Evaluation of short-term Ogawa passive, photolytic, and federal reference method sampling devices for nitrogen oxides in El Paso and Houston, Texas

Passive Sampling Devices (PSDs) have been successfully used by government and academic agencies to monitor common ambient air pollutants such as ozone and nitrogen dioxide (NO(2)). Most PSD studies have involved long-term (e.g. bi-weekly or monthly) sampling. But the Passive Ozone Network of Dallas (POND) studies of 1998 and 1999 showed that high quality 24-hour and 12-hour data using the Ogawa PSD could be collected for ambient ozone concentrations. This paper presents an evaluation of short-term passive sampling results for nitrogen oxides (NO(x)) in El Paso and Houston, Texas, using the Ogawa PSD. The Ogawa NO(x) PSDs were compared to both Federal Reference Method (FRM) monitors and a photolytic converter, with the photolytic converter designed to report closer concentrations to "true" NO(x) by more effectively limiting the interferences of other nitrogen species. Overall, good agreement was noted for all three monitor types in both cities, supporting the potential use of lower cost Ogawa PSDs for large multi-site episodic NO(x)/NO(2)/NO saturation screening studies. This evaluation was conducted during two separate six week periods of the cooler winter months so additional testing of the Ogawa PSDs during different seasons is recommended.     

Putting first things first: Outcome and process focus in knowledge work teams

This paper presents a new perspective on the management of outcomes and processes in a knowledge team's work. Knowledge teams frequently face complex, open‐ended tasks for which the a priori specification of goals and work processes is not possible. Such teams must define these work elements themselves; emphasizing one over the other can lead a team to become either outcome‐or process‐focused, with implications for the level at which they identify their activities and the flexibility with which they conduct work. A survey study of student teams and a field study of organizational teams test the effects of outcome versus process focus on performance. Consistent with prior findings, the first study demonstrates that outcome focus is positively related to performance on complex, open‐ended tasks and that team members' level of action identification mediates the effects of outcome and process focus on performance. Action research conducted as part of the second study demonstrates the importance of early events in a team's life cycle and the challenge for managers who hope to influence their teams to have a greater degree of focus on outcomes over process. Copyright © 2009 John Wiley & Sons, Ltd.     

A review of current knowledge concerning dry deposition of atmospheric mercury

The status of the current knowledge concerning the dry deposition of atmospheric mercury, including elemental gaseous mercury (Hg⁰), reactive gaseous mercury (RGM), and particulate mercury (Hg_p), is reviewed. The air–surface exchange of Hg⁰ is commonly bi-directional, with daytime emission and nighttime deposition over non-vegetated surfaces and vegetated surfaces with small leaf area indices under low ambient Hg⁰ conditions. However, daytime deposition has also been observed, especially when the ambient Hg⁰ is high. Typical dry deposition velocities (V_d) for Hg⁰ are in the range of 0.1–0.4 cm s^?1 over vegetated surfaces and wetlands, but substantially smaller over non-vegetated surfaces and soils below canopies. Meteorological, biological, and soil conditions, as well as the ambient Hg⁰ concentrations all play important roles in the diurnal and seasonal variations of Hg⁰ air–surface exchange processes. Measurements of RGM deposition are limited and are known to have large uncertainties. Nevertheless, all of the measurements suggest that RGM can deposit very quickly onto any type of surface, with its V_d ranging from 0.5 to 6 cm s^?1. The very limited data for Hg_p suggest that its V_d values are in the range of 0.02–2 cm s^?1.A resistance approach is commonly used in mercury transport models to estimate V_d for RGM and Hg_p; however, there is a wide range of complexities in the dry deposition scheme of Hg⁰. Although resistance-approach based dry deposition schemes seem to be able to produce the typical V_d values for RGM and Hg⁰ over different surface types, more sophisticated air–surface exchange models have been developed to handle the bi-directional exchange processes. Both existing and newly developed dry deposition schemes need further evaluation using field measurements and intercomparisons within different modelling frameworks.     

