−1) and the intra-particle diffusion model demonstrated that Cr(III) biosorption was film-diffusion-controlled. 相似文献
432.
Zhenyi Zhang Chihiro Inoue Guanghe Li 《Frontiers of Environmental Science & Engineering》2010,4(3):329-333
The consequence of polycyclic aromatic hydrocarbons (PAHs) in the environment is of great concern. The hydrophobic properties of PAHs significantly impact phase distribution causing limited bioavailability. Enhanced biodegradation has been extensively carried out by surfactants and the redeployment effect was recognized. However, the quantitative relationship concerning the impact of solids was rarely reported. A batch of biphasic tests were carried out by introducing Mycobacterium vanbaalenii PYR-1 and hydroxypropyl-β-cyclodextrin (HPCD) into a mixture of phenanthrene solution and various glass beads (GB37-63, GB105-125, and GB350-500). The comparative results demonstrated that HPCD had little effect on microbial growth and was not degradable by bacterium. A model was proposed to describe the biodegradation process. The regression results indicated that the partition coefficient k d (1.234, 0.726 and 0.448 L·g?1) and the degradation rate k (0 mmol·L?1: 0.055, 0.094, and 0.112; 20 mmol·L?1: 0.126, 0.141, and 0.156; 40 mmol·L?1: 0.141, 0.156 and 0.184 d?1) were positively and negatively correlated with the calculated total surface area (TSA) of solids, respectively. Degradation enhanced in the presence of HPCD, and the enhancing factor f was calculated (20 mmol·L?1: 15.16, 40.01, and 145.5; 40 mmol·L?1: 13.29, 37.97, and 138.4), indicating that the impact of solids was significant for the enhancement of biodegradation. 相似文献
433.
Shuting ZHANG Bo WEI Xin YU Bing LIU Zhuoying WU Li GU 《Frontiers of Environmental Science & Engineering》2010,4(4):459-465
The biologic activated carbon (BAC) process is widely used in drinking water treatments. A comprehensive molecular analysis of the microbial community structure provides very helpful data to improve the reactor performance. However, the bottleneck of deoxyribonucleic acid (DNA) extraction from BAC attached biofilm has to be solved since the conventional procedure was unsuccessful due to firm biomass attachment and adsorption capacity of the BAC granules. In this study, five pretreatments were compared, and adding skim milk followed by ultrasonic vibration was proven to be the optimal choice. This protocol was further tested using the vertical BAC samples from the full-scale biofilter of Pinghu Water Plant. The results showed the DNA yielded a range of 40 μg·g-1 BAC (dry weight) to over 100 μg·g-1 BAC (dry weight), which were consistent with the biomass distribution. All results suggested that the final protocol could produce qualified genomic DNA as a template from the BAC filter for downstream molecular biology researches. 相似文献
434.
Guixiang ZHANG Xitao LIU Ke SUN Ye ZHAO Chunye LIN 《Frontiers of Environmental Science & Engineering》2010,4(4):421-429
Batch sorption experiments were conducted to evaluate the sorption behavior of tetracycline (TC, H3L) on sediments and soils in the presence and absence of cadmium (Cd), as affected by pH and properties of sediments and soils. The results indicated stronger nonlinearity and higher capacity of TC sorption on sediments than on soils. Sorption of TC also strongly depended on environmental factors and sediment/soil properties. Lower pH facilitated TC sorption through a cation exchange mechanism, which also took place at pH values above 5.5, where TC existed as a zwitterion (H2L0) or anions (HL- and L2-). When pH was above 7, however, ligand-promoted dissolution of TC might occur due to TC weakening the Al-O bond of aluminum oxide and the Fe-O bond of iron oxide. Natural organic matter (NOM) plays a more important role in TC sorption than cation exchange capacity (CEC) and clay contents. The presence of Cd (II) increased TC sorption on both sediments and soils, which resulted from the decrease of equilibrium solution pH caused by Cd2+ exchange with H+ ions of sediment/soil surfaces. The increase of TC sorption was also related to the formation of TC-Cd complexes, where Cd2+ acted as a bridge between the sediment/soil and TC. 相似文献
435.
