The effect of solvent concentration on the use of palladized-iron for the step-wise dechlorination of polychlorinated biphenyls in soil extracts

This report describes the application of palladized iron (Pd/Fe) to the dechlorination of polychlorinted biphenyls (PCBs) at ambient temperature. Experiments supported by congener-specific analyses demonstrated that dechlorination occurs in a step-wise fashion with the meta-chlorines being more reactive than ortho-chlorines. Over the course of the laboratory experiments, complete conversion to biphenyl was observed. The process was also tested with PCBs dissolved in high (40-60%) concentrations of ethanol and isopropanol as a means of simulating solutions generated by commercial soil and solid waste extraction processes. The reaction rate was sensitive to the percentage of solvent but complete dechlorination was still indicated. Tests with soil extracts from a contaminated site demonstrated that there were no apparent interferences from asphalt and other miscellaneous debris. Short-duration tests with highly contaminated PCB solutions from a hazardous waste site demonstrated efficient dechlorination although there was a reduction in reaction rate with time.     

Environmental Reporting by the Fortune 50 Firms

/ The extent and use of industry-reported environmental data are increasing, warranting an in-depth analysis of this information. This paper reviews the environmental reporting guidelines issued by several business and nonprofit organizations and evaluates the environmental reports published by the Fortune 50 companies, half of which publish reports. After describing the history of environmental reporting and the content of the guidelines, a comparative evaluation is made to indicate the types of companies producing reports, the topics reported, the intended audiences, the scope and depth of the material reported, and the effectiveness of the reports as communication devices. These reports are mechanisms to enhance a firm's image, public relations, and marketing and are aimed largely at concerned individuals, affected communities, and investors. Significant differences in the content and the depth of reports are seen as firms report on topics that are perceived by the public as high risks. The most complete reports are published by industries with poor or controversial public images, e.g., the chemical and timber industries. Still, no report provided information that was sufficient for comprehensive or comparative analyses of environmental performance. Recommendations are provided to increase the quality and effectiveness of environmental reporting.KEY WORDS: Communication; Environmental management; Performance reporting; Reporting; Stakeholder     

USING UNCENSORED TRACE-LEVEL MEASUREMENTS TO DETECT TRENDS IN GROUND WATER CONTAMINATION1

ABSTRACT: Environmental decision making involving trace-levels of contaminants can be complicated by censoring, the practice of reporting concentrations either as less than the limit of detection (LOD) or as not detected (ND) when a test result is less than the LOD. Censoring can result in data series that are difficult to meaningfully summarize, graph, and analyze through traditional statistical methods. In spite of the relatively large measurement errors associated with test results below the LOD, simple and meaningful analyses can be carried out that provide valuable information not available if data are censored. For example, an indication of increasing levels of contamination at the fringe of a plume can act as an early warning signal to trigger further study, an increased sampling frequency, or a higher level of remediation at the source. This paper involves the application of nonparametric trend analyses to uncensored trace-level groundwater monitoring data collected between March 1991 and August 1994 on dissolved arsenic and chromium for seven wells at an industrial site in New York.     

A STRIP MODEL APPROACH TO PARAMETERIZE A COUPLED GREEN‐AMPT KINEMATIC WAVE MODEL1

ABSTRACT: Infiltration processes at the plot scale are often described and modeled using a single effective hydraulic conductivity (Kg) value. This can lead to errors in runoff and erosion prediction. An integrated field measurement and modeling study was conducted to evaluate: (1) the relationship among rainfall intensity, spatially variable soil and vegetation characteristics, and infiltration processes; and (2) how this relationship could be modeled using Green and Ampt and a spatially distributed hydrologic model. Experiments were conducted using a newly developed variable intensity rainfall simulator on 2 m by 6 m plots in a rangeland watershed in southeastern Arizona. Rainfall application rates varied between 50 and 200 mm/hr. Results of the rainfall simulator experiments showed that the observed hydrologic response changed with changes in rainfall intensity and that the response varied with antecedent moisture condition. A distributed process based hydrologic simulation model was used to model the plots at different levels of hydrologic complexity. The measurement and simulation model results show that the rainfall runoff relationship cannot be accurately described or modeled using a single Kg value at the plot scale. Multi‐plane model configurations with infiltration parameters based on soil and plot characteristics resulted in a significant improvement over single‐plane configurations.     