C2–C8 NMHCs over the Eastern Mediterranean: Seasonal variation and impact on regional oxidation chemistry

More than 2500 measurements of C₂–C₈ non-methane hydrocarbons (NMHCs) have been conducted at Finokalia sampling station on the island of Crete over a thirty-month period (September 2003–February 2006), to investigate the factors controlling NMHC levels and estimate their role in the oxidizing capacity of the Eastern Mediterranean atmosphere. Atmospheric concentrations of NMHCs range from below the detection limit (5 pptv) to a few ppbv and present a hydroxyl radical (OH) driven seasonal pattern with lower values during summer. The diel variability was also influenced by the reaction of the NMHC with the OH radical, exhibiting a nighttime maximum and a midday or early afternoon minimum. Long-lived compounds demonstrate higher concentrations under the influence of the northern sector (European continent), indicating that besides chemistry, transport significantly contributes to NMHCs levels in the area. Based on the observed NMHCs diurnal cycles, mean OH radical levels of 3.5 × 10⁶ molecules cm⁻³ have been derived for May–October period.     

Development of a distance-to-roadway proximity metric to compare near-road pollutant levels to a central site monitor

The primary objective of the Detroit Exposure and Aerosol Research Study (DEARS) was to compare air pollutant concentrations measured at various neighborhoods, or exposure monitoring areas (EMAs), throughout a major metropolitan area to levels measured at a central site or community monitor. One of the EMAs was located near a busy freeway (annual average daily traffic (AADT) of ～130,000) so that impacts of mobile sources could be examined. Air pollution concentrations from the roadway-proximate sites were compared to the central site monitor. The volatile organic compounds (VOCs) selected (benzene, toluene, ethylbenzene, m,p- and o-xylene, 1,3 butadiene, 1,3,5-trimethylbenzene and 4-ethyltoluene) are typically associated with mobile sources. Gradients were also evident that demonstrated the amplification of pollutant levels near the roadway compared to the community monitor. A novel distance-to-roadway proximity metric was developed to plot the measurements and model these gradients. Effective distance represents the actual distance an air parcel travels from the middle of a roadway to a site and varies as a function of wind direction, whereas perpendicular distance is a fixed distance oriented normal to the roadway. Perpendicular distance is often used as a proxy for exposures to traffic emissions in epidemiological studies.Elevated concentrations of all the compounds were found for both a summer and winter season. Effective distance was found to be a statistically significant (p < 0.05) univariate predictor for concentrations of toluene, ethylbenzene, m,p-xylene and o-xylene for summer 2005. For each of these pollutants, effective distance yielded lower p-values than the corresponding perpendicular distance models, and model fit improved. Results demonstrate that this near-road EMA had elevated levels of traffic-related VOCs compared to the community monitor, and that effective distance was a more accurate predictor of the degree to which they were elevated as a function of distance. Effective distance produced a range of distance-to-roadway values for a single site based on wind direction, thus increasing the number and range of values that could be used to plot and predict relative differences in pollutant concentrations between two sites.     

Understanding Social Complexity Within the Wildland–Urban Interface: A New Species of Human Habitation?

The lack of knowledge regarding social diversity in the Wildland Urban Interface (WUI) or an in-depth understanding of the ways people living there interact to address common problems is concerning, perhaps even dangerous, given that community action is necessary for successful wildland fire preparedness and natural resource management activities. In this article, we lay out the knowledge and preliminary case study evidence needed to begin systematically documenting the differing levels and types of adaptive capacity WUI communities have for addressing collective problems such as wildland fire hazard. In order to achieve this end, we draw from two theoretical perspectives encompassing humans' interactions with their environment, including (1) Kenneth Wilkinson's interactional approach to community, (2) and certain elements of place literature. We also present case study research on wildfire protection planning in two drastically different California communities to illustrate how social diversity influences adaptive capacity to deal with hazards such as wildland fire. These perspectives promote an image of the WUI not as a monolithic entity but a complex mosaic of communities with different needs and existing capacities for wildland fire and natural resource management.     

