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排序方式: 共有238条查询结果,搜索用时 46 毫秒
71.
A study was done on the influence of redox potential on the mobility and availability of the various arsenic chemical forms in a Mollisol soil from central Chile amended with biosolid. Arsenic availability was strongly dependent on the applied redox potential. As expected, under reducing conditions (-200 mV vs Hg/Hg(2)Cl(2)) arsenic availability increased significantly, and arsenic was found mainly as arsenite. On the contrary under oxidizing conditions (200 mV vs Hg/Hg(2)Cl(2)) arsenic solubility decreased markedly and was governed by the presence of arsenate. The greatest concentration of organic arsenic species was found under reducing conditions, which would indicate that methylated species may participate in the transformation of arsenate to arsenite. In biosolid-amended soils the concentrations of methylated species increased as a function of time under reducing conditions, which can be attributed to the greater microbial activity resulting from the organic matter supply from the biosolid to soil. In all the systems, a high concentration of As(V) was found under reducing conditions, indicating that the chemical kinetics for the conversion of arsenate to arsenite is slow. Along time, the content of As(V) increased in the control soils, which may be attributed to the possible dissolution of iron oxides and hydroxides under reducing conditions. 相似文献
72.
Martínez-Lladó X Gibert O Martí V Díez S Romo J Bayona JM de Pablo J 《Environmental pollution (Barking, Essex : 1987)》2007,149(1):104-113
Sediments have long been recognised as a sink for many contaminants like polycyclic aromatic hydrocarbons (PAHs) and tributyltin (TBT), which by virtue of their nature can strongly adsorb onto sediments affecting the benthic community inhabiting them. Using geographical information systems, this study reports and combines the results of several already existing studies along Barcelona harbour in order to assess the potential ecological impacts of these contaminants on the benthos of the harbour ecosystem. Chemical analysis indicated low to moderate contents of PAHs and high contents of TBT in sediments in Barcelona harbour. Comparison against existing sediment quality guidelines (SQGs) indicated that acutely toxic effects would not be expected for PAHs but for TBT, which represents a serious environmental threat for the benthic community. Benthos surveys revealed a deterioration of the benthic community throughout the harbour, especially in the inner port. 相似文献
73.
Trends in the elemental composition of fine particulate matter in Santiago, Chile, from 1998 to 2003
Sax SN Koutrakis P Rudolph PA Cereceda-Balic F Gramsch E Oyola P 《Journal of the Air & Waste Management Association (1995)》2007,57(7):845-855
Santiago, Chile, is one of the most polluted cities in South America. As a response, over the past 15 yr, numerous pollution reduction programs have been implemented by the environmental authority, Comisión Nacional del Medio Ambiente. This paper assesses the effectiveness of these interventions by examining the trends of fine particulate matter (PM(2.5)) and its associated elements. Daily fine particle filter samples were collected in Santiago at a downtown location from April 1998 through March 2003. Additionally, meteorological variables were measured continuously. Annual average concentrations of PM(2.5) decreased only marginally, from 41.8 microg/m3 for the 1998-1999 period to 35.4 microg/m3 for the 2002-2003 period. PM(2.5) concentrations exceeded the annual U.S. Environmental Protection Agency standard of 15 microg/m3. Also, approximately 20% of the daily samples exceeded the old standard of 65 microg/m3, whereas approximately half of the samples exceeded the new standard of 35 microg/m3 (effective in 2006). Mean PM(2.5) levels measured during the cold season (April through September) were three times higher than those measured in the warm season (October through March). Particulate mass and elemental concentration trends were investigated using regression models, controlling for year, month, weekday, wind speed, temperature, and relative humidity. The results showed significant decreases for Pb, Br, and S concentrations and minor but still significant decreases for Ni, Al, Si, Ca, and Fe. The larger decreases were associated with specific remediation policies implemented, including the removal of lead from gasoline, the reduction of sulfur levels in diesel fuel, and the introduction of natural gas. These results suggest that the pollution reduction programs, especially the ones related to transport, have been effective in reducing various important components of PM(2.5). However, particle mass and other associated element levels remain high, and it is thus imperative to continue the efforts to improve air quality, particularly focusing on industrial sources. 相似文献
74.