Jinbao WU Zongqiang GONG Liyan ZHENG Yanli YI Jinghua JIN Xiaojun LI Peijun LI 《Frontiers of Environmental Science & Engineering》2010,4(4):387-394
Solubilizing experiments were carried out to evaluate the ability of biodiesel to remove polycyclic aromatic hydrocarbons (PAHs) from highly contaminated manufactured gas plant (MGP) and PAHs spiked soils with hydroxypropyl-β-cyclodextrin (HPCD) and tween 80 as comparisons. Biodiesel displayed the highest solubilities of phenanthrene (420.7 mg·L-1), pyrene (541.0 mg·L-1), and benzo(a)pyrene (436.3 mg·L-1). These corresponded to several fold increases relative to 10% HPCD and tween 80. Biodiesel showed a good efficiency for PAH removal from the spiked and MGP soils for both low molecular weight and high molecular weight PAHs at high concentrations. Biodiesel was the best agent for PAH removal from the spiked soils as compared with HPCD and tween 80; as over 77.9% of individual PAH were removed by biodiesel. Tween 80 also showed comparable capability with biodiesel for PAH solubilization at a concentration of 10% for the spiked soils. Biodiesel solubilized a wider range of PAHs as compared to HPCD and tween 80 for the MPG soils. At PAH concentrations of 229.6 and 996.9 mg·kg-1, biodiesel showed obvious advantage over the 10% HPCD and tween 80, because it removed higher than 80% of total PAH. In this study, a significant difference between PAH removals from the spiked and field MGP soils was observed; PAH removals from the MGP soil by HPCD and tween 80 were much lower than those from the spiked soil. These results demonstrate that the potential for utilizing biodiesel for remediation of highly PAH-contaminated soil has been established. 相似文献
436.
Manuela Baumgarten Rainer Matyssek Christian Huber Hans-Peter Dietrich 《Environmental Sciences Europe》2010,22(5):579-595
Background, aim, and scope Increasing background concentrations of ground-level tropospheric ozone and more frequent and prolonged summer drought incidences due to climate change are supposed to increase the stress on Bavarian forests. For such scenarios growth reduction and yield losses are predicted. Sustainable forest management in Bavaria aims to significantly increase the proportion of beech (Fagus sylvatica L.) because of its broad ecological amplitude. In our regional study different approaches for calculating ozone impact were used to estimate the risks for Bavarian forests in the average climatic, rather moist year 2002 and the extremely dry year 2003.Materials and methods Measurements were conducted for eleven forest ecosystem sites and two forest research sites representing typical Bavarian forest stands under different climatic conditions and situated in different altitudes. For risk assessment currently used approaches were applied either based on the calculation of the cumulative ozone exposure (external dose; MPOC maximal permitted ozone concentration; critical level AOT40phen? accumulated ozone exposure over a threshold of 40 nl [O3] l–1, for the effective phenolgy of beech) or based on the calculation of the phytomedically relevant ozone flux into the stomata (internal dose, critical level AFst>1,6, accumulated stomatal flux above a flux threshold of 1.6 nmol O3?m–2 PLA; PLA = projected leaf area). For calculations continuously recorded ozone concentrations and meteorological and phenological data from nearby rural open field background measuring stations from the national air pollution control and from forested sites were used. Additionally ozone induced leaf symptoms were assessed.Results The exposure-based indices AOT40phen and MPOC as well as the flux-based index AFst>1.6suggest that Bavarian forests are at risk from O3 during a rather moist average year concerning climate conditions (2002) as well as in an extreme dry year (2003). Thus, growth reductions of 5?% are predicted when thresholds are exceeded. Threshold exceedance occurred in both years at all plots, mostly already at the beginning of the growing season and often even many times over. Ozone induced leaf symptoms could be detected only on a few plots in a very slight occurrence.Discussion The results for the applied critical level indices differed depending on climatic conditions during the growing seasons: Regarding exposure-based indices, the highest degree of threshold exceedance occurred in the dry year of 2003 at all plots; the flux-based approach indicated the highest stomatal ozone uptake and thus an increased risk at moist sites or during humid years, whereas the risk was decreasing at dry sites with prolonged water limitation. Hence, soil and accordingly plant water availability was the decisive factor for the flux-modelled internal ozone uptake via stomata. Drought and increased ozone impact can generate synergistic, but also antagonistic effects for forest trees. At water limited rather dry forest sites restricted transpiration and thus production, but concurrently lower ozone uptake and reduced risk for damage can be expected.Conclusions, recommendations, and perspectives For realistic site-specific risk assessment in forest stands the determination of the internal ozone dose via modeling flux based internal stomatal ozone uptake is more appropriate than the calculation of the external ozone dose. The predicted 5?% growth reductions are in discrepancy with the frequently observed increment increase during the last decades in forest stands. Comprehensive and significant statistical verification for ozone induced forest growth reduction as well as the systematic validation of thresholds for ozone in the field is still lacking. However, a multiplicity of different specific new and retrospective growth analysis data should allow closing the gap. Moreover, the determination of canopy transpiration with sap flow measurements is a novel approach to provide cause-effect related, site specific results for the effective internal ozone dose as well as for canopy water supply and consecutively for regional risk estimation. A further future objective is the refinement of O3 flux modelling by further consideration of soil/water budget characteristics and the above mentioned improved estimations of crown and canopy transpiration. Further, the introduction of threshold ranges for forest trees in view of their specific regional climatic conditions and their validation in real forest stands is necessary for developing meaningful ozone risk predictions for forests. 相似文献
437.