Understanding the Ecology of Blue Elderberry to Inform Landscape Restoration in Semiarid River Corridors

Societal constraints often limit full process restoration in large river systems, making local rehabilitation activities valuable for regeneration of riparian vegetation. A target of much mitigation and restoration is the federally threatened Valley elderberry longhorn beetle and its sole host plant, blue elderberry, in upper riparian floodplain environments. However, blue elderberry ecology is not well understood and restoration attempts typically have low success rates. We determined broad-scale habitat characteristics of elderberry in altered systems and examined associated plant species composition in remnant habitat. We quantified vegetation community composition in 139 remnant riparian forest patches along the Sacramento River and elderberry stem diameters along this and four adjacent rivers. The greatest proportion of plots containing elderberry was located on higher and older floodplain surfaces and in riparian woodlands dominated by black walnut. Blue elderberry saplings and shrubs with stems <5.0 cm in diameter were rare, suggesting a lack of recruitment. A complex suite of vegetation was associated with blue elderberry, including several invasive species which are potentially outcompeting seedlings for light, water, or other resources. Such lack of recruitment places increased importance on horticultural restoration for the survival of an imperiled species. These findings further indicate a need to ascertain whether intervention is necessary to maintain functional and diverse riparian woodlands, and a need to monitor vegetative species composition over time, especially in relation to flow regulation.     

An improved user-based beach climate index

In many coastal resort areas of the world, it is likely that optimal climatic conditions for beach use might occur outside the peak of the tourist season. Investigation of this issue together with associated publicity might help to spread the tourism load and hence reduce undesirable social and environmental effects of extreme seasonality in tourist demand. For this to take place, better knowledge of beach user preferences in terms of climate and bathing water temperature is required. Questionnaire surveys were carried out in Wales, Malta and Turkey to establish the preferences of north European beach users for thermal sensation and bathing water temperature, plus priority levels for other climatic attributes. A user-based beach climate index based on these preferences and priorities was formulated. Linkage was made between the user-generated ratings for various climatic conditions and published climate data to evaluate most major Euro-Mediterranean/Black Sea and a range of other beach tourism areas on a month-by-month basis. Results showed excessively hot thermal sensation in many southern and eastern Mediterranean coastal destinations during July and August, the present peak of the beach tourism season. Highest preference was given to water temperatures rather lower than those found in these areas during late summer. Many long haul coastal destinations popular with north European visitors had similar unpleasant thermal sensations over several months. Uncertainties and deficiencies still exist with the system, but from the point of view of north European beach users the final scores generated in this study may be regarded as good approximations of the quality of resort area climates for sedentary beach use.     

Assessing anthropogenic impact on Mediterranean sand dunes from aerial digital photography

The Mediterranean region plays host to ca. 33% of the world’s tourism industry. This population of visitors (ca. 147 million in 1990) inevitably exerts an enormous impact on the natural resources of this coastal zone. In May 1997, a new generation Aerial Digital Photographic System [ADPS] configured with a Kodak Digital Science 460 CIR digital camera was used to acquire colour infrared digital photographs of the sand dune systems along the Mediterranean coast of France, from Le Barcares to St-Cyprien-Plage. These have been used to assess the condition of the dunes along this coast. A series of simple analytical techniques to identify and measure features indicative of public pressure using image processing software has been devised. The dune manager with basic computer skills can analyse such indicators as path length, vegetation cover (and conversely the extent of bare sand) to enable monitoring of the performance of their dune systems under particular management regimes. These photographs have been compared with similar digital photographs of dune sites in SW France to allow a comparison of dune degradation in a region with a different population pressure and climate regime. Dune systems sampled from the Mediterranean coastal zone showed more evidence of anthropogenically induced change than those sampled in SW France.     

Comparing impacts across climate models

In this paper we combine a climate-forecasting model, COSMIC, with a global impact model, GIM, to compare the market impacts of climate change projected by 14 general circulation models. Given a specific date (2100), carbon dioxide concentration (612 ppmv), and global temperature sensitivity (2.5°C), predicted impacts to economies are calculated using climate-response functions from Experimental and Cross-sectional evidence. The Cross-sectional impact model predicts small global benefits across all climate models, whereas the Experimental impact model predicts a range from small benefits to small damages. High-latitude countries are less sensitive to temperature increases than low-latitude countries because they are currently cool. Uniform global temperature changes overestimate global damages because they underestimate the benefits in polar regions and overestimate the damages in tropical regions compared to the GCM predictions.