The Almería-Oran Oceanographic Front (AOOF) has been proposed as an effective marine barrier to gene flow between the NE Atlantic
Ocean and the Mediterranean Sea for several species. Previous studies using allozymes and mitochondrial DNA have reported
a scenario of secondary intergradation between populations of Mytilus galloprovincialis from those basins, with the allelic frequencies of some loci showing abrupt clinal patterns across the AOOF. In this study,
we aimed at testing the congruence between six neutral polymorphic microsatellites versus previous data on allozymes and mtDNA-RFLPs,
at depicting the population structure of this species in the Iberian Peninsula. Microsatellite genotyping was scored on 17
samples of mussels collected in the Iberian coast, including some areas not sampled before. Microsatellites exhibited larger
intrabasin diversity (F
SC = 1.72%,
), similar interbasin differentiation (F
CT = 2.81%) and fewer allelic clines than allozymes or mtDNA haplotypes. These results fully support the scenario of secondary
intergradation with some ongoing gene flow between basins, as proposed in previous analyses. Moreover, this congruence between
markers and analyses separated by a 12-year period (1988–2000) confirm the temporal stability of this marine barrier at shaping
the Iberian phylogeographic break in M. galloprovincialis. In addition, the genetic continuity between the NE Atlantic (Portugal) and the Alboran Sea seems to be warranted across the
Gulf of Cadiz and the Gibraltar strait after the present microsatellite data.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
75.
Rocío Mariano-Jelicich Sofía Copello Juan Pablo Seco Pon Marco Favero 《Marine Biology》2014,161(1):119-129
Black-browed albatrosses (Thalassarche melanophris) disperse over the Argentinean Continental Shelf and neighboring waters during their non-breeding season. It is one of the most frequent seabirds attending fishing vessels and also the most common Procellariform in the bycatch of longliners and trawlers in the area. Understanding the use of fishery discards by this species is an important issue when assessing the potential effect of strategic discard management in decreasing the abundance, interactions, and mitigating mortality. In the present study, we analyzed carbon and nitrogen stable isotope compositions in the blood of Black-browed albatrosses to assess the relative contribution of discards from different fisheries to the diet of this species in winter. Samples were obtained in winter 2011 from fishing vessels operating between 41–43°S and 57–59°W. No sex differences in δ13C and δ15N were observed. Results indicate that during their non-breeding season, isotopic signatures of Black-browed albatrosses are closer to discards and offal generated by fisheries and in particular by trawlers. The large fishing effort of trawl fisheries in Argentina highlights the urgency of an exhaustive analysis to find practical and effective ways to reduce the number of seabirds attending trawlers. 相似文献
76.
Rim Khlifi Pablo Olmedo Fernando Gil Molka Feki-Tounsi Bouthaina Hammami Ahmed Rebai Amel Hamza-Chaffai 《Environmental monitoring and assessment》2014,186(2):761-779
The human health impact of the historic and current mining and industrial activities in Tunisia is not known. This study assessed the exposure to metals in the population of Southern Tunisia, using biomonitoring. The aim of this pilot study was to evaluate metal exposure on 350 participants living near mining and active industrial areas in the South of Tunisia. Blood specimens were analyzed for metals (Cd, Cr, As, and Ni) by Atomic Absorption Spectrometer equipped with Zeeman background correction and AS-800 auto sampler by graphite furnace and graphite tubes with integrated L'vov platform. The sample population was classified according to different age groups, sex, smoking habit, sea food and water drinking consumption, occupational exposure, amalgam fillings and place of residence. The blood As, Cd, Cr and Ni values expressed as mean?±?SD were 1.56?±?2.49, 0.74?±?1.15, 35.04?±?26.02 and 30.56?±?29.96 μg/l, respectively. Blood Cd and Ni levels in smokers were 2 and 1.2 times, respectively, higher than in non-smokers. Blood Cd levels increase significantly with age (p?=?0.002). As, Cd and Ni were significantly correlated with gender and age (p?<?0.05). Cd level in blood samples of subjects occupationally exposed was 1.3 times higher than that of non-exposed. Blood metals were not significantly affected by amalgam fillings, place of living and sea food and drinking water consumption. This first biomonitoring study of metal exposure in the South of Tunisia reveals a substantial exposure to several metals. The pathways of exposure and health significance of these findings need to be further investigated. 相似文献
77.