Rapid,recurring, structured survey versus bioblitz for generating biodiversity data and analysis with a multispecies abundance model

A bioblitz inexpensively and quickly generates biodiversity data, but bioblitzes are often conducted with haphazard, unreplicated sampling. Results tend to be taxonomically, geographically, or temporally biased, lack metadata, and consist of lists of observed taxa that do not enable further analyses or correction for imperfect detection. A rapid, recurring, structured survey (RRSS) uses a structured sampling design and temporal and spatial replication to survey randomly selected sites on a conservation property. We participated in a loosely structured bioblitz and a subsequent RRSS at Big Canoe Creek Nature Preserve in Springville (St. Clair County), Alabama (USA) to compare observed richness derived from the 2 survey approaches. The RRSS data structure enabled us to fit models that accounted for imperfect detection to estimate abundances, occupancy probabilities, and habitat associations. The loosely structured bioblitz data could not be used in such models. We present a new integrated multispecies abundance model that we applied to avian RRSS data. Our model extension enables estimation for the community, employs data augmentation to estimate the number of undetected species, and incorporates covariates. The RRSS generated a more comprehensive and less biased list of observed taxonomic richness than the loosely structured bioblitz (e.g., 73 vs. 45 bird species and 104 vs. 63 insect families from the RRSS vs. loosely structured bioblitz, respectively). Models fit to the RRSS data identified seasonal patterns in avian community composition and allowed for estimation of habitat–occupancy relationships for insect taxa. The RRSS protocol has potential for broad transferability as a standardized, quick, and inexpensive way to inventory biodiversity and estimate ecological parameters while providing an outreach opportunity.     

Topographic heterogeneity influences fish use of an experimentally restored tidal marsh.

Ecological theory predicts that incorporating habitat heterogeneity into restoration sites should enhance diversity and key functions, yet research is limited on how topographic heterogeneity affects higher trophic levels. Our large (8-ha) southern California restoration experiment tested effects of tidal creek networks and pools on trophic structure of salt marsh habitat and high-tide use by two regionally dominant fish species, California killifish (Fundulus parvipinnis) and longjaw mudsucker (Gillichthys mirabilis). We expected tidal creeks to function as "conduits" that would enhance connectivity between subtidal and intertidal habitat and pools to serve as microhabitat "oases" for fishes. Pools did provide abundant invertebrate prey and were a preferred microhabitat for F. parvipinnis, even when the entire marsh was inundated (catch rates were 61% higher in pools). However, G. mirabilis showed no preference for pools. At a larger scale, effects of tidal creek networks were also mixed. Areas containing creeks had 12% higher catch rates of G. mirabilis, but lower catch rates and feeding rates of F. parvipinnis. Collectively, the results indicate that restoring multiple forms of heterogeneity is required to provide opportunities for multiple target consumers.     

Retrospective assessment of dryland soil stability in relation to grazing and climate change

Accelerated soil erosion is an aspect of dryland degradation that is affected by repeated intense drought events and land management activities such as commercial livestock grazing. A soil stability index (SSI) that detects the erosion status and susceptibility of a landscape at the pixel level, i.e., stable, erosional, or depositional pixels, was derived from the spectral properties of an archived time series (from 1972 to 1997) of Landsat satellite data of a commercial ranch in northeastern Utah. The SSI was retrospectively validated with contemporary field measures of soil organic matter and erosion status that was surveyed by US federal land management agencies. Catastrophe theory provided the conceptual framework for retrospective assessment of the impact of commercial grazing and soil water availability on the SSI. The overall SSI trend was from an eroding landscape in the early drier 1970s towards stable conditions in the wetter mid-1980s and late 1990s. The landscape catastrophically shifted towards an extreme eroding state that was coincident with the “The Great North American Drought of 1988”. Periods of landscape stability and trajectories toward stability were coincident with extremely wet El Niño events. Commercial grazing had less correlation with soil stability than drought conditions. However, the landscape became more susceptible to erosion events under multiple droughts and grazing. Land managers now have nearly a year warning of El Niño and La Niña events and can adjust their management decisions according to predicted landscape erosion conditions.     

Estimating the value of foresight: aggregate analysis of natural hazard mitigation benefits and costs

Hazard mitigation planners claim that foresighted present actions and investments produce significant future benefits. However, they have difficulty in supporting their claims, since previously their evidence typically was derived from individual case studies. Constituents and decision makers are often sceptical, believing that individual cases are either inapplicable to their situation or non-randomly selected to support a particular view. Planners need objective evidence based on a large body of experience to support the case for mitigation. Such is the unique contribution of a recent U.S. study that found that each dollar spent in three federal natural hazard mitigation grant programs (the Hazard Mitigation Grant Program, Project Impact, and the Flood Mitigation Assistance Program) saves society an average of $4 in future avoided losses. Complementing the aggregate benefit-cost analysis with community-based evaluations, the study yielded insights on how planners can improve long-term community resilience in the face of extreme events. Valuable lessons for mitigation planners and policy makers emerged: the need to consider a wide variety of losses, the importance of mixing qualitative with quantitative analysis, the value of averaging results over a large number of projects, and the need to more explicitly address social issues and data collection in order to reduce vulnerability and enhance resilience to cope with twenty-first century hazards.