Metal contamination of surface soils of industrial city Sialkot,Pakistan: a multivariate and GIS approach 总被引:3,自引:0,他引:3
Riffat Naseem Malik Waqar Azeem Jadoon Syed Zahoor Husain 《Environmental geochemistry and health》2010,32(3):179-191
In this study concentrations of selected metals viz., Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Na, Ni, Pb and Zn in surface soils of
Sialkot city known worldwide for tanneries and pharmaceutical industries were measured to assess the status of urban soil
pollution and to identify sources of contamination. Hierarchical cluster analysis (HACA) indicated concentrations of Mg and
Ca related to parent rock material, Cd, Co, and Pb with traffic related activities, Cr, Cu, Ni and Zn either associated with
automobiles activities or industrial pollution and Fe, K and Na related with anthropogenic activities or lithogenous materials.
Correlation analyses and principal component analysis based on factor analysis confirmed the results of HACA. Spatial distribution
maps exhibited relatively higher concentrations of Cd, Co, Cu, Ni, Pb, Cr and Zn along traffic routes in the city and streams.
The results highlighted concentration of Cd, Ni, Cr, Zn, and Pb measured in urban soil exceeded the permissible limit of surface
soils and advocated an imperative need for detailed baseline investigations of spatial distribution of heavy metals and other
contaminants for the formulation of geochemical database that should be made available to stakeholder involved in monitoring,
assessment and conservation of soil contamination for future planning and management of the Sialkot city. 相似文献
438.
In this paper, we propose a semiparametric survival model to investigate the pattern of spatial and temporal variation in
disease prevalence of chronic wasting disease (CWD) in wild deer in Wisconsin over the years 2002 and 2006. The semiparametric
survival model we suggested allows to build a more flexible model than the parametric model with fewer parametric assumptions
by modeling the baseline hazard using a Gamma process prior. Based on the proposed model, we investigate the geographical
distribution of CWD, and assess the effect of sex on disease prevalence. We use a Bayesian hierarchical framework where latent
parameters capture temporal and spatial trends in disease incidence, incorporating sex and spatially correlated random effects.
We also propose bivariate baseline hazard which change over age and time simultaneously to adopt different effects of age
and time on the baseline hazard. Inference is carried out by using MCMC simulation techniques in a fully Bayesian framework.
Our results suggest that disease has been spreaded mainly in the disease eradication zone and male deer show a significantly
higher infection probability than female deer. 相似文献
439.
Dorota Jermakowicz-Bartkowiak 《Environmental geochemistry and health》2010,32(4):317-320
Vinylbenzyl chloride/divinylbenzene gel copolymer beads have been modified using piperidine, hexamethyleneimine, piperazine,
1-(2-aminoethyl)piperazine, and N-cyclohexyl-1,3-propanediamine. These resins were then tested for the sorption of noble metal ions, namely, Re(VII), Pd(II),
Pt(IV), and Au(III), from a 0.1 M HCl solution. The effect of these resins on the sorption of other coexisting ions, such
as Cu, Ni and Fe, was also studied. Of the resins tested, resin 4 [1-(2-aminoethyl)piperazine groups] showed the highest sorption
capacity for Pt(IV) and Re(VII) from single and multicomponent solutions, with the sorption of Pt(IV) from the multicomponent
solution (Re, Au, Pd, Pt, Cu, Ni Fe) in 0.1 M HCl reaching 68 mg Pt/g. 相似文献
440.
Alecos Demetriades Xiangdong Li Michael H. Ramsey Iain Thornton 《Environmental geochemistry and health》2010,32(6):529-552
In the Lavrion urban area study, Hellas, a five-step sequential extraction method was applied on samples of ‘soil’ (n = 224), affected by long-term mining and metallurgical activities, and house dust (n = 127), for the purpose of studying the potential bioaccessibility of lead and other metals to humans. In this paper, the
Pb concentrations in soil and house dust samples are discussed, together with those in rocks and children’s blood. Lead is
mainly associated with the carbonate, Fe–Mn oxides and residual fractions in soil and house dust. Considering the very low
pH of gastric fluids (1–3), a high amount of metals, present in soil (810–152,000 mg/kg Pb) and house dust (418–18,600 mg/kg Pb),
could be potentially bioaccessible. Consequently, children in the neighbourhoods with a large amount of metallurgical processing
wastes have high blood-Pb concentrations (5.98–60.49 μg/100 ml; median 17.83 μg/100 ml; n = 235). It is concluded that the Lavrion urban and sub-urban environment is extremely hazardous to human health, and the
Hellenic State authorities should urgently tackle this health-related hazard in order to improve the living conditions of
local residents. 相似文献