Towards a framework for assessment and management of cumulative human impacts on marine food webs
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Sylvaine Giakoumi Benjamin S. Halpern Loïc N. Michel Sylvie Gobert Maria Sini Charles‐François Boudouresque Maria‐Cristina Gambi Stelios Katsanevakis Pierre Lejeune Monica Montefalcone Gerard Pergent Christine Pergent‐Martini Pablo Sanchez‐Jerez Branko Velimirov Salvatrice Vizzini Arnaud Abadie Marta Coll Paolo Guidetti Fiorenza Micheli Hugh P. Possingham 《Conservation biology》2015,29(4):1228-1234
Effective ecosystem‐based management requires understanding ecosystem responses to multiple human threats, rather than focusing on single threats. To understand ecosystem responses to anthropogenic threats holistically, it is necessary to know how threats affect different components within ecosystems and ultimately alter ecosystem functioning. We used a case study of a Mediterranean seagrass (Posidonia oceanica) food web and expert knowledge elicitation in an application of the initial steps of a framework for assessment of cumulative human impacts on food webs. We produced a conceptual seagrass food web model, determined the main trophic relationships, identified the main threats to the food web components, and assessed the components’ vulnerability to those threats. Some threats had high (e.g., coastal infrastructure) or low impacts (e.g., agricultural runoff) on all food web components, whereas others (e.g., introduced carnivores) had very different impacts on each component. Partitioning the ecosystem into its components enabled us to identify threats previously overlooked and to reevaluate the importance of threats commonly perceived as major. By incorporating this understanding of system vulnerability with data on changes in the state of each threat (e.g., decreasing domestic pollution and increasing fishing) into a food web model, managers may be better able to estimate and predict cumulative human impacts on ecosystems and to prioritize conservation actions. 相似文献
78.
79.
Pablo Resco Ana Iglesias Isabel Bardají Vicente Sotés 《Regional Environmental Change》2016,16(4):979-993
Our aim was to explore the adaptation choices to climate change in the grapevine regions of Spain from two points of view. First, what are the main reasons for concern? Second, how large is the adaptation effort in each region? We address the first question by measuring sensitivity to climate change with Huglin, Cold Night and Dryness Indices over the entire territory, providing information on the adaptation type (e.g. varieties, zoning, water allocation). We then estimate probabilistic projections across scenario, zone and sensitivity indices in the 56 Protected Designation of Origin areas to inform on the magnitude of the adaptation effort. Second, we propose an adaptation effort measure that is framed according to the local environmental context. Results suggest that most areas urgently need an adaptation plan due to the deterioration of production and quality indices as a result of climate change. Potential opportunities in many climate regions might be limited by current policy. The production objectives of quality and quantity trade-offs will probably need to be revised by analysing the sustainability of grapevine production. 相似文献
80.
Duarte-Guardia Sandra Peri Pablo L. Amelung Wulf Sheil Douglas Laffan Shawn W. Borchard Nils Bird Michael I. Dieleman Wouter Pepper David A. Zutta Brian Jobbagy Esteban Silva Lucas C. R. Bonser Stephen P. Berhongaray Gonzalo Piñeiro Gervasio Martinez Maria-Jose Cowie Annette L. Ladd Brenton 《Mitigation and Adaptation Strategies for Global Change》2019,24(3):355-372
Mitigation and Adaptation Strategies for Global Change - Soils hold the largest pool of organic carbon (C) on Earth; yet, soil organic carbon (SOC) reservoirs are not well represented in climate... 相